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Hydrous Oxide
Hydrous oxides are inorganic compounds of a metal, hydroxide, and weakly bound water. Some examples include: * Hydrous ferric oxide (HFO) *Hydrous cupric oxide *Hydrous thorium oxide (THO) and hydrous titanium oxide (TiHO) *Hydrous aluminum oxide (HAO) Some of them, such as HFO and HAO, are precipitated in highly porous poorly crystalline or amorphous forms and therefore are good adsorbents used for example in water treatment. Some others are gels. Hydrous oxide films may be used an various applications such as electrocatalysis, supercapacitors, and sensors. HFO and HAO may also result from oxidative weathering of rocks to produce iron an aluminum hydrous oxide clay soils. See also * Hydrate * Ferrihydrite Ferrihydrite (Fh) is a widespread hydrous ferric oxyhydroxide mineral at the Earth's surface, and a likely constituent in extraterrestrial materials. It forms in several types of environments, from freshwater to marine systems, aquifers to hydr ... References {{chem-s ...
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Hydroxide
Hydroxide is a diatomic anion with chemical formula OH−. It consists of an oxygen and hydrogen atom held together by a single covalent bond, and carries a negative electric charge. It is an important but usually minor constituent of water. It functions as a base, a ligand, a nucleophile, and a catalyst. The hydroxide ion forms salts, some of which dissociate in aqueous solution, liberating solvated hydroxide ions. Sodium hydroxide is a multi-million-ton per annum commodity chemical. The corresponding electrically neutral compound HO• is the hydroxyl radical. The corresponding covalently bound group –OH of atoms is the hydroxy group. Both the hydroxide ion and hydroxy group are nucleophiles and can act as catalysts in organic chemistry. Many inorganic substances which bear the word ''hydroxide'' in their names are not ionic compounds of the hydroxide ion, but covalent compounds which contain hydroxy groups. Hydroxide ion The hydroxide ion is a natural p ...
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Hydrous Ferric Oxide
Iron(III) oxide-hydroxide or ferric oxyhydroxideA. L. Mackay (1960): "β-Ferric Oxyhydroxide". ''Mineralogical Magazine'' (''Journal of the Mineralogical Society''), volume 32, issue 250, pages 545-557. is the chemical compound of iron, oxygen, and hydrogen with formula . The compound is often encountered as one of its hydrates, ·''n'' ust The monohydrate · is often referred to as iron(III) hydroxide ,CAS , C.I. 77492 hydrated iron oxide, yellow iron oxide, or Pigment Yellow 42. Natural occurrences Minerals Anhydrous ferric hydroxide occurs in the nature as the exceedingly rare mineral bernalite, Fe(OH)3·''n''H2O (n=0.0-0.25). Iron oxyhydroxides, , are much more common and occur naturally as structurally different minerals (polymorphs) denoted by the Greek letters α, β, γ and δ. * Goethite, α-FeO(OH), has been used as an ochre pigment since prehistoric times. * Akaganeite is the β polymorph,A. L. Mackay (1962): "β-Ferric oxyhydroxide—akaganéite", ''Miner ...
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Water Treatment
Water treatment is any process that improves the quality of water to make it appropriate for a specific end-use. The end use may be drinking, industrial water supply, irrigation, river flow maintenance, water recreation or many other uses, including being safely returned to the environment. Water treatment removes contaminants and undesirable components, or reduces their concentration so that the water becomes fit for its desired end-use. This treatment is crucial to human health and allows humans to benefit from both drinking and irrigation use. Water is the most crucial compound for life on Earth, and having drinkable water is a key worldwide concern for the twenty-first century. All living things require clean, uncontaminated water as a basic requirement. Water covers more than 71 percent of the earth’s surface, but only around 1% of it is drinkable according to international standards due to various contaminations . Waste water discharge from industries, agricultural ...
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Hydrate
In chemistry, a hydrate is a substance that contains water or its constituent elements. The chemical state of the water varies widely between different classes of hydrates, some of which were so labeled before their chemical structure was understood. Chemical nature Inorganic chemistry Hydrates are inorganic salts "containing water molecules combined in a definite ratio as an integral part of the crystal" that are either bound to a metal center or that have crystallized with the metal complex. Such hydrates are also said to contain ''water of crystallization'' or ''water of hydration''. If the water is heavy water in which the constituent hydrogen is the isotope deuterium, then the term ''deuterate'' may be used in place of ''hydrate''. A colorful example is cobalt(II) chloride, which turns from blue to red upon hydration, and can therefore be used as a water indicator. The notation "''hydrated compound''⋅''n''", where ''n'' is the number of water molecules per formula ...
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Ferrihydrite
Ferrihydrite (Fh) is a widespread hydrous ferric oxyhydroxide mineral at the Earth's surface, and a likely constituent in extraterrestrial materials. It forms in several types of environments, from freshwater to marine systems, aquifers to hydrothermal hot springs and scales, soils, and areas affected by mining. It can be precipitated directly from oxygenated iron-rich aqueous solutions, or by bacteria either as a result of a metabolic activity or passive sorption of dissolved iron followed by nucleation reactions. Ferrihydrite also occurs in the core of the ferritin protein from many living organisms, for the purpose of intra-cellular iron storage. Structure Ferrihydrite only exists as a fine grained and highly defective nanomaterial. The powder X-ray diffraction pattern of Fh contains two scattering bands in its most disordered state, and a maximum of six strong lines in its most crystalline state. The principal difference between these two diffraction end-members, commonly ...
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Inorganic Compounds
In chemistry, an inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds, that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as '' inorganic chemistry''. Inorganic compounds comprise most of the Earth's crust, although the compositions of the deep mantle remain active areas of investigation. Some simple carbon compounds are often considered inorganic. Examples include the allotropes of carbon ( graphite, diamond, buckminsterfullerene, etc.), carbon monoxide, carbon dioxide, carbides, and the following salts of inorganic anions: carbonates, cyanides, cyanates, and thiocyanates. Many of these are normal parts of mostly organic systems, including organisms; describing a chemical as inorganic does not necessarily mean that it does not occur within living things. History Friedrich Wöhler's conversion of ammonium cyanate into urea in 1828 is often cited as the starting point of ...
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Hydrogen Compounds
Hydrogen compounds are compounds containg the element hydrogen. In these compounds, hydrogen can form in the +1 and -1 oxidation states. Hydrogen can form compounds both ionically and in covalent substances. It is a part of many organic compounds such as hydrocarbons as well as water and other organic substances. The ion is often called a proton because it has one proton and no electrons, although the proton does not move freely. Brønsted–Lowry acids are capable of donating ions to bases. Covalent and organic compounds While is not very reactive under standard conditions, it does form compounds with most elements. Hydrogen can form compounds with elements that are more electronegative, such as halogens (F, Cl, Br, I), or oxygen; in these compounds hydrogen takes on a partial positive charge. When bonded to a more electronegative element, particularly fluorine, oxygen, or nitrogen, hydrogen can participate in a form of medium-strength noncovalent bonding with another elect ...
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Oxygen Compounds
The oxidation state of oxygen is −2 in almost all known compounds of oxygen. The oxidation state −1 is found in a few compounds such as peroxides. Compounds containing oxygen in other oxidation states are very uncommon: − (superoxides), − (ozonides), 0 (elemental, hypofluorous acid), + ( dioxygenyl), +1 ( dioxygen difluoride), and +2 (oxygen difluoride). Oxygen is reactive and will form oxides with all other elements except the noble gases helium, neon, argon and krypton. Oxides Water () is the oxide of hydrogen and most familiar oxygen compound. Its bulk properties partly result from the interaction of its component atoms, oxygen and hydrogen, with atoms of nearby water molecules. Hydrogen atoms are covalently bonded to oxygen in a water molecule but also have an additional attraction (about 23.3 kJ·mol−1 per hydrogen atom) to an adjacent oxygen atom in a separate molecule. These hydrogen bonds between water molecules hold them approximately 15% closer ...
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