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Hamiltonian (quantum Mechanics)
In quantum mechanics, the Hamiltonian of a system is an operator corresponding to the total energy of that system, including both kinetic energy and potential energy. Its spectrum, the system's ''energy spectrum'' or its set of ''energy eigenvalues'', is the set of possible outcomes obtainable from a measurement of the system's total energy. Due to its close relation to the energy spectrum and time-evolution of a system, it is of fundamental importance in most formulations of quantum theory. The Hamiltonian is named after William Rowan Hamilton, who developed a revolutionary reformulation of Newtonian mechanics, known as Hamiltonian mechanics, which was historically important to the development of quantum physics. Similar to vector notation, it is typically denoted by \hat, where the hat indicates that it is an operator. It can also be written as H or \check. Introduction The Hamiltonian of a system represents the total energy of the system; that is, the sum of the kine ...
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Quantum Mechanics
Quantum mechanics is the fundamental physical Scientific theory, theory that describes the behavior of matter and of light; its unusual characteristics typically occur at and below the scale of atoms. Reprinted, Addison-Wesley, 1989, It is the foundation of all quantum physics, which includes quantum chemistry, quantum field theory, quantum technology, and quantum information science. Quantum mechanics can describe many systems that classical physics cannot. Classical physics can describe many aspects of nature at an ordinary (macroscopic and Microscopic scale, (optical) microscopic) scale, but is not sufficient for describing them at very small submicroscopic (atomic and subatomic) scales. Classical mechanics can be derived from quantum mechanics as an approximation that is valid at ordinary scales. Quantum systems have Bound state, bound states that are Quantization (physics), quantized to Discrete mathematics, discrete values of energy, momentum, angular momentum, and ot ...
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Laplacian
In mathematics, the Laplace operator or Laplacian is a differential operator given by the divergence of the gradient of a scalar function on Euclidean space. It is usually denoted by the symbols \nabla\cdot\nabla, \nabla^2 (where \nabla is the nabla operator), or \Delta. In a Cartesian coordinate system, the Laplacian is given by the sum of second partial derivatives of the function with respect to each independent variable. In other coordinate systems, such as cylindrical and spherical coordinates, the Laplacian also has a useful form. Informally, the Laplacian of a function at a point measures by how much the average value of over small spheres or balls centered at deviates from . The Laplace operator is named after the French mathematician Pierre-Simon de Laplace (1749–1827), who first applied the operator to the study of celestial mechanics: the Laplacian of the gravitational potential due to a given mass density distribution is a constant multiple of that de ...
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Homomorphism
In algebra, a homomorphism is a morphism, structure-preserving map (mathematics), map between two algebraic structures of the same type (such as two group (mathematics), groups, two ring (mathematics), rings, or two vector spaces). The word ''homomorphism'' comes from the Ancient Greek language: () meaning "same" and () meaning "form" or "shape". However, the word was apparently introduced to mathematics due to a (mis)translation of German meaning "similar" to meaning "same". The term "homomorphism" appeared as early as 1892, when it was attributed to the German mathematician Felix Klein (1849–1925). Homomorphisms of vector spaces are also called linear maps, and their study is the subject of linear algebra. The concept of homomorphism has been generalized, under the name of morphism, to many other structures that either do not have an underlying set, or are not algebraic. This generalization is the starting point of category theory. A homomorphism may also be an isomorphis ...
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Holomorphic Functional Calculus
In mathematics, holomorphic functional calculus is functional calculus with holomorphic functions. That is to say, given a holomorphic function ''f'' of a complex argument ''z'' and an operator ''T'', the aim is to construct an operator, ''f''(''T''), which naturally extends the function ''f'' from complex argument to operator argument. More precisely, the functional calculus defines a continuous algebra homomorphism from the holomorphic functions on a neighbourhood of the spectrum of ''T'' to the bounded operators. This article will discuss the case where ''T'' is a bounded linear operator on some Banach space. In particular, ''T'' can be a square matrix with complex entries, a case which will be used to illustrate functional calculus and provide some heuristic insights for the assumptions involved in the general construction. Motivation Need for a general functional calculus In this section ''T'' will be assumed to be a ''n'' × ''n'' matrix with complex entrie ...
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Continuous Functional Calculus
In mathematics, particularly in operator theory and C*-algebra theory, the continuous functional calculus is a functional calculus which allows the application of a continuous function to normal elements of a C*-algebra. In advanced theory, the applications of this functional calculus are so natural that they are often not even mentioned. It is no overstatement to say that the continuous functional calculus makes ''the'' difference between C*-algebras and general Banach algebras, in which only a holomorphic functional calculus exists. Motivation If one wants to extend the natural functional calculus for polynomials on the spectrum \sigma(a) of an element a of a Banach algebra \mathcal to a functional calculus for continuous functions C(\sigma(a)) on the spectrum, it seems obvious to approximate a continuous function by polynomials according to the Stone-Weierstrass theorem, to insert the element into these polynomials and to show that this sequence of elements converges to ...
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Functional Calculus
In mathematics, a functional calculus is a theory allowing one to apply mathematical functions to mathematical operators. It is now a branch (more accurately, several related areas) of the field of functional analysis, connected with spectral theory. (Historically, the term was also used synonymously with calculus of variations; this usage is obsolete, except for functional derivative. Sometimes it is used in relation to types of functional equations, or in logic for systems of predicate calculus.) If f is a function, say a numerical function of a real number, and M is an operator, there is no particular reason why the expression f(M) should make sense. If it does, then we are no longer using f on its original function domain. In the tradition of operational calculus, algebraic expressions in operators are handled irrespective of their meaning. This passes nearly unnoticed if we talk about 'squaring a matrix', though, which is the case of f(x) = x^2 and M an n\times ...
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Unbounded Operator
In mathematics, more specifically functional analysis and operator theory, the notion of unbounded operator provides an abstract framework for dealing with differential operators, unbounded observables in quantum mechanics, and other cases. The term "unbounded operator" can be misleading, since * "unbounded" should sometimes be understood as "not necessarily bounded"; * "operator" should be understood as "linear operator" (as in the case of "bounded operator"); * the domain of the operator is a linear subspace, not necessarily the whole space; * this linear subspace is not necessarily closed; often (but not always) it is assumed to be dense; * in the special case of a bounded operator, still, the domain is usually assumed to be the whole space. In contrast to bounded operators, unbounded operators on a given space do not form an algebra, nor even a linear space, because each one is defined on its own domain. The term "operator" often means "bounded linear operator", but in the ...
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Matrix Exponential
In mathematics, the matrix exponential is a matrix function on square matrix, square matrices analogous to the ordinary exponential function. It is used to solve systems of linear differential equations. In the theory of Lie groups, the matrix exponential gives the exponential map (Lie theory), exponential map between a matrix Lie algebra and the corresponding Lie group. Let be an real number, real or complex number, complex matrix (mathematics), matrix. The exponential of , denoted by or , is the matrix given by the power series e^X = \sum_^\infty \frac X^k where X^0 is defined to be the identity matrix I with the same dimensions as X, and . The series always converges, so the exponential of is well-defined. Equivalently, e^X = \lim_ \left(I + \frac \right)^k for integer-valued , where is the identity matrix. Equivalently, given by the solution to the differential equation \frac d e^ = X e^, \quad e^ = I When is an diagonal matrix then will be an diagonal matr ...
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Hamilton–Jacobi Equation
In physics, the Hamilton–Jacobi equation, named after William Rowan Hamilton and Carl Gustav Jacob Jacobi, is an alternative formulation of classical mechanics, equivalent to other formulations such as Newton's laws of motion, Lagrangian mechanics and Hamiltonian mechanics. The Hamilton–Jacobi equation is a formulation of mechanics in which the motion of a particle can be represented as a wave. In this sense, it fulfilled a long-held goal of theoretical physics (dating at least to Johann Bernoulli in the eighteenth century) of finding an analogy between the propagation of light and the motion of a particle. The wave equation followed by mechanical systems is similar to, but not identical with, the Schrödinger equation, as described below; for this reason, the Hamilton–Jacobi equation is considered the "closest approach" of classical mechanics to quantum mechanics. (particularly the discussion beginning in the last paragraph of page 491) The qualitative form of this conne ...
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Many-body Problem
The many-body problem is a general name for a vast category of physical problems pertaining to the properties of microscopic systems made of many interacting particles. Terminology ''Microscopic'' here implies that quantum mechanics has to be used to provide an accurate description of the system. ''Many'' can be anywhere from three to infinity (in the case of a practically infinite, homogeneous or periodic system, such as a crystal), although three- and four-body systems can be treated by specific means (respectively the Faddeev and Faddeev–Yakubovsky equations) and are thus sometimes separately classified as few-body systems. Explanation of the problem In general terms, while the underlying physical laws that govern the motion of each individual particle may (or may not) be simple, the study of the collection of particles can be extremely complex. In such a quantum system, the repeated interactions between particles create quantum correlations, or entanglement. As a consequ ...
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Divergence Theorem
In vector calculus, the divergence theorem, also known as Gauss's theorem or Ostrogradsky's theorem, reprinted in is a theorem relating the '' flux'' of a vector field through a closed surface to the ''divergence'' of the field in the volume enclosed. More precisely, the divergence theorem states that the surface integral of a vector field over a closed surface, which is called the "flux" through the surface, is equal to the volume integral of the divergence over the region enclosed by the surface. Intuitively, it states that "the sum of all sources of the field in a region (with sinks regarded as negative sources) gives the net flux out of the region". The divergence theorem is an important result for the mathematics of physics and engineering, particularly in electrostatics and fluid dynamics. In these fields, it is usually applied in three dimensions. However, it generalizes to any number of dimensions. In one dimension, it is equivalent to the fundamental theorem of cal ...
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