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Fuel Cell Vehicles
A fuel cell vehicle (FCV) or fuel cell electric vehicle (FCEV) is an electric vehicle that uses a fuel cell, sometimes in combination with a small battery or supercapacitor, to power its onboard electric motor. Fuel cells in vehicles generate electricity generally using oxygen from the air and compressed hydrogen. Most fuel cell vehicles are classified as zero-emissions vehicles that emit only water and heat. As compared with internal combustion vehicles, hydrogen vehicles centralize pollutants at the site of the hydrogen production, where hydrogen is typically derived from reformed natural gas. Transporting and storing hydrogen may also create pollutants. Fuel cells have been used in various kinds of vehicles including forklifts, especially in indoor applications where their clean emissions are important to air quality, and in space applications. The first commercially produced hydrogen fuel cell automobile, the Hyundai ix35 FCEV, was introduced in 2013, the Toyota Mirai follo ...
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Toyota Mirai
The (from , Japanese for 'future') is a mid-size hydrogen fuel cell vehicle (FCV) manufactured by Toyota, and is one of the first FCV automobiles to be mass-produced and sold commercially. The Mirai was unveiled at the November 2014 Los Angeles Auto Show. , global sales totaled 17,940 units; the top-selling markets were the U.S. with 9,274 units, Japan with 6,618 and the rest of the world with 2,048. Under the U.S. Environmental Protection Agency (EPA) cycle, the 2016 model year Mirai has a total range of on a full tank. The MPG-equivalent combined city/highway fuel economy rating was , making the Mirai the most fuel-efficient hydrogen fuel cell vehicle rated at the time by the EPA, and the one with the longest range. ''One kg of hydrogen is roughly equivalent to one U.S. gallon of gasoline.'' In August 2021, the second-generation Mirai set a world record of traveling with a full tank of 5.65 kg hydrogen. Sales in Japan began on 15 December 2014 at (~) at ''Toyota St ...
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Honda Clarity
The Honda Clarity is a nameplate used by Honda on alternative fuel vehicles. It was initially used only on hydrogen fuel-cell electric vehicles such as the 2008 Honda FCX Clarity, but in 2017 the nameplate was expanded to include the battery-electric Honda Clarity Electric and the plug-in hybrid electric Honda Clarity Plug-in Hybrid, in addition to the next generation Honda Clarity Fuel Cell. Clarity production ended in August 2021 with US leases for the fuel cell variant continuing through to 2022. Honda FCX Clarity (2008–2014) History The Honda FCX Clarity is based on the 2006 Honda FCX Concept and only available as a hydrogen fuel-cell electric vehicle. The FCX Clarity had electric car qualities such as zero emissions while offering five minute refueling times and long range in a full function large sedan. It was the first hydrogen fuel cell vehicle available to retail customers. Production began in June 2008 with leasing in the U.S. commenced in July 2008. It was i ...
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Francis Thomas Bacon
Francis Thomas Bacon OBE FREng FRS (21 December 1904 – 24 May 1992) was an English engineer who in 1932 developed the first practical hydrogen–oxygen fuel cell. It is used to generate power for space capsules and satellites. Life and works Francis Thomas Bacon was born in 1904 at Ramsden Hall, Billericay, Essex, England. An engineer at Trinity College, Cambridge, in 1932 he developed the fuel cell which was used as part of the Apollo moon project in the 1960s. Fuel cells were first demonstrated by Sir William Robert Grove in 1839, but his invention lay largely dormant for over 100 years until it was revived by Bacon. The alkaline fuel cell (AFC), also known as the Bacon fuel cell after its inventor, has been used in NASA space programs since the mid-1960s to generate power for satellites and space capsules. The U.S. President Richard Nixon welcomed Bacon to the White House, and told him; "Without you Tom, we wouldn't have gotten to the moon.” After the successful lu ...
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William Robert Grove
Sir William Robert Grove, FRS FRSE (11 July 1811 – 1 August 1896) was a Welsh judge and physical scientist. He anticipated the general theory of the conservation of energy, and was a pioneer of fuel cell technology. He invented the Grove voltaic cell. Early life Born in Swansea, Wales, Grove was the only child of John, a magistrate and deputy lieutenant of Glamorgan, and his wife, Anne ''née'' Bevan. His early education was in the hands of private tutors, before he attended Brasenose College, Oxford to study classics, though his scientific interests may have been cultivated by mathematician Baden Powell. Otherwise, his taste for science has no clear origin though his circle in Swansea was broadly educated. He graduated in 1832. In 1835 he was called to the bar by Lincoln's Inn. In the same year, Grove joined the Royal Institution and was a founder of the Swansea Literary and Philosophical Society, an organisation with which he maintained close links. Scientific ...
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Humphry Davy
Sir Humphry Davy, 1st Baronet, (17 December 177829 May 1829) was a British chemist and inventor who invented the Davy lamp and a very early form of arc lamp. He is also remembered for isolating, by using electricity, several elements for the first time: potassium and sodium in 1807 and calcium, strontium, barium, magnesium and boron the following year, as well as for discovering the elemental nature of chlorine and iodine. Davy also studied the forces involved in these separations, inventing the new field of electrochemistry. Davy is also credited to have been the first to discover clathrate hydrates in his lab. In 1799 he experimented with nitrous oxide and was astonished at how it made him laugh, so he nicknamed it "laughing gas" and wrote about its potential anaesthetic properties in relieving pain during surgery. Davy was a baronet, President of the Royal Society (PRS), Member of the Royal Irish Academy (MRIA), Fellow of the Geological Society (FGS), and a mem ...
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1966 GM Electrovan - Fuel Cell
Events January * January 1 – In a coup, Colonel Jean-Bédel Bokassa takes over as military ruler of the Central African Republic, ousting President David Dacko. * January 3 – 1966 Upper Voltan coup d'état: President Maurice Yaméogo is deposed by a military coup in the Republic of Upper Volta (modern-day Burkina Faso). * January 10 ** Pakistani–Indian peace negotiations end successfully with the signing of the Tashkent Declaration, a day before the sudden death of Indian prime minister Lal Bahadur Shastri. ** The House of Representatives of the US state of Georgia refuses to allow African-American representative Julian Bond to take his seat, because of his anti-war stance. ** A Commonwealth Prime Ministers' Conference convenes in Lagos, Nigeria, primarily to discuss Rhodesia. * January 12 – United States President Lyndon Johnson states that the United States should stay in South Vietnam until Communist aggression there is ended. * January 15 – 1966 Nigeria ...
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RMFC
Reformed Methanol Fuel Cell (RMFC) or Indirect Methanol Fuel Cell (IMFC) systems are a subcategory of proton exchange membrane fuel cell, proton-exchange fuel cells where, the fuel, methanol (CH3OH), is reformed, before being fed into the fuel cell. RMFC systems offer advantages over direct methanol fuel cell (DMFC) systems including higher efficiency, smaller cell stacks, less requirement on methanol purity, no water management, better operation at low temperatures, and storage at sub-zero temperatures because methanol is a liquid from -97.0 °C to 64.7 °C (-142.6 °F to 148.5 °F) and as there is no liquid methanol-water mixture in the cells which can destroy the membrane of DMFC in case of frost. The reason for the high efficiency of RMFC in contrast to DMFC is that hydrogen containing gas is fed to the fuel cell stack instead of methanol and overpotential (power loss for catalytic conversion) on anode is much lower for hydrogen than for methanol. The trade ...
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SOFC
A solid oxide fuel cell (or SOFC) is an electrochemical conversion device that produces electricity directly from oxidizing a fuel. Fuel cells are characterized by their electrolyte material; the SOFC has a solid oxide or ceramic electrolyte. Advantages of this class of fuel cells include high combined heat and power efficiency, long-term stability, fuel flexibility, low emissions, and relatively low cost. The largest disadvantage is the high operating temperature which results in longer start-up times and mechanical and chemical compatibility issues. Introduction Solid oxide fuel cells are a class of fuel cells characterized by the use of a solid oxide material as the electrolyte. SOFCs use a solid oxide electrolyte to conduct negative oxygen ions from the cathode to the anode. The electrochemical oxidation of the hydrogen, carbon monoxide or other organic intermediates by oxygen ions thus occurs on the anode side. More recently, proton-conducting SOFCs (PC-SOFC) are being deve ...
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Molten Carbonate Fuel Cell
Molten-carbonate fuel cells (MCFCs) are high-temperature fuel cells that operate at temperatures of 600 °C and above. Molten carbonate fuel cells (MCFCs) were developed for natural gas, biogas (produced as a result of anaerobic digestion or biomass gasification), and coal- based power plants for electrical utility, industrial, and military applications. MCFCs are high-temperature fuel cells that use an electrolyte composed of a molten carbonate salt mixture suspended in a porous, chemically inert ceramic matrix of beta-alumina solid electrolyte (BASE). Since they operate at extremely high temperatures of 650 °C (roughly 1,200 °F) and above, non-precious metals can be used as catalysts at the anode and cathode, reducing costs. Improved efficiency is another reason MCFCs offer significant cost reductions over phosphoric acid fuel cells (PAFCs). Molten carbonate fuel cells can reach efficiencies approaching 60%, considerably higher than the 37–42% efficienci ...
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Phosphoric Acid Fuel Cell
Phosphoric acid fuel cells (PAFC) are a type of fuel cell that uses liquid phosphoric acid as an electrolyte. They were the first fuel cells to be commercialized. Developed in the mid-1960s and field-tested since the 1970s, they have improved significantly in stability, performance, and cost. Such characteristics have made the PAFC a good candidate for early stationary applications. Design Electrolyte is highly concentrated or pure liquid phosphoric acid (H3PO4) saturated in a silicon carbide (SiC) matrix. Operating range is about 150 to 210 °C. The electrodes are made of carbon paper coated with a finely dispersed platinum catalyst. Electrode reactions Anode reaction: 2H2(g) → 4H+ + 4e‾ Cathode reaction: O2(g) + 4H+ + 4e‾ → 2H2O Overall cell reaction: 2 H2 + O2 → 2H2O Advantages and disadvantages At an operating range of 150 to 200 °C, the expelled water can be converted to steam for air and water heating (combined heat and power). This potentially all ...
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DMFC
Direct-methanol fuel cells or DMFCs are a subcategory of proton-exchange fuel cells in which methanol is used as the fuel. Their main advantage is the ease of transport of methanol, an energy-dense yet reasonably stable liquid at all environmental conditions. Whilst the thermodynamic theoretical energy conversion efficiency of a DMFC is 97%; the currently achievable energy conversion efficiency for operational cells attains 30% – 40%. There is intensive research on promising approaches to increase the operational efficiency. A more efficient version of a direct fuel cell would play a key role in the theoretical use of methanol as a general energy transport medium, in the hypothesized methanol economy. The cell In contrast to indirect methanol fuel cells, where methanol is reacted to hydrogen by steam reforming, DMFCs use a methanol solution (usually around 1 M, i.e. about 3% in mass) to carry the reactant into the cell; common operating temperatures are in the range , where ...
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PEMFC
Proton-exchange membrane fuel cells (PEMFC), also known as polymer electrolyte membrane (PEM) fuel cells, are a type of fuel cell being developed mainly for transport applications, as well as for stationary fuel-cell applications and portable fuel-cell applications. Their distinguishing features include lower temperature/pressure ranges (50 to 100 °C) and a special proton-conducting polymer electrolyte membrane. PEMFCs generate electricity and operate on the opposite principle to PEM electrolysis, which consumes electricity. They are a leading candidate to replace the aging alkaline fuel-cell technology, which was used in the Space Shuttle. Science PEMFCs are built out of membrane electrode assemblies (MEA) which include the electrodes, electrolyte, catalyst, and gas diffusion layers. An ink of catalyst, carbon, and electrode are sprayed or painted onto the solid electrolyte and carbon paper is hot pressed on either side to protect the inside of the cell and also act ...
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