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Electron Holes
In physics, chemistry, and electronic engineering, an electron hole (often simply called a hole) is a quasiparticle denoting the lack of an electron at a position where one could exist in an atom or atomic lattice. Since in a normal atom or crystal lattice the negative charge of the electrons is balanced by the positive charge of the atomic nuclei, the absence of an electron leaves a net positive charge at the hole's location. Holes in a metal or semiconductor crystal lattice can move through the lattice as electrons can, and act similarly to positively-charged particles. They play an important role in the operation of semiconductor devices such as transistors, diodes (including light-emitting diodes) and integrated circuits. If an electron is excited into a higher state it leaves a hole in its old state. This meaning is used in Auger electron spectroscopy (and other x-ray techniques), in computational chemistry, and to explain the low electron-electron scattering-rate in cr ...
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X-ray
An X-ray (also known in many languages as Röntgen radiation) is a form of high-energy electromagnetic radiation with a wavelength shorter than those of ultraviolet rays and longer than those of gamma rays. Roughly, X-rays have a wavelength ranging from 10 Nanometre, nanometers to 10 Picometre, picometers, corresponding to frequency, frequencies in the range of 30 Hertz, petahertz to 30 Hertz, exahertz ( to ) and photon energies in the range of 100 electronvolt, eV to 100 keV, respectively. X-rays were discovered in 1895 in science, 1895 by the German scientist Wilhelm Röntgen, Wilhelm Conrad Röntgen, who named it ''X-radiation'' to signify an unknown type of radiation.Novelline, Robert (1997). ''Squire's Fundamentals of Radiology''. Harvard University Press. 5th edition. . X-rays can penetrate many solid substances such as construction materials and living tissue, so X-ray radiography is widely used in medical diagnostics (e.g., checking for Bo ...
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Crystal Structure
In crystallography, crystal structure is a description of ordered arrangement of atoms, ions, or molecules in a crystalline material. Ordered structures occur from intrinsic nature of constituent particles to form symmetric patterns that repeat along the principal directions of three-dimensional space in matter. The smallest group of particles in a material that constitutes this repeating pattern is the unit cell of the structure. The unit cell completely reflects the symmetry and structure of the entire crystal, which is built up by repetitive translation of the unit cell along its principal axes. The translation vectors define the nodes of the Bravais lattice. The lengths of principal axes/edges, of the unit cell and angles between them are lattice constants, also called ''lattice parameters'' or ''cell parameters''. The symmetry properties of a crystal are described by the concept of space groups. All possible symmetric arrangements of particles in three-dimensional space ...
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Valence Band
In solid-state physics, the valence band and conduction band are the bands closest to the Fermi level, and thus determine the electrical conductivity of the solid. In nonmetals, the valence band is the highest range of electron energies in which electrons are normally present at absolute zero temperature, while the conduction band is the lowest range of vacant electronic states. On a graph of the electronic band structure of a semiconducting material, the valence band is located below the Fermi level, while the conduction band is located above it. The distinction between the valence and conduction bands is meaningless in metals, because conduction occurs in one or more partially filled bands that take on the properties of both the valence and conduction bands. Band gap In semiconductors and insulators the two bands are separated by a band gap, while in conductors the bands overlap. A band gap is an energy range in a solid where no electron states can exist due to th ...
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Semiconductor
A semiconductor is a material with electrical conductivity between that of a conductor and an insulator. Its conductivity can be modified by adding impurities (" doping") to its crystal structure. When two regions with different doping levels are present in the same crystal, they form a semiconductor junction. The behavior of charge carriers, which include electrons, ions, and electron holes, at these junctions is the basis of diodes, transistors, and most modern electronics. Some examples of semiconductors are silicon, germanium, gallium arsenide, and elements near the so-called " metalloid staircase" on the periodic table. After silicon, gallium arsenide is the second-most common semiconductor and is used in laser diodes, solar cells, microwave-frequency integrated circuits, and others. Silicon is a critical element for fabricating most electronic circuits. Semiconductor devices can display a range of different useful properties, such as passing current more easil ...
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Group Velocity
The group velocity of a wave is the velocity with which the overall envelope shape of the wave's amplitudes—known as the ''modulation'' or ''envelope (waves), envelope'' of the wave—propagates through space. For example, if a stone is thrown into the middle of a very still pond, a circular pattern of waves with a quiescent center appears in the water, also known as a capillary wave. The expanding ring of waves is the wave group or wave packet, within which one can discern individual waves that travel faster than the group as a whole. The amplitudes of the individual waves grow as they emerge from the trailing edge of the group and diminish as they approach the leading edge of the group. History The idea of a group velocity distinct from a wave's phase velocity was first proposed by William Rowan Hamilton, W.R. Hamilton in 1839, and the first full treatment was by John Strutt, 3rd Baron Rayleigh, Rayleigh in his "Theory of Sound" in 1877. Definition and interpretation ...
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Crystal Momentum
In solid-state physics, crystal momentum or quasimomentum is a Momentum#Momentum in quantum mechanics, momentum-like Vector (geometric), vector associated with electrons in a Crystal structure, crystal lattice. It is defined by the associated Reciprocal lattice, wave vectors \mathbf of this lattice, according to \mathbf_ \equiv \hbar \mathbf (where \hbar is the reduced Planck constant). Frequently, crystal momentum is Momentum#Conservation, conserved like mechanical momentum, making it useful to physicists and materials scientists as an analytical tool. Lattice symmetry origins A common method of modeling crystal structure and behavior is to view electrons as Quantum mechanics, quantum mechanical particles traveling through a fixed infinite periodic potential V(x) such that V(\mathbf + \mathbf) = V(\mathbf), where \mathbf is an arbitrary Bravais lattice, lattice vector. Such a model is sensible because crystal Ion, ions that form the lattice structure are typically on the order ...
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Negative Mass
In theoretical physics, negative mass is a hypothetical type of exotic matter whose mass is of opposite sign to the mass of normal matter, e.g. −1 kg. Such matter would violate one or more energy conditions and exhibit strange properties such as the oppositely oriented acceleration for an applied force orientation. It is used in certain speculative hypothetical technologies such as time travel to the past and future, construction of traversable artificial wormholes, which may also allow for time travel, Krasnikov tubes, the Alcubierre drive, and potentially other types of faster-than-light warp drives. Currently, the closest known real representative of such exotic matter is a region of negative pressure density produced by the Casimir effect. In cosmology In December 2018, astrophysicist Jamie Farnes from the University of Oxford proposed a " dark fluid" theory, related, in part, to notions of gravitationally repulsive negative masses, presented earlier by Albert Ein ...
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Effective Mass (solid-state Physics)
In solid state physics, a particle's effective mass (often denoted m^*) is the mass that it ''seems'' to have when responding to forces, or the mass that it seems to have when interacting with other identical particles in a thermal distribution. One of the results from the band theory of solids is that the movement of particles in a periodic potential, over long distances larger than the lattice spacing, can be very different from their motion in a vacuum. The effective mass is a quantity that is used to simplify band structures by modeling the behavior of a free particle with that mass. For some purposes and some materials, the effective mass can be considered to be a simple constant of a material. In general, however, the value of effective mass depends on the purpose for which it is used, and can vary depending on a number of factors. For electrons or electron holes in a solid, the effective mass is usually stated as a factor multiplying the rest mass of an electron, ''m'' ...
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Electronic Band Structure
In solid-state physics, the electronic band structure (or simply band structure) of a solid describes the range of energy levels that electrons may have within it, as well as the ranges of energy that they may not have (called ''band gaps'' or ''forbidden bands''). Band theory derives these bands and band gaps by examining the allowed quantum mechanical wave functions for an electron in a large, periodic lattice of atoms or molecules. Band theory has been successfully used to explain many physical properties of solids, such as electrical resistivity and optical absorption, and forms the foundation of the understanding of all solid-state devices (transistors, solar cells, etc.). Why bands and band gaps occur The formation of electronic bands and band gaps can be illustrated with two complementary models for electrons in solids. The first one is the nearly free electron model, in which the electrons are assumed to move almost freely within the material. In this model, the ...
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Crystal
A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macroscopic single crystals are usually identifiable by their geometrical shape, consisting of flat faces with specific, characteristic orientations. The scientific study of crystals and crystal formation is known as crystallography. The process of crystal formation via mechanisms of crystal growth is called crystallization or solidification. The word ''crystal'' derives from the Ancient Greek word (), meaning both "ice" and " rock crystal", from (), "icy cold, frost". Examples of large crystals include snowflakes, diamonds, and table salt. Most inorganic solids are not crystals but polycrystals, i.e. many microscopic crystals fused together into a single solid. Polycrystals include most metals, rocks, ceramics, and ice. A third cat ...
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Dirac Sea
The Dirac sea is a theoretical model of the electron vacuum as an infinite sea of electrons with negative energy, now called '' positrons''. It was first postulated by the British physicist Paul Dirac in 1930 to explain the anomalous negative-energy quantum states predicted by the relativistically-correct Dirac equation for electrons. The positron, the antimatter counterpart of the electron, was originally conceived of as a hole in the Dirac sea, before its experimental discovery in 1932.This was not the original intent of Dirac though, as the title of his 1930 paper (''A Theory of Electrons and Protons'') indicates. But it soon afterwards became clear that the mass of holes must be that of the electron. In hole theory, the solutions with negative time evolution factors are reinterpreted as representing the positron, discovered by Carl Anderson. The interpretation of this result requires a Dirac sea, showing that the Dirac equation is not merely a combination of special relativ ...
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