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Cyanoacrylate
Cyanoacrylates are a family of strong fast-acting adhesives with industrial, medical, and household uses. They are derived from ethyl cyanoacrylate and related esters. The cyanoacrylate group in the monomer rapidly polymerizes in the presence of water to form long, strong chains. They have some minor toxicity. Specific cyanoacrylates include methyl 2-cyanoacrylate (MCA), ethyl 2-cyanoacrylate (ECA, commonly sold under trade names such as "Super Glue" and "Krazy Glue", or Toagosei), ''n''-butyl cyanoacrylate (n-BCA), octyl cyanoacrylate, and 2-octyl cyanoacrylate (used in medical, veterinary and first aid applications). Octyl cyanoacrylate was developed to address toxicity concerns and to reduce skin irritation and allergic response. Cyanoacrylate adhesives are sometimes known generically as instant glues, power glues or superglues. The abbreviation "CA" is commonly used for industrial grade cyanoacrylate. Development The original patent for cyanoacrylate was filed in 1 ...
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Butyl Cyanoacrylate
''n''-Butyl cyanoacrylate (n-BCA, NBCA), a cyanoacrylate ester, is a butyl ester of 2-cyano-2-propenoic acid. It is a colorless liquid with a sharp, irritating odor. It is insoluble in water. Its chief use is as the main component of medical cyanoacrylate glues. It can be encountered under various trade names, e.g. Cutseal, MediBond, MediCryl, PeriAcryl, GluStitch, Xoin, Gesika, VetGlu, Vetbond, LiquiVet, Indermil, LiquiBand, Histoacryl, IFABond, CutisSeal and others. The generic international nonproprietary name (INN) for NBCA is enbucrilate. In medical and veterinary applications, NBCA, isobutyl cyanoacrylate, and octyl cyanoacrylate are commonly used. They are bacteriostatic and their use is usually painless. Butyl esters provide stronger bond, but are rigid. Octyl esters, while providing weaker bond, are more flexible. Blends of octyl cyanoacrylate and n-butyl cyanoacrylate are available (such as GLUture) which offer both flexibility and a strong bond. n-Butyl cyanoacryl ...
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Ethyl Cyanoacrylate
Ethyl cyanoacrylate (ECA), a cyanoacrylate ester, is an ethyl ester of 2-cyano-2-propenoic acid. It is a colorless liquid with low viscosity and a faint sweet smell in pure form. It is the main component of cyanoacrylate glues and can be encountered under many trade names. It is soluble in acetone, methyl ethyl ketone, nitromethane, and methylene chloride. ECA polymerizes rapidly in presence of moisture. Production Ethyl cyanoacrylate is prepared by the condensation of formaldehyde with ethyl cyanoacetate: : + → + This exothermic reaction affords the polymer, which is subsequently sintered, thermally "cracked" to give the monomer. Alternatively, it can be prepared by the ethoxycarbonylation of cyanoacetylene. Applications Ethyl cyanoacrylate is used for gluing various materials. It is also used in medicine, for liquid bandages and for suture-less surgery, but it is used less often than the less toxic ''n''-butyl and octyl cyanoacrylates. Off-the-shelf consumer ...
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Ethyl Cyanoacrylate
Ethyl cyanoacrylate (ECA), a cyanoacrylate ester, is an ethyl ester of 2-cyano-2-propenoic acid. It is a colorless liquid with low viscosity and a faint sweet smell in pure form. It is the main component of cyanoacrylate glues and can be encountered under many trade names. It is soluble in acetone, methyl ethyl ketone, nitromethane, and methylene chloride. ECA polymerizes rapidly in presence of moisture. Production Ethyl cyanoacrylate is prepared by the condensation of formaldehyde with ethyl cyanoacetate: : + → + This exothermic reaction affords the polymer, which is subsequently sintered, thermally "cracked" to give the monomer. Alternatively, it can be prepared by the ethoxycarbonylation of cyanoacetylene. Applications Ethyl cyanoacrylate is used for gluing various materials. It is also used in medicine, for liquid bandages and for suture-less surgery, but it is used less often than the less toxic ''n''-butyl and octyl cyanoacrylates. Off-the-shelf consumer ...
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Methyl Cyanoacrylate
Methyl cyanoacrylate (MCA) (also sometimes referred to as α-cyanoacrylate or alpha-cyanoacrylate) is an organic compound that contains several functional groups: a methyl ester, a nitrile, and an alkene. It is a colorless liquid with low viscosity. Its chief use is as the main component of cyanoacrylate glues. It can be encountered under many trade names. Methyl cyanoacrylate is less commonly encountered than ethyl cyanoacrylate. It is soluble in acetone, methyl ethyl ketone, nitromethane, and dichloromethane. MCA polymerizes rapidly in presence of moisture. Safety Heating the polymer causes depolymerization of the cured MCA, producing gaseous products which are a strong irritant to the lungs The lungs are the primary organs of the respiratory system in humans and most other animals, including some snails and a small number of fish. In mammals and most other vertebrates, two lungs are located near the backbone on either si ... and eyes. With regards to occu ...
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Octyl Cyanoacrylate
Octyl cyanoacrylate (OCA), a cyanoacrylate ester, is an octyl ester of 2-cyano-2-propenoic acid. It is a clear colorless liquid with a sharp, irritating odor. Its chief use is as the main component of medical cyanoacrylate glues. In medical and veterinary applications, OCA, ''n''-butyl cyanoacrylate (n-BCA) and isobutyl cyanoacrylate (ICA) are commonly used. They provide rapid wound closure, are bacteriostatic, and their use is usually painless. Butyl esters provide a stronger bond, but the glue is rigid. The octyl ester, while providing weaker bond, is more flexible. Blends of OCA and n-BCA are available which offer both flexibility and a strong bond. It polymerizes rapidly in presence of moisture. Heating to higher temperatures causes pyrolysis and depolymerization of the cured glue, producing gaseous products strongly irritating to the lungs and eyes. References {{reflist See also * Methyl cyanoacrylate * Ethyl cyanoacrylate * Butyl cyanoacrylate ''n''-Butyl cyanoacr ...
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Harry Coover
Harry Wesley Coover Jr. (March 6, 1917 – March 26, 2011) was the inventor of Eastman 910, commonly known as Super Glue. Life and career Coover was born in Newark, Delaware. He lived in Delaware until his teen years. During this time he was hit by a train while driving which resulted in him being in a coma for about six weeks. After he recovered, Coover moved to Weedsport, New York to finish high school.Family history submitted by Dr. Dana Coover, (granddaughter) He stayed in New York and received his Bachelor of Science from Hobart College in chemistry before earning his Master of Science and Ph. D. in organic chemistry from Cornell University. His dissertation was on commercial synthesis of vitamin B6. He intended to work with vitamin B6 until WWII hit and the process he developed was taken by the military for their use. Coover worked as a chemist for Eastman Kodak from 1944–1973 and as the Vice President of research and development for the company from 1973-1984. In 1951 ...
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Loctite
Loctite is an American brand of adhesives, sealants, surface treatments, and other industrial chemicals that include acrylic, anaerobic, cyanoacrylate, epoxy, hot melt, silicone, urethane, and UV/light curing technologies. Loctite products are sold globally and are used in a variety of industrial and hobbyist applications. History In 1953, American Schwenkfelder professor Vernon K. Krieble developed anaerobic threadlocking adhesives in his basement laboratory at Trinity College in Hartford, Connecticut. Krieble’s company, American Sealants, founded the Loctite brand, which was promoted as ushering in a new era of mechanical reliability by eliminating the vibrational loosening of mechanical fasteners, a frequent cause of machine failure. In 1956, the name Loctite was chosen by Krieble’s daughter-in-law, Nancy Brayton Krieble. The Loctite sealant made its official public debut at a press conference at the University Club of New York on July 26 of that year. In 1963, ...
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Adhesive
Adhesive, also known as glue, cement, mucilage, or paste, is any non-metallic substance applied to one or both surfaces of two separate items that binds them together and resists their separation. The use of adhesives offers certain advantages over other binding techniques such as sewing, mechanical fastenings, or welding. These include the ability to bind different materials together, the more efficient distribution of stress across a joint, the cost-effectiveness of an easily mechanized process, and greater flexibility in design. Disadvantages of adhesive use include decreased stability at high temperatures, relative weakness in bonding large objects with a small bonding surface area, and greater difficulty in separating objects during testing. Adhesives are typically organized by the method of adhesion followed by ''reactive'' or ''non-reactive'', a term which refers to whether the adhesive chemically reacts in order to harden. Alternatively, they can be organized eith ...
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Toagosei
is a Japanese chemical company, producing cyanoacrylate adhesives since 1963. Other chemical products of the company include high purity gases, soda and chlorine products, and instant glue, which is sold in Japan as Aron Alpha and marketed in the United States as Krazy Glue. The company was originally named Yahagi Kogyo and was founded by Momosuke Fukuzawa in 1933 with the manufacturing of ammonium sulfate, sulfuric acid, and nitric acid Nitric acid is the inorganic compound with the formula . It is a highly corrosive mineral acid. The compound is colorless, but older samples tend to be yellow cast due to decomposition into oxides of nitrogen. Most commercially available ni ... as its products. The present company was formed when Yahagi Kogyo merged with three other chemical companies in 1944. References External links Official global website {{Authority control Mitsui Chemical companies based in Tokyo Manufacturing companies based in Tokyo Companies listed o ...
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Unilever
Unilever plc is a British multinational consumer goods company with headquarters in London, England. Unilever products include food, condiments, bottled water, baby food, soft drink, ice cream, instant coffee, cleaning agents, energy drink, toothpaste, pet food, pharmaceutical and consumer healthcare products, tea, breakfast cereals, beauty products, and personal care. Unilever is the largest producer of soap in the world and its products are available in around 190 countries. Unilever's largest brands include Lifebuoy, Dove, Sunsilk, Knorr, Lux, Sunlight, Rexona/Degree, Axe/Lynx, Ben & Jerry's, Omo/Persil, Heartbrand (Wall's) ice creams, Hellmann's and Magnum. Unilever is organised into three main divisions: Foods and Refreshments, Home Care, and Beauty & Personal Care. It has research and development facilities in China, India, the Netherlands, the United Kingdom, and the United States. Unilever was founded on 2 September 1929, by the merger of the B ...
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Hydroxide Ion
Hydroxide is a diatomic anion with chemical formula OH−. It consists of an oxygen and hydrogen atom held together by a single covalent bond, and carries a negative electric charge. It is an important but usually minor constituent of water. It functions as a base, a ligand, a nucleophile, and a catalyst. The hydroxide ion forms salts, some of which dissociate in aqueous solution, liberating solvated hydroxide ions. Sodium hydroxide is a multi-million-ton per annum commodity chemical. The corresponding electrically neutral compound HO• is the hydroxyl radical. The corresponding covalently bound group –OH of atoms is the hydroxy group. Both the hydroxide ion and hydroxy group are nucleophiles and can act as catalysts in organic chemistry. Many inorganic substances which bear the word ''hydroxide'' in their names are not ionic compounds of the hydroxide ion, but covalent compounds which contain hydroxy groups. Hydroxide ion The hydroxide ion is a natural ...
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