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Cobalt Green
Cobalt green is an ambiguous term for either of two families of green inorganic pigments. Both are obtained by doping cobalt(II) oxide into colorless host oxides. Spinel-based cobalt green Doping Co(II) into Mg(II) and Zn(II) sites of Mg2TiO4 and Zn2TiO4, respectively gives one family of cobalt greens. These materials adopt the spinel structure.Völz, Hans G. ''et al.'' "Pigments, Inorganic" in ''Ullmann's Encyclopedia of Industrial Chemistry'', 2006 Wiley-VCH, Weinheim. . Rinman's green Rinman's green, also referred to as Rinmann's green, is obtained by doping cobalt(II) oxide into zinc oxide. Sven Rinman, a Swedish chemist, discovered this compound in 1780. Zinc oxide–derived pigments have been used in many industries and processes. It is rarely used because it is a weak chromophore and relatively expensive compared to chromium(III) oxide. The structure and color of compositions Zn1−xCoxO depends on the value of x. For x ≤ 0.3, the material adopts the Wurtzite stru ...
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Pigment
A pigment is a powder used to add or alter color or change visual appearance. Pigments are completely or nearly solubility, insoluble and reactivity (chemistry), chemically unreactive in water or another medium; in contrast, dyes are colored substances which are soluble or go into solution at some stage in their use. Dyes are often organic compounds whereas pigments are often inorganic compound, inorganic. Pigments of prehistoric and historic value include ochre, charcoal, and lapis lazuli. Economic impact In 2006, around 7.4 million tons of inorganic chemistry, inorganic, organic chemistry, organic, and special pigments were marketed worldwide. According to an April 2018 report by ''Bloomberg Businessweek'', the estimated value of the pigment industry globally is $30 billion. The value of titanium dioxide – used to enhance the white brightness of many products – was placed at $13.2 billion per year, while the color Ferrari red is valued at $300 million each yea ...
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Spinel
Spinel () is the magnesium/aluminium member of the larger spinel group of minerals. It has the formula in the cubic crystal system. Its name comes from the Latin word , a diminutive form of ''spine,'' in reference to its pointed crystals. Properties Spinel crystallizes in the isometric system; common crystal forms are octahedron, octahedra, usually Crystal twinning, twinned. It has no true Cleavage (crystal), cleavage, but shows an octahedral Parting (crystal), parting and a conchoidal fracture. Its Mohs scale of mineral hardness, hardness is 8, its specific gravity is 3.5–4.1, and it is transparent to opaque with a vitreous to dull Lustre (mineralogy), luster. It may be colorless, but is usually various shades of red, lavender (color), lavender, blue, green, brown, black, or yellow. Chromium(III) causes the red color in spinel from Burma. Some spinels are among the most famous gemstones; among them are the Black Prince's Ruby and the "Timur ruby" in the British Crown Jewels ...
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Sven Rinman
Sven Rinman (23 June (N.S)/12 June (O.S) 1720 – 20 December 1792) was a Swedish chemist and mineralogist who discovered the pigment cobalt green, sometimes also called Rinman's green. He had a great influence on mining and the steel production in Sweden. Life and work Rinman was born in Uppsala on 23 June(N.S) 1720. At the age of 20 he became an intern at the Royal Bureau of Mines. In the years 1746 and 1747 Rinman visited several European countries to improve his knowledge on mining and metallurgy. After his return he became inspector in several mines and metal works. His research on mining and metallurgy had a big influence on the Swedish industry. He was elected a member of the Royal Swedish Academy of Sciences The Royal Swedish Academy of Sciences () is one of the Swedish Royal Academies, royal academies of Sweden. Founded on 2 June 1739, it is an independent, non-governmental scientific organization that takes special responsibility for promoting nat ... in 1753. H ...
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Zinc Oxide
Zinc oxide is an inorganic compound with the Chemical formula, formula . It is a white powder which is insoluble in water. ZnO is used as an additive in numerous materials and products including cosmetics, Zinc metabolism, food supplements, rubbers, plastics, ceramics, glass, cement, lubricants, paints, sunscreens, ointments, adhesives, sealants, pigments, foods, batteries, ferrites, fire retardants, semi conductors, and first-aid tapes. Although it occurs naturally as the mineral zincite, most zinc oxide is produced synthetically. History Early humans probably used zinc compounds in processed and unprocessed forms, as paint or medicinal ointment; however, their composition is uncertain. The use of ''pushpanjan'', probably zinc oxide, as a salve for eyes and open wounds is mentioned in the Indian medical text the Charaka Samhita, thought to date from 500 BC or before. Zinc oxide ointment is also mentioned by the Greek physician Dioscorides (1st century AD). Galen suggested treatin ...
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Chromium(III) Oxide
Chromium(III) oxide (or chromia) is an inorganic compound with the formula . It is one of the principal oxides of chromium and is used as a pigment. In nature, it occurs as the rare mineral eskolaite. Structure and properties has the corundum structure, consisting of a hexagonal close packed array of oxide anions with two thirds of the octahedral holes occupied by chromium. Similar to corundum, is a hard, brittle material (Mohs hardness 8 to 8.5). It is antiferromagnetic up to , the Néel temperature. It is not readily attacked by acids. Occurrence occurs naturally as the mineral eskolaite, which is found in chromium-rich tremolite skarns, metaquartzites, and chlorite veins. Eskolaite is also a rare component of chondrite meteorites. The mineral is named after Finnish geologist Pentti Eskola. Production The Parisians Pannetier and Binet first prepared the transparent hydrated form of in 1838 via a secret process, sold as a pigment. It is derived from the mineral chromi ...
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Wurtzite Structure
In crystallography, the hexagonal crystal family is one of the six crystal families, which includes two crystal systems (hexagonal and trigonal) and two lattice systems (hexagonal and rhombohedral). While commonly confused, the trigonal crystal system and the rhombohedral lattice system are not equivalent (see section crystal systems below). In particular, there are crystals that have trigonal symmetry but belong to the hexagonal lattice (such as α-quartz). The hexagonal crystal family consists of the 12 point groups such that at least one of their space groups has the hexagonal lattice as underlying lattice, and is the union of the hexagonal crystal system and the trigonal crystal system. There are 52 space groups associated with it, which are exactly those whose Bravais lattice is either hexagonal or rhombohedral. __TOC__ Lattice systems The hexagonal crystal family consists of two lattice systems: hexagonal and rhombohedral. Each lattice system consists of one Bravais lat ...
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Sodium Chloride
Sodium chloride , commonly known as Salt#Edible salt, edible salt, is an ionic compound with the chemical formula NaCl, representing a 1:1 ratio of sodium and chloride ions. It is transparent or translucent, brittle, hygroscopic, and occurs as the mineral halite. In its edible form, it is commonly used as a condiment and curing (food preservation), food preservative. Large quantities of sodium chloride are used in many industrial processes, and it is a major source of sodium and chlorine compounds used as feedstocks for further Chemical synthesis, chemical syntheses. Another major application of sodium chloride is deicing of roadways in sub-freezing weather. Uses In addition to the many familiar domestic uses of salt, more dominant applications of the approximately 250 million tonnes per year production (2008 data) include chemicals and de-icing.Westphal, Gisbert ''et al.'' (2002) "Sodium Chloride" in Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH, Weinheim . Chem ...
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Spintronic
Spintronics (a portmanteau meaning spin transport electronics), also known as spin electronics, is the study of the intrinsic spin of the electron and its associated magnetic moment, in addition to its fundamental electronic charge, in solid-state devices. The field of spintronics concerns spin-charge coupling in metallic systems; the analogous effects in insulators fall into the field of multiferroics. Spintronics fundamentally differs from traditional electronics in that, in addition to charge state, electron spins are used as a further degree of freedom, with implications in the efficiency of data storage and transfer. Spintronic systems are most often realised in dilute magnetic semiconductors (DMS) and Heusler alloys and are of particular interest in the field of quantum computing and neuromorphic computing, upon which leads to integrated research requirements around Hyperdimensional Computation. History Spintronics emerged from discoveries in the 1980s concerning spin-de ...
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Cobalt Blue
Cobalt blue is a blue pigment made by sintering cobalt(II) oxide with aluminium(III) oxide (alumina) at 1200 °C. Chemically, cobalt blue pigment is cobalt(II) oxide-aluminium oxide, or cobalt(II) aluminate, CoAl2O4. Cobalt blue is lighter and less intense than the (iron-cyanide based) pigment Prussian blue. It is extremely stable, and has historically been used as a coloring agent in ceramics (especially Chinese porcelain), jewelry, and paint. Transparent glasses are tinted with the silica-based cobalt pigment "smalt". Historical uses and production Ores containing cobalt have been used since antiquity as pigments to give a blue color to porcelain and glass. Cobalt blue in impure forms had long been used in Chinese porcelain. In 1742, Swedish chemist Georg Brandt showed that the blue color was due to a previously unidentified metal, cobalt. The first recorded use of ''cobalt blue'' as a color name in English was in 1777. It was independently discovered as an alumina ...
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List Of Inorganic Pigments
The following list includes commercially or artistically important inorganic pigments of natural and synthetic origin.. Purple pigments Aluminosilicate pigments * Ultramarine violet (): a synthetic or naturally occurring sulfur containing silicate mineral. Copper pigments * Han purple: BaCuSi2O6. Cobalt pigments * Cobalt violet (): Co3(PO4)2. Manganese pigments * Manganese violet: NH4MnP2O7 () manganic ammonium pyrophosphate. Blue pigments Aluminosilicate pigments * Ultramarine (): a synthetic or naturally occurring sulfur containing silicate mineral - (generalized formula) * Persian blue: made by grinding up the mineral Lapis lazuli. The most important mineral component of lapis lazuli is lazurite (25% to 40%), a feldspathoid silicate mineral with the formula . Cobalt pigments *Cobalt blue (): cobalt(II) aluminate. * Cerulean blue (): cobalt(II) stannate. * Cerium uranium blue Iron pigments * Prussian blue (): a synthetic inert pigment made of iron and cyanide: C18 ...
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Inorganic Pigments
An inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds⁠that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as '' inorganic chemistry''. Inorganic compounds comprise most of the Earth's crust, although the compositions of the deep mantle remain active areas of investigation. All allotropes (structurally different pure forms of an element) and some simple carbon compounds are often considered inorganic. Examples include the allotropes of carbon (graphite, diamond, buckminsterfullerene, graphene, etc.), carbon monoxide , carbon dioxide , carbides, and salts of inorganic anions such as carbonates, cyanides, cyanates, thiocyanates, isothiocyanates, etc. Many of these are normal parts of mostly organic systems, including organisms; describing a chemical as inorganic does not necessarily mean that it cannot occur within living things. History Friedrich Wöhler's conv ...
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Cobalt Compounds
Cobalt compounds are chemical compounds formed by cobalt with other elements. Inorganic compounds Halides Many halides of cobalt(II) are known: cobalt(II) fluoride (CoF2) which is a pink solid, cobalt(II) chloride (CoCl2) which is a blue solid, cobalt(II) bromide (CoBr2) which is a green solid, and cobalt(II) iodide (CoI2) which is a blue-black solid. In addition to the anhydrous forms, these cobalt halides also have hydrates. Anhydrous cobalt(II) chloride is blue, while the hexahydrate is magenta in colour. Because cobalt(II) chloride changes color upon Mineral hydration, hydration, it can be used to manufacture color-changing silica gel. Anhydrous cobalt halides react with nitric oxide at 70~120 °C to generate [Co(NO)2X]2 (X = Cl, Br or I). The complex of cobalt halides and triethylphosphine ((C2H5)3P) can absorb nitric monoxide in benzene to form the diamagnetic material Co(NO)X2(P(C2H5)3)申泮文 等. 无机化学丛书 第九卷 锰分族 铁系 铂系. 科学� ...
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