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Caput Mortuum (pigment)
Caput mortuum (, and variously spelled caput mortum or caput mortem), also known as cardinal purple, is the name given to a purple variety of hematite iron oxide pigment, used in oil paints and paper dyes. Due to the cultural significance of its deep purple colour, it was very popular for painting the robes of religious figures and important personages (e.g. art patrons), with its popularity peaking in the 18th and 19th centuries. The name for this pigment may have come from the alchemical usage, since iron oxide (rust) is the useless residue ('' caput mortuum'') of oxidization. It was originally a byproduct of sulfuric acid manufacture during the 17th and 18th centuries, and was possibly an early form of the copperas Iron(II) sulfate or ferrous sulfate (British English: sulphate instead of sulfate) denotes a range of salts with the formula Fe SO4·''x''H2O. These compounds exist most commonly as the heptahydrate (''x'' = 7), but several values for ... process ...
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Ferric Oxide
Iron(III) oxide or ferric oxide is the inorganic compound with the formula . It occurs in nature as the mineral hematite, which serves as the primary source of iron for the steel industry. It is also known as red iron oxide, especially when used in pigments. It is one of the three main oxides of iron, the other two being iron(II) oxide (FeO), which is rare; and iron(II,III) oxide (), which also occurs naturally as the mineral magnetite. Iron(III) oxide is often called rust, since rust shares several properties and has a similar composition; however, in chemistry, rust is considered an ill-defined material, described as hydrous ferric oxide. Ferric oxide is readily attacked by even weak acids. It is a weak oxidising agent, most famously when reduced by aluminium in the thermite reaction. Structure can be obtained in various polymorphs. In the primary polymorph, α, iron adopts octahedral coordination geometry. That is, each Fe center is bound to six oxygen ligands. In ...
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Hematite
Hematite (), also spelled as haematite, is a common iron oxide compound with the formula, Fe2O3 and is widely found in rocks and soils. Hematite crystals belong to the rhombohedral lattice system which is designated the alpha polymorph of . It has the same crystal structure as corundum () and ilmenite (). With this it forms a complete solid solution at temperatures above . Hematite occurs naturally in black to steel or silver-gray, brown to reddish-brown, or red colors. It is mined as an important ore mineral of iron. It is electrically conductive. Hematite varieties include ''kidney ore'', ''martite'' ( pseudomorphs after magnetite), ''iron rose'' and ''specularite'' ( specular hematite). While these forms vary, they all have a rust-red streak. Hematite is not only harder than pure iron, but also much more brittle. The term ''kidney ore'' may be broadly used to describe botryoidal, mammillary, or reniform hematite. Maghemite is a polymorph of hematite (γ-) with the ...
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Iron Oxide
An iron oxide is a chemical compound composed of iron and oxygen. Several iron oxides are recognized. Often they are non-stoichiometric. Ferric oxyhydroxides are a related class of compounds, perhaps the best known of which is rust. Iron oxides and oxyhydroxides are widespread in nature and play an important role in many geological and biological processes. They are used as iron ores, pigments, catalysts, and in thermite, and occur in hemoglobin. Iron oxides are inexpensive and durable pigments in paints, coatings and colored concretes. Colors commonly available are in the " earthy" end of the yellow/orange/red/brown/black range. When used as a food coloring, it has E number E172. Stoichiometries Iron oxides feature as ferrous ( Fe(II)) or ferric ( Fe(III)) or both. They adopt octahedral or tetrahedral coordination geometry. Only a few oxides are significant at the earth's surface, particularly wüstite, magnetite, and hematite. * Oxides of FeII ** FeO: ir ...
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Oil Painting
Oil painting is a painting method involving the procedure of painting with pigments combined with a drying oil as the Binder (material), binder. It has been the most common technique for artistic painting on canvas, wood panel, or oil on copper, copper for several centuries. The advantages of oil for painting images include "greater flexibility, richer and denser color, the use of layers, and a wider range from light to dark". The oldest known oil paintings were created by Buddhism, Buddhist artists in Afghanistan, and date back to the 7th century AD. Oil paint was later developed by Europeans for painting statues and woodwork from at least the 12th century, but its common use for painted images began with Early Netherlandish painting in Northern Europe, and by the height of the Renaissance, oil painting techniques had almost completely replaced the use of egg tempera paints for panel paintings in most of Europe, though not for Orthodox icons or wall paintings, where tempera a ...
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Caput Mortuum
''Caput mortuum'' (plural ''capita mortua''; literally "dead head") is a Latin term used in alchemy to signify a useless substance left over from a chemical operation such as sublimation and the epitome of decline and decay (alternatively called '' nigredo''). Alchemists represented this residue with a stylized human skull, a literal death's head. The symbol shown on this page was also used in 18th-century chemistry to mean ''residue'', ''remainder'', or ''residuum''. ''Caput mortuum'' was also sometimes used to mean ''crocus metallorum'', i.e. brownish-red metallic compounds such as ''crocus martis'' (ferrous sulfate Iron(II) sulfate or ferrous sulfate (British English: sulphate instead of sulfate) denotes a range of salts with the formula Fe SO4·''x''H2O. These compounds exist most commonly as the heptahydrate (''x'' = 7), but several values for ...), and ''crocus veneris'' . References {{reflist Alchemical substances Latin words and phrases ...
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Sulfuric Acid
Sulfuric acid (American spelling and the preferred IUPAC name) or sulphuric acid (English in the Commonwealth of Nations, Commonwealth spelling), known in antiquity as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen, and hydrogen, with the molecular formula . It is a colorless, odorless, and Viscosity, viscous liquid that is Miscibility, miscible with water. Pure sulfuric acid does not occur naturally due to its Dehydration reaction, strong affinity to water vapor; it is Hygroscopy, hygroscopic and readily absorbs water vapor from the Atmosphere of Earth, air. Concentrated sulfuric acid is a strong oxidant with powerful dehydrating properties, making it highly corrosive towards other materials, from rocks to metals. Phosphorus pentoxide is a notable exception in that it is not dehydrated by sulfuric acid but, to the contrary, dehydrates sulfuric acid to sulfur trioxide. Upon addition of sulfuric acid to water, a considerable amount of heat is releas ...
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Copperas
Iron(II) sulfate or ferrous sulfate (British English: sulphate instead of sulfate) denotes a range of salts with the formula Fe SO4·''x''H2O. These compounds exist most commonly as the heptahydrate (''x'' = 7), but several values for x are known. The hydrated form is used medically to treat or prevent iron deficiency, and also for industrial applications. Known since ancient times as copperas and as green vitriol ( vitriol is an archaic name for hydrated sulfate minerals), the blue-green heptahydrate (hydrate with 7 molecules of water) is the most common form of this material. All the iron(II) sulfates dissolve in water to give the same aquo complex e(H2O)6sup>2+, which has octahedral molecular geometry and is paramagnetic. The name copperas dates from times when the copper(II) sulfate was known as blue copperas, and perhaps in analogy, iron(II) and zinc sulfate were known respectively as green and white copperas. It is on the World Health Organization's List of ...
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Venetian Red
Venetian red is a light and warm (somewhat unsaturated) pigment that is a darker shade of red. The composition of Venetian red changed over time. Originally it consisted of natural ferric oxide (Fe2O3, partially hydrated) obtained from the red hematite. Modern versions are frequently made with synthetic red iron oxide produced via calcination of green vitriol (a.k.a. copperas) mixed with white chalk. The pigment contains up to 50% of the ferric oxide. Historically, Venetian red was a red earth color often used in Italian Renaissance paintings. It was also called sinopia because the best-quality pigment came from the port of Sinop in northern Turkey. It was the major ingredient in the pigment called ', described by the 15th-century Italian painter and writer Cennino Cennini Cennino d'Andrea Cennini (; – before 1427) was an Italian painter influenced by Giotto. He was a student of Agnolo Gaddi in Florence. Gaddi trained under his father, called Taddeo Gaddi, who tra ...
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Copperas Red
Iron(II) sulfate or ferrous sulfate (British English: sulphate instead of sulfate) denotes a range of salts with the formula Fe SO4·''x''H2O. These compounds exist most commonly as the heptahydrate (''x'' = 7), but several values for x are known. The hydrated form is used medically to treat or prevent iron deficiency, and also for industrial applications. Known since ancient times as copperas and as green vitriol (vitriol is an archaic name for hydrated sulfate minerals), the blue-green heptahydrate (hydrate with 7 molecules of water) is the most common form of this material. All the iron(II) sulfates dissolve in water to give the same aquo complex e(H2O)6sup>2+, which has octahedral molecular geometry and is paramagnetic. The name copperas dates from times when the copper(II) sulfate was known as blue copperas, and perhaps in analogy, iron(II) and zinc sulfate were known respectively as green and white copperas. It is on the World Health Organization's List of Esse ...
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Pigments
A pigment is a powder used to add or alter color or change visual appearance. Pigments are completely or nearly solubility, insoluble and reactivity (chemistry), chemically unreactive in water or another medium; in contrast, dyes are colored substances which are soluble or go into solution at some stage in their use. Dyes are often organic compounds whereas pigments are often inorganic compound, inorganic. Pigments of prehistoric and historic value include ochre, charcoal, and lapis lazuli. Economic impact In 2006, around 7.4 million tons of inorganic chemistry, inorganic, organic chemistry, organic, and special pigments were marketed worldwide. According to an April 2018 report by ''Bloomberg Businessweek'', the estimated value of the pigment industry globally is $30 billion. The value of titanium dioxide – used to enhance the white brightness of many products – was placed at $13.2 billion per year, while the color Ferrari red is valued at $300 million each yea ...
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Organic Pigments
Organic may refer to: * Organic, of or relating to an organism, a living entity * Organic, of or relating to an anatomical organ Chemistry * Organic matter, matter that has come from a once-living organism, is capable of decay or is the product of decay, or is composed of organic compounds * Organic compound, a compound that contains carbon ** Organic chemistry, chemistry involving organic compounds Farming, certification and products * Organic farming, agriculture conducted according to certain standards, especially the use of stated methods of fertilization and pest control * Organic certification, accreditation process for producers of organically-farmed products * Organic horticulture, the science and art of growing fruits, vegetables, flowers, or ornamental plants by following the essential principles of organic agriculture * Organic products, "organics": ** Organic food, food produced from organic farming methods and often certified organic according to organic farming stan ...
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