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Zel'dovich Number
The Zeldovich number is a dimensionless number which provides a quantitative measure for the activation energy of a chemical reaction which appears in the Arrhenius exponent, named after the Russian scientist Yakov Borisovich Zeldovich, who along with David A. Frank-Kamenetskii, first introduced in their paper in 1938. In 1983 ICDERS meeting at Poitiers, it was decided that the non-dimensional number will be named after Zeldovich.Clavin, P. (1985). Dynamic behavior of premixed flame fronts in laminar and turbulent flows. Progress in energy and combustion science, 11(1), 1-59. It is defined as :\beta = \frac \cdot \frac where *E_a is the activation energy of the reaction *R is the universal gas constant *T_b is the burnt gas temperature *T_u is the unburnt mixture temperature. In terms of heat release parameter q, it is given by :\beta = \frac \frac For typical combustion phenomena, the value for Zel'dovich number lies in the range \beta\approx 8-20. Activation energy asym ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Dimensionless Number
Dimensionless quantities, or quantities of dimension one, are quantities implicitly defined in a manner that prevents their aggregation into unit of measurement, units of measurement. ISBN 978-92-822-2272-0. Typically expressed as ratios that align with another system, these quantities do not necessitate explicitly defined Unit of measurement, units. For instance, alcohol by volume (ABV) represents a volumetric ratio; its value remains independent of the specific Unit of volume, units of volume used, such as in milliliters per milliliter (mL/mL). The 1, number one is recognized as a dimensionless Base unit of measurement, base quantity. Radians serve as dimensionless units for Angle, angular measurements, derived from the universal ratio of 2π times the radius of a circle being equal to its circumference. Dimensionless quantities play a crucial role serving as parameters in differential equations in various technical disciplines. In calculus, concepts like the unitless ratios ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Universal Gas Constant
The molar gas constant (also known as the gas constant, universal gas constant, or ideal gas constant) is denoted by the symbol or . It is the molar equivalent to the Boltzmann constant, expressed in units of energy per temperature, temperature increment per amount of substance, rather than energy per temperature increment per ''particle''. The constant is also a combination of the constants from Boyle's law, Charles's law, Avogadro's law, and Gay-Lussac's law. It is a physical constant that is featured in many fundamental equations in the physical sciences, such as the ideal gas law, the Arrhenius equation, and the Nernst equation. The gas constant is the constant of proportionality that relates the energy scale in physics to the temperature scale and the scale used for amount of substance. Thus, the value of the gas constant ultimately derives from historical decisions and accidents in the setting of units of energy, temperature and amount of substance. The Boltzmann constan ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Dimensionless Numbers Of Fluid Mechanics
Dimensionless quantities, or quantities of dimension one, are quantities implicitly defined in a manner that prevents their aggregation into unit of measurement, units of measurement. ISBN 978-92-822-2272-0. Typically expressed as ratios that align with another system, these quantities do not necessitate explicitly defined Unit of measurement, units. For instance, alcohol by volume (ABV) represents a volumetric ratio; its value remains independent of the specific Unit of volume, units of volume used, such as in milliliters per milliliter (mL/mL). The 1, number one is recognized as a dimensionless Base unit of measurement, base quantity. Radians serve as dimensionless units for Angle, angular measurements, derived from the universal ratio of 2π times the radius of a circle being equal to its circumference. Dimensionless quantities play a crucial role serving as parameters in differential equations in various technical disciplines. In calculus, concepts like the unitless ratios ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Combustion
Combustion, or burning, is a high-temperature exothermic redox chemical reaction between a fuel (the reductant) and an oxidant, usually atmospheric oxygen, that produces oxidized, often gaseous products, in a mixture termed as smoke. Combustion does not always result in fire, because a flame is only visible when substances undergoing combustion vaporize, but when it does, a flame is a characteristic indicator of the reaction. While activation energy must be supplied to initiate combustion (e.g., using a lit match to light a fire), the heat from a flame may provide enough energy to make the reaction self-sustaining. The study of combustion is known as combustion science. Combustion is often a complicated sequence of elementary reaction, elementary Radical (chemistry), radical reactions. Solid fuels, such as wood and coal, first undergo endothermic pyrolysis to produce gaseous fuels whose combustion then supplies the heat required to produce more of them. Combustion is often hot e ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chemical Kinetics
Chemical kinetics, also known as reaction kinetics, is the branch of physical chemistry that is concerned with understanding the rates of chemical reactions. It is different from chemical thermodynamics, which deals with the direction in which a reaction occurs but in itself tells nothing about its rate. Chemical kinetics includes investigations of how experimental conditions influence the speed of a chemical reaction and yield information about the reaction's mechanism and transition states, as well as the construction of mathematical models that also can describe the characteristics of a chemical reaction. History The pioneering work of chemical kinetics was done by German chemist Ludwig Wilhelmy in 1850. He experimentally studied the rate of inversion of sucrose and he used integrated rate law for the determination of the reaction kinetics of this reaction. His work was noticed 34 years later by Wilhelm Ostwald. In 1864, Peter Waage and Cato Guldberg published the law ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Activation Energy Asymptotics
Activation energy asymptotics (AEA), also known as large activation energy asymptotics, is an asymptotic analysis used in the combustion field utilizing the fact that the reaction rate is extremely sensitive to temperature changes due to the large activation energy of the chemical reaction. History The techniques were pioneered by the Russian scientists Yakov Borisovich Zel'dovich, David A. Frank-Kamenetskii and co-workers in the 30s, in their study on premixed flames and thermal explosions ( Frank-Kamenetskii theory), but not popular to western scientists until the 70s. In the early 70s, due to the pioneering work of Williams B. Bush, Francis E. Fendell, Forman A. Williams, Amable Liñán and John F. Clarke, it became popular in western community and since then it was widely used to explain more complicated problems in combustion. Method overview In combustion processes, the reaction rate \omega is dependent on temperature T in the following form ( Arrhenius law), :\omega(T) ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Combustion
Combustion, or burning, is a high-temperature exothermic redox chemical reaction between a fuel (the reductant) and an oxidant, usually atmospheric oxygen, that produces oxidized, often gaseous products, in a mixture termed as smoke. Combustion does not always result in fire, because a flame is only visible when substances undergoing combustion vaporize, but when it does, a flame is a characteristic indicator of the reaction. While activation energy must be supplied to initiate combustion (e.g., using a lit match to light a fire), the heat from a flame may provide enough energy to make the reaction self-sustaining. The study of combustion is known as combustion science. Combustion is often a complicated sequence of elementary reaction, elementary Radical (chemistry), radical reactions. Solid fuels, such as wood and coal, first undergo endothermic pyrolysis to produce gaseous fuels whose combustion then supplies the heat required to produce more of them. Combustion is often hot e ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Heat Release Parameter
In combustion, heat release parameter (or gas expansion parameter) is a dimensionless parameter which measures the amount of heat released by an adiabatic combustion process. It is defined as :q = \frac where *T_ is the adiabatic flame temperature *T_u is the unburnt mixture temperature. In typical combustion process, q\approx 2-7. For isobaric combustion, using ideal gas law, the parameter can be expressed in terms of density Density (volumetric mass density or specific mass) is the ratio of a substance's mass to its volume. The symbol most often used for density is ''ρ'' (the lower case Greek letter rho), although the Latin letter ''D'' (or ''d'') can also be u ...,Clavin, P. (1985). Dynamic behavior of premixed flame fronts in laminar and turbulent flows. Progress in energy and combustion science, 11(1), 1-59. i.e., :q = \frac = \frac. The ratio of burnt gas to unburnt gas temperature is :\frac =1+q. Gas expansion ratio The gas expansion ratio is simply defined by ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Poitiers
Poitiers is a city on the river Clain in west-central France. It is a commune in France, commune, the capital of the Vienne (department), Vienne department and the historical center of Poitou, Poitou Province. In 2021, it had a population of 90,240. Its conurbation had 134,397 inhabitants in 2021 and is the municipal center of an urban area of 281,789 inhabitants. It is a city of art and history, still known popularly as "Ville aux cent clochers" (literal translation: "City of hundred bell towers"). With more than 30,000 students, Poitiers has been a major university town since the creation of its University of Poitiers, university in 1431, having hosted world-renowned figures and thinkers such as René Descartes, Joachim du Bellay and François Rabelais, among others. The plaza of the town is picturesque; its streets including predominantly preserved historical architecture and half-timbered houses, especially religious edifices, commonly from the Romanesque architecture, Roma ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Activation Energy
In the Arrhenius model of reaction rates, activation energy is the minimum amount of energy that must be available to reactants for a chemical reaction to occur. The activation energy (''E''a) of a reaction is measured in kilojoules per mole (kJ/mol) or kilocalories per mole (kcal/mol). Activation energy can be thought of as a magnitude of the potential barrier (sometimes called the energy barrier) separating minima of the potential energy surface pertaining to the initial and final thermodynamic state. For a chemical reaction to proceed at a reasonable rate, the temperature of the system should be high enough such that there exists an appreciable number of molecules with translational energy equal to or greater than the activation energy. The term "activation energy" was introduced in 1889 by the Swedish scientist Svante Arrhenius. Other uses Although less commonly used, activation energy also applies to nuclear reactions and various other physical phenomena. Temperature ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
David A
David (; , "beloved one") was a king of ancient Israel and Judah and the third king of the United Monarchy, according to the Hebrew Bible and Old Testament. The Tel Dan stele, an Aramaic-inscribed stone erected by a king of Aram-Damascus in the late 9th/early 8th centuries BCE to commemorate a victory over two enemy kings, contains the phrase (), which is translated as " House of David" by most scholars. The Mesha Stele, erected by King Mesha of Moab in the 9th century BCE, may also refer to the "House of David", although this is disputed. According to Jewish works such as the '' Seder Olam Rabbah'', '' Seder Olam Zutta'', and '' Sefer ha-Qabbalah'' (all written over a thousand years later), David ascended the throne as the king of Judah in 885 BCE. Apart from this, all that is known of David comes from biblical literature, the historicity of which has been extensively challenged,Writing and Rewriting the Story of Solomon in Ancient Israel; by Isaac Kalimi; page 3 ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Yakov Borisovich Zeldovich
Yakov Borisovich Zeldovich (, ; 8 March 1914 – 2 December 1987), also known as YaB, was a leading Soviet physicist of Belarusian origin, who is known for his prolific contributions in physical cosmology, physics of thermonuclear reactions, combustion, and hydrodynamical phenomena. From 1943, Zeldovich, a self-taught physicist, started his career by playing a crucial role in the development of the former Soviet program of nuclear weapons. In 1963, he returned to academia to embark on pioneering contributions on the fundamental understanding of the thermodynamics of black holes and expanding the scope of physical cosmology. Biography Early life and education Yakov Zeldovich was born into a Belarusian Jewish family in his grandfather's house in Minsk. However, in mid-1914, the Zeldovich family moved to Saint Petersburg. They resided there until August 1941, when the family was evacuated together with the faculty of the Institute of Chemical Physics to Kazan to avoid the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
