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Water-gas Shift Reaction
Water gas is a kind of fuel gas, a mixture of carbon monoxide and hydrogen. It is produced by "alternately hot blowing a fuel layer okewith air and gasifying it with steam". The caloric yield of the fuel produced by this method is about 10% of the yield from a modern syngas plant. The coke needed to produce water gas also costs significantly more than the precursors for syngas (mainly methane from natural gas), making water gas technology an even less attractive business proposition. Production Synthesis gas is made by passing steam over a red-hot carbon fuel such as coke: : (Δ''H'' = +131 kJ/mol) The reaction is endothermic, so the fuel must be continually re-heated to maintain the reaction. To do this, an air stream, which alternates with the vapor stream, is introduced to combust some of the carbon: : (Δ''H'' = −393 kJ/mol) Theoretically, to make 6 L of water gas, 5 L of air is required. Alternatively, to prevent contamination with nitrogen, energy can be p ...
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Fuel Gas
Fuel gas is one of a number of fuels that under ordinary conditions are gaseous. Most fuel gases are composed of hydrocarbons (such as methane and propane), hydrogen, carbon monoxide, or mixtures thereof. Such gases are sources of energy that can be readily transmitted and distributed through pipes. Fuel gas is contrasted with liquid fuels and solid fuels, although some fuel gases are Liquefaction of gases, liquefied for storage or transport (for example, autogas and Liquefied petroleum gas, liquified petroleum gas). While their gaseous nature has advantages, avoiding the difficulty of transporting solid fuel and the dangers of spillage inherent in liquid fuels, it also has limitations. It is possible for a fuel gas to be undetected and cause a gas explosion. For this reason, odorizers are added to most fuel gases. The most common type of fuel gas in current use is natural gas. Types of fuel gas There are two broad classes of fuel gases, based not on their chemical composition ...
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Pneumatic Institution
The Pneumatic Institution (also referred to as Pneumatic Institute) was a medical research facility in Bristol, England, in 1799–1802. It was established by physician and science writer Thomas Beddoes to study the medical effects of gases, known as factitious airs, that had recently been discovered. Humphry Davy headed the Institution's laboratory, examining the effects of laughing gas on himself and others, and James Watt designed much of the lab's equipment. History Preliminaries After Lavoisier had established the role of oxygen in animal respiration, members of the Lunar Society, such as Joseph Priestley (who had co-discovered oxygen), originated pneumatic chemistry, which eventually led to the establishment of the Pneumatic Institution. Georgiana, Duchess of Devonshire, who was unusually educated about Chemistry, visited Thomas Beddoes in his laboratory in Hope Square, Bristol, in December 1793. He had set it up earlier that year to study possible medical uses of the ...
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Thaddeus S
Thaddeus (, , from ) is a masculine given name. As of the 1990 Census, ''Thaddeus'' was the 611th most popular male name in the United States, while '' Thad'', its diminutive version, was the 846th. Alternate forms * Taco – Dutch * Tadeu ( ind. Tade) – Albanian * Թադէոս ("Tadeos"), Թադևոս ("Tadevos"), Թաթոս ("Tatos") – Armenian * Tadija – Croatian * Tadeáš – Czech * Thaddée – French * თადეოზი (''tadeozi'') Georgian * Thaddäus – German * Tádé – Hungarian * Tadáias (Biblical), Tadhg (given name) – Irish * Taddeo – Italian * Taddeus (Biblical; old translation), Taday (modern translation) – Turkish * Tadejs – Latvian * Tadas – Lithuanian * Тадеј (Tadej) - Macedonian * Thadhewoos – Malayalam * Tadeusz – Polish * Tadeu – Portuguese * Тадэвуш ("Tadevush") – Belarusian * Фаддей ("Faddey") or Фадей ("Fadey") – Russian * Тадей ("Тadey") – Ukrainian * Тадеј (Tadej) ...
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Claude Bernard
Claude Bernard (; 12 July 1813 – 10 February 1878) was a French physiologist. I. Bernard Cohen of Harvard University called Bernard "one of the greatest of all men of science". He originated the term ''milieu intérieur'' and the associated concept of homeostasis (the latter term being coined by Walter Cannon). Life Bernard was born in 12 July 1813 in the village of Saint-Julien, near Villefranche-sur-Saône. He received his early education in the Jesuit school of that town, then attended college at Lyon, which he soon left to become assistant in a druggist's shop. He is sometimes described as an agnostic, and even humorously referred to by his colleagues as a "great priest of atheism". Despite this, after his death Cardinal Ferdinand Donnet claimed Bernard was a fervent Catholic, with a biographical entry in the ''Catholic Encyclopedia''. His leisure hours were devoted to the composition of a vaudeville comedy, and the success it achieved moved him to attempt a prose dra ...
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Carbon Monoxide-releasing Molecules
Carbon monoxide-releasing molecules (CORMs) are chemical compounds designed to release controlled amounts of carbon monoxide (CO). CORMs are being developed as potential therapeutic agents to locally deliver CO to cells and tissues, thus overcoming limitations of CO gas inhalation protocols. CO is best known for its toxicity in carbon monoxide poisoning at high doses. However, CO is a gasotransmitter and supplemental low dosage of CO has been linked to therapeutic benefits. Pre-clinical research has focused on CO's anti-inflammatory activity with significant applications in cardiovascular disease, oncology, transplant surgery, and neuroprotection. History Therapeutic interest in CO dates back to the study of factitious airs ( hydrocarbonate) in the 1790s by Thomas Beddoes, James Watt, James Lind, Humphry Davy, Tiberius Cavallo and many others. Nickel tetracarbonyl was the first carbonyl-complex used to achieve local delivery of CO and was the first CO delivery molecule sugges ...
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James Lind (physician, Born 1736)
James Lind Royal Society of London, FRS FRSE FRCPE (May 17, 1736 – October 17, 1812) was a Scottish natural philosopher and physician. Life James Lind was born in Gorgie, Edinburgh on 17 May 1736. He studied medicine at Edinburgh University under William Cullen and Joseph Black, and graduated in 1768. In 1766, he then joined the East India Company as surgeon. In 1768 he received his doctorate (MD) from Edinburgh upon completing a dissertation on marsh fever (malaria) in Bengal. On 6 November 1770 he was admitted a Fellow of the College of Physicians, Edinburgh, College of Physicians, Edinburgh. In 1773 he was a founding member of the Aesculapian Club. Lind was also a corresponding member of the Lunar Society of Birmingham, Lunar Society. Personality Lind is widely regarded as having an eccentric personality, and considered to be reckless with spending money as captured by the following dialogue: "Why, Dr. Lind, you spend a whole seas of gold", to which Lind replied, "Madam ...
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Spasm
A spasm is a sudden involuntary contraction of a muscle, a group of muscles, or a hollow organ, such as the bladder. A spasmodic muscle contraction may be caused by many medical conditions, including dystonia. Most commonly, it is a muscle cramp which is accompanied by a sudden burst of pain. A muscle cramp is usually harmless and ceases after a few minutes. It is typically caused by ion imbalance or muscle fatigue. There are other causes of involuntary muscle contractions, and some of these may cause a health problem. A series of spasms, or permanent spasms, is referred to as a "spasmism". Description and causes Spasms occur when the part of the brain that controls movement malfunctions, causing involuntary muscle activity. A spasm may be a muscle contraction caused by abnormal nerve stimulation or by abnormal activity of the muscle itself. Causes The cause of spasms is often unknown, but it can be due to an inherited genetic problem, a side effect of medicatio ...
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Hydrothorax
Hydrothorax is the synonym of pleural effusion in which fluid accumulates in the pleural cavity. This condition is most likely to develop secondary to congestive heart failure, following an increase in hydrostatic pressure within the lungs. More rarely, hydrothorax can develop in 10% of patients with ascites which is called hepatic hydrothorax. It is often difficult to manage in end-stage liver failure and often fails to respond to therapy. Pleural effusions may also develop following the accumulation of other fluids within the pleural cavity; if the fluid is blood it is known as hemothorax (as in major chest injuries), if the fluid is pus it is known as pyothorax (resulting from chest infections), and if the fluid is lymph it is known as chylothorax (resulting from rupture of the thoracic duct). Treatment Treatment of hydrothorax is difficult for several reasons. The underlying condition needs to be corrected; however, often the source of the hydrothorax is end stage liver di ...
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Pneumonia
Pneumonia is an Inflammation, inflammatory condition of the lung primarily affecting the small air sacs known as Pulmonary alveolus, alveoli. Symptoms typically include some combination of Cough#Classification, productive or dry cough, chest pain, fever, and Shortness of breath, difficulty breathing. The severity of the condition is variable. Pneumonia is usually caused by infection with viruses or bacteria, and less commonly by other microorganisms. Identifying the responsible pathogen can be difficult. Diagnosis is often based on symptoms and physical examination. Chest X-rays, blood tests, and Microbiological culture, culture of the sputum may help confirm the diagnosis. The disease may be classified by where it was acquired, such as community- or hospital-acquired or healthcare-associated pneumonia. Risk factors for pneumonia include cystic fibrosis, chronic obstructive pulmonary disease (COPD), sickle cell disease, asthma, diabetes, heart failure, a history of smoking, ...
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Hemoptysis
Hemoptysis or haemoptysis is the discharge of blood or blood-stained sputum, mucus through the mouth coming from the bronchi, larynx, vertebrate trachea, trachea, or lungs. It does not necessarily involve coughing. In other words, it is the airway bleeding. This can occur with lung cancer, infections such as tuberculosis, bronchitis, or pneumonia, and certain cardiovascular conditions. Hemoptysis is considered massive at . In such cases, there are always severe injuries. The primary danger comes from choking, rather than bleeding, blood loss. Diagnosis * Past history, history of present illness, family history ** history of tuberculosis, bronchiectasis, chronic bronchitis, mitral stenosis, etc. ** history of cigarette smoking, occupational diseases by exposure to silica dust, etc. * Blood ** duration, frequency, amount ** Amounts of blood: large amounts of blood, or there is blood-streaked sputum ** Probable source of bleeding: Is the blood coughed up, or vomited? * Bloody sput ...
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Expectoration
Sputum is mucus that is coughed up from the lower airways (the trachea and bronchi). In medicine, sputum samples are usually used for a naked-eye examination, microbiological investigation of respiratory infections, and cytological investigations of respiratory system. A naked eye exam of the sputum can be done at home by a patient in order to note the various colors (see below). Any hint of yellow or green color (pus) suggests an airway infection (but does not indicate the type of organism causing it). Such color hints are best detected when the sputum is viewed against a bright white background, such as white paper, a white pot, or a white sink surface. Having green, yellow, or thickened phlegm (sputum) does not always indicate the presence of an infection. Also, if an infection is present, the color of the phlegm (sputum) does not determine whether a virus, a bacterium or another pathogen has caused it. Simple allergies can also cause changes in the color of mucus. Descript ...
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Asthma
Asthma is a common long-term inflammatory disease of the airways of the lungs. It is characterized by variable and recurring symptoms, reversible airflow obstruction, and easily triggered bronchospasms. Symptoms include episodes of wheezing, coughing, chest tightness, and shortness of breath. A sudden worsening of asthma symptoms sometimes called an 'asthma attack' or an 'asthma exacerbation' can occur when allergens, pollen, dust, or other particles, are inhaled into the lungs, causing the bronchioles to constrict and produce mucus, which then restricts oxygen flow to the alveoli. These may occur a few times a day or a few times per week. Depending on the person, asthma symptoms may become worse at night or with exercise. Asthma is thought to be caused by a combination of genetic and environmental factors. Environmental factors include exposure to air pollution and allergens. Other potential triggers include medications such as aspirin and beta blockers. Diag ...
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