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Tutton's Salt
Tutton's salts are a family of salts with the formula M2M'(SO4)2(H2O)6 (sulfates) or M2M'(SeO4)2(H2O)6 (selenates). These materials are double salts, which means that they contain two different cations, M+ and M'2+ crystallized in the same regular ionic lattice. The univalent cation can be potassium, rubidium, cesium, ammonium (NH4), deuterated ammonium (ND4) or thallium. Sodium or lithium ions are too small. The divalent cation can be magnesium, vanadium, chromium, manganese, iron, cobalt, nickel, copper, zinc or cadmium. In addition to sulfate and selenate, the divalent anion can be chromate (CrO42−), tetrafluoroberyllate (BeF42−), hydrogenphosphate (HPO42−) or monofluorophosphate (PO3F2−). Tutton's salts crystallize in the monoclinic space group ''P''21/''a''. The robustness is the result of the complementary hydrogen-bonding between the tetrahedral anions and cations as well their interactions with the metal aquo complex (H2O)6sup>2+. Examples and related compou ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chemical Formula
In chemistry, a chemical formula is a way of presenting information about the chemical proportions of atoms that constitute a particular chemical compound or molecule, using chemical element symbols, numbers, and sometimes also other symbols, such as parentheses, dashes, brackets, commas and ''plus'' (+) and ''minus'' (−) signs. These are limited to a single typographic line of symbols, which may include subscripts and superscripts. A chemical formula is not a chemical name, and it contains no words. Although a chemical formula may imply certain simple chemical structures, it is not the same as a full chemical structural formula. Chemical formulae can fully specify the structure of only the simplest of molecules and chemical substances, and are generally more limited in power than chemical names and structural formulae. The simplest types of chemical formulae are called ''empirical formulae'', which use letters and numbers indicating the numerical ''proportions'' of ato ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hydrogen Bond
In chemistry, a hydrogen bond (or H-bond) is a primarily electrostatic force of attraction between a hydrogen (H) atom which is covalently bound to a more electronegative "donor" atom or group (Dn), and another electronegative atom bearing a lone pair of electrons—the hydrogen bond acceptor (Ac). Such an interacting system is generally denoted , where the solid line denotes a polar covalent bond, and the dotted or dashed line indicates the hydrogen bond. The most frequent donor and acceptor atoms are the second-row elements nitrogen (N), oxygen (O), and fluorine (F). Hydrogen bonds can be intermolecular (occurring between separate molecules) or intramolecular (occurring among parts of the same molecule). The energy of a hydrogen bond depends on the geometry, the environment, and the nature of the specific donor and acceptor atoms and can vary between 1 and 40 kcal/mol. This makes them somewhat stronger than a van der Waals interaction, and weaker than fully covalent o ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Boussingaultite
Boussingaultite is a rare ammonium magnesium hydrated sulfate mineral of the chemical formula: (NH4)2Mg(SO4)2 · 6 H2O. The formula of boussingaultite is that of Tutton's salts type. It was originally described from geothermal fields in Tuscany, Italy, where it occurs together with its iron analogue mohrite, but is more commonly found on burning coal dumps. The mineral possess monoclinic symmetry and forms clear, often rounded crystals. The mineral is named after the French chemist Jean-Baptiste Boussingault (1802–1887). See also * Mohr's salt Ammonium iron(II) sulfate, or Mohr's salt, is the inorganic compound with the formula (NH4)2Fe(SO4)2(H2O)6. Containing two different cations, Fe2+ and NH4+, it is classified as a double salt of ferrous sulfate and ammonium sulfate. It is a commo ... * Mohrite References Ammonium minerals Magnesium minerals Sulfate minerals Hydrates Monoclinic minerals Minerals in space group 14 {{sulfate-mineral-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Picromerite
Picromerite (synonyms: schoenite, schönite) is a mineral from the class of hydrous sulfates lacking additional anions, and containing medium to large cations according to the Nickel–Strunz classification. Etymology The name comes from the Greek words πικρός ikrosfor "bitter" and μέρος eros for "part", and relates to the bitter taste of the mineral. Occurrence Picromerite is found on comparatively few places, currently (2015) only about 40 localities are known. It was first identified in active volcanic fumaroles on Mount Vesuvius by Arcangelo Scacchi in 1855 and has also been found in volcanic deposits on Mount Etna and on Hawai'i. It is more commonly found in the kainite zones of some marine salt deposits, among them salt mines in Thuringia, Lower Saxony and Saxony-Anhalt (Germany), near Hall in Tirol, Hallstatt and Bad Ischl (Austria), near Whitby (UK), and in the Carlsbad Potash District (New Mexico), also on salt lakes in western China. Picromerite can a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Mohrite
Mohrite, (NH4)2Fe(SO4)2 · 6 H2O, is a rare ammonium iron(II) sulfate mineral originally found in the geothermal fields of Tuscany, Italy. This Fe-dominant analogue of boussingaultite is sometimes reported from burning coal dumps where it is a product of pyrite oxidation. The mineral crystallizes in the monoclinic crystal system with space group ''P21/a''. See also * Mohr's salt Ammonium iron(II) sulfate, or Mohr's salt, is the inorganic compound with the formula (NH4)2Fe(SO4)2(H2O)6. Containing two different cations, Fe2+ and NH4+, it is classified as a double salt of ferrous sulfate and ammonium sulfate. It is a commo ... * Acid mine drainage, pyrite oxidation References Ammonium minerals Iron(II) minerals Sulfate minerals Monoclinic minerals Minerals in space group 14 {{sulfate-mineral-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ammonium Sulfate
Ammonium sulfate (American English and international scientific usage; ammonium sulphate in British English); (NH4)2SO4, is an inorganic salt with a number of commercial uses. The most common use is as a soil fertilizer. It contains 21% nitrogen and 24% sulfur. Uses The primary use of ammonium sulfate is as a fertilizer for alkaline soils. In the soil the ammonium ion is released and forms a small amount of acid, lowering the pH balance of the soil, while contributing essential nitrogen for plant growth. The main disadvantage to the use of ammonium sulfate is its low nitrogen content relative to ammonium nitrate, which elevates transportation costs.Karl-Heinz Zapp "Ammonium Compounds" in ''Ullmann's Encyclopedia of Industrial Chemistry'', 2012, Wiley-VCH, Weinheim. It is also used as an agricultural spray adjuvant for water-soluble insecticides, herbicides, and fungicides. There, it functions to bind iron and calcium cations that are present in both well water and plant cells. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Alfred Edwin Howard Tutton
Alfred Edwin Howard Tutton (22 August 1864 – 14 July 1938) was a British inspector of schools who was a crystallographer in his spare time. He was elected Fellow of the Royal Society in 1899. Tutton was born in Cheadle Moseley, Cheshire, to Venetian blind-maker James Tutton. Educated at the National School, Edgeley, he worked for a while as a town clerk and later as a medical officer at Stockport. He attended evening classes in chemistry at Owens College with lectures by Sir Henry Roscoe. A scholarship allowed him to study under Percy Faraday Frankland, Thomas Edward Thorpe, John Wesley Judd and Arthur William Rucker at the Royal College of Science in London for three years. He became a lecturer in chemistry in 1889 and an inspector for schools in 1895. He set up a laboratory at home and began to work on crystallography in his spare time. He taught himself everything about crystallography on his own, except for some assistance from HA Miers. He designed instruments to mea ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Schönite
Picromerite (synonyms: schoenite, schönite) is a mineral from the class of hydrous sulfates lacking additional anions, and containing medium to large cations according to the Nickel–Strunz classification. Etymology The name comes from the Greek words πικρός ikrosfor "bitter" and μέρος eros for "part", and relates to the bitter taste of the mineral. Occurrence Picromerite is found on comparatively few places, currently (2015) only about 40 localities are known. It was first identified in active volcanic fumaroles on Mount Vesuvius by Arcangelo Scacchi in 1855 and has also been found in volcanic deposits on Mount Etna and on Hawai'i. It is more commonly found in the kainite zones of some marine salt deposits, among them salt mines in Thuringia, Lower Saxony and Saxony-Anhalt (Germany), near Hall in Tirol, Hallstatt and Bad Ischl (Austria), near Whitby (UK), and in the Carlsbad Potash District (New Mexico), also on salt lakes in western China. Picromerite can ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Alum
An alum () is a type of chemical compound, usually a hydrated double sulfate salt of aluminium with the general formula , where is a monovalent cation such as potassium or ammonium. By itself, "alum" often refers to potassium alum, with the formula . Other alums are named after the monovalent ion, such as sodium alum and ammonium alum. The name "alum" is also used, more generally, for salts with the same formula and structure, except that aluminium is replaced by another trivalent metal ion like chromium, and/or sulfur is replaced by another chalcogen like selenium. The most common of these analogs is chrome alum . In most industries, the name "alum" (or "papermaker's alum") is used to refer to aluminium sulfate, , which is used for most industrial flocculation (the variable is an integer whose size depends on the amount of water absorbed into the alum). In medicine, "alum" may also refer to aluminium hydroxide gel used as a vaccine adjuvant. History Alum found at ar ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Double Salts
A double salt is a salt that contains two or more different cations or anions. Examples of double salts include alums (with the general formula ) and Tutton's salts (with the general formula ). Other examples include potassium sodium tartrate, ammonium iron(II) sulfate (Mohr's salt), potassium uranyl sulfate (used to discover radioactivity) and bromlite . The fluorocarbonates contain fluoride and carbonate anions. Many coordination complexes form double salts. Double salts should not be confused with complexes. Double salts only exist in the solid. When dissolved in water, a double salt acts as a mixture of the two separate salts: it completely dissociates into simple ions while a hexaaquo complex does not; the complex ion remains unchanged. Similarly, potassium hexaiodoytterbate(II) is a complex salt and contains the discrete hexaiodoytterbate(II) ion , which remains intact in aqueous solutions. In many cases, the complex ion is indicated by square brackets " . Double salts ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
