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Sour Gas
Sour gas is natural gas or any other gas containing significant amounts of hydrogen sulfide (H2S). Natural gas is usually considered sour if there are more than 5.7 milligrams of H2S per cubic meter of natural gas, which is equivalent to approximately 4 ppm by volume under standard temperature and pressure.NaturalGas.org website page
''Processing Natural Gas''
However, this threshold varies by country, state, or even agency or application. For instance, the Texas Railroad Commission considers a sour gas pipeline one that carries gas over 100 ppm by volume of H2S. However, the
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Natural Gas
Natural gas (also fossil gas, methane gas, and gas) is a naturally occurring compound of gaseous hydrocarbons, primarily methane (95%), small amounts of higher alkanes, and traces of carbon dioxide and nitrogen, hydrogen sulfide and helium. Methane is a colorless and odorless gas, and, after carbon dioxide, is the second-greatest greenhouse gas that contributes to global climate change. Because natural gas is odorless, a commercial odorizer, such as Methanethiol (mercaptan brand), that smells of hydrogen sulfide (rotten eggs) is added to the gas for the ready detection of gas leaks. Natural gas is a fossil fuel that is formed when layers of organic matter (primarily marine microorganisms) are thermally decomposed under oxygen-free conditions, subjected to intense heat and pressure underground over millions of years. The energy that the decayed organisms originally obtained from the sun via photosynthesis is stored as chemical energy within the molecules of methane and other ...
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Natural Gas Processing
Nature is an inherent character or constitution, particularly of the ecosphere or the universe as a whole. In this general sense nature refers to the laws, elements and phenomena of the physical world, including life. Although humans are part of nature, human activity or humans as a whole are often described as at times at odds, or outright separate and even superior to nature. During the advent of modern scientific method in the last several centuries, nature became the passive reality, organized and moved by divine laws. With the Industrial Revolution, nature increasingly became seen as the part of reality deprived from intentional intervention: it was hence considered as sacred by some traditions ( Rousseau, American transcendentalism) or a mere decorum for divine providence or human history ( Hegel, Marx). However, a vitalist vision of nature, closer to the pre-Socratic one, got reborn at the same time, especially after Charles Darwin. Within the various uses of the wo ...
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Natural Gas
Natural gas (also fossil gas, methane gas, and gas) is a naturally occurring compound of gaseous hydrocarbons, primarily methane (95%), small amounts of higher alkanes, and traces of carbon dioxide and nitrogen, hydrogen sulfide and helium. Methane is a colorless and odorless gas, and, after carbon dioxide, is the second-greatest greenhouse gas that contributes to global climate change. Because natural gas is odorless, a commercial odorizer, such as Methanethiol (mercaptan brand), that smells of hydrogen sulfide (rotten eggs) is added to the gas for the ready detection of gas leaks. Natural gas is a fossil fuel that is formed when layers of organic matter (primarily marine microorganisms) are thermally decomposed under oxygen-free conditions, subjected to intense heat and pressure underground over millions of years. The energy that the decayed organisms originally obtained from the sun via photosynthesis is stored as chemical energy within the molecules of methane and other ...
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Shah Gas Field
The Shah gas field is a UAE natural gas field that was discovered in 1967. It began production in 2014 and produces natural gas and condensates. The total proven reserves of the Shah gas field are around 17 trillion cubic feet (480 billion m³) and production is slated to be around 1 billion cubic feet/day (28.3 million m³). The gas deposits consist of 23% H2S and 10% CO2, making it one of the most sour operational gas fields in the world. Sour gas Sour gas is natural gas or any other gas containing significant amounts of hydrogen sulfide (H2S). Natural gas is usually considered sour if there are more than 5.7 milligrams of H2S per cubic meter of natural gas, which is equivalent to approxima ... is defined as gas containing a high proportion of hydrogen sulphide. This environmental pollutant is required to be removed either as solid sulphur for commercial sale, or concentrated sulphide solutions are extracted and re-injected underground. References Natural gas fields in th ...
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Rectisol
Rectisol is the trade name for an Amine gas treating, acid gas removal process that uses methanol as a solvent to separate acid gases such as hydrogen sulfide and carbon dioxide from valuable feed gas streams. By doing so, the feed gas is made more suitable for combustion and/or further processing. Rectisol is used most often to treat synthesis gas (primarily hydrogen and carbon monoxide) produced by gasification of coal or heavy hydrocarbons, as the methanol solvent is well able to remove trace contaminants such as ammonia, mercury (element), mercury, and hydrogen cyanide usually found in these gases. As an acid gas and large component of valuable feed gas streams, CO2 is separated during the methanol solvent regeneration. Process description In thRectisol process(licensed by both Linde AG and Air Liquide#Subsidiaries, Air Liquide), cold methanol at approximately –40 °F (–40 °C) dissolves (absorbs) the acid gases from the feed gas at relatively high pressure, usual ...
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Carbonyl Sulfide
Carbonyl sulfide is the chemical compound with the linear formula . It is a colorless flammable gas with an unpleasant odor. It is a linear molecule consisting of a carbonyl double bonded to a sulfur atom. Carbonyl sulfide can be considered to be intermediate between carbon dioxide and carbon disulfide, both of which are valence isoelectronic with it. Occurrence Carbonyl sulfide is the most abundant sulfur compound naturally present in the atmosphere, at , because it is emitted from oceans, volcanoes and deep sea vents. As such, it is a significant compound in the global sulfur cycle. Measurements on the Antarctica ice cores and from air trapped in snow above glaciers ( firn air) have provided a detailed picture of OCS concentrations from 1640 to the present day and allow an understanding of the relative importance of anthropogenic and non-anthropogenic sources of this gas to the atmosphere. Some carbonyl sulfide that is transported into the stratospheric sulfate lay ...
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Redox
Redox ( , , reduction–oxidation or oxidation–reduction) is a type of chemical reaction in which the oxidation states of the reactants change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or a decrease in the oxidation state. The oxidation and reduction processes occur simultaneously in the chemical reaction. There are two classes of redox reactions: * Electron transfer, Electron-transfer – Only one (usually) electron flows from the atom, ion, or molecule being oxidized to the atom, ion, or molecule that is reduced. This type of redox reaction is often discussed in terms of redox couples and electrode potentials. * Atom transfer – An atom transfers from one Substrate (chemistry), substrate to another. For example, in the rusting of iron, the oxidation state of iron atoms increases as the iron converts to an oxide, and simultaneously, the oxidation state of oxygen decreases as it accepts electrons r ...
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Gas Compressor
A compressor is a mechanical device that increases the pressure of a gas by reducing its volume. An air compressor is a specific type of gas compressor. Many compressors can be staged, that is, the gas is compressed several times in steps or stages, to increase discharge pressure. Often, the second stage is physically smaller than the primary stage, to accommodate the already compressed gas without reducing its pressure. Each stage further compresses the gas and increases its pressure and also temperature (if inter cooling between stages is not used). Types Compressors are similar to pumps: both increase the pressure on a fluid (such as a gas) and both can transport the fluid through a pipe (material), pipe. The main distinction is that the focus of a compressor is to change the density or volume of the fluid, which is mostly only achievable on gases. Gases are compressible, while liquids are relatively incompressible, so compressors are rarely used for liquids. The main actio ...
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Sulfuric Acid
Sulfuric acid (American spelling and the preferred IUPAC name) or sulphuric acid (English in the Commonwealth of Nations, Commonwealth spelling), known in antiquity as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen, and hydrogen, with the molecular formula . It is a colorless, odorless, and Viscosity, viscous liquid that is Miscibility, miscible with water. Pure sulfuric acid does not occur naturally due to its Dehydration reaction, strong affinity to water vapor; it is Hygroscopy, hygroscopic and readily absorbs water vapor from the Atmosphere of Earth, air. Concentrated sulfuric acid is a strong oxidant with powerful dehydrating properties, making it highly corrosive towards other materials, from rocks to metals. Phosphorus pentoxide is a notable exception in that it is not dehydrated by sulfuric acid but, to the contrary, dehydrates sulfuric acid to sulfur trioxide. Upon addition of sulfuric acid to water, a considerable amount of heat is releas ...
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Wet Sulfuric Acid Process
The wet sulfuric acid process (WSA process) is a gas desulfurization process introduced by Danish company Haldor Topsoe in 1987. The WSA process can be applied in all industries where sulfur removal presents an issue, and produces commercial quality sulfuric acid (H2SO4) and high-pressure steam during desulfurization The wet catalysis process is used for processing sulfur-containing streams, such as: * H2S gas from e.g. amine gas treating unit * Off-gas from sour water stripper (SWS) gas *Off-gas from Rectisol *Spent acid from an alkylation unit * Claus process tail gas *Heavy residue or petcoke-fired utility boiler off-gas *Boiler flue gases from various processes SNOX flue gas desulfurization *Metallurgical process gas *Production of sulfuric acid The process ;The main reactions in the WSA process *Combustion: 2 H2S + 3 O2 2 H2O + 2 SO2 (-1036 kJ/mol) *Oxidation: 2 SO2 + O2 2 SO3 (-198 kJ/mol) Vanadium(V)_oxide.html" ;"title="n the presence of a Vanadium(V) oxide">va ...
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Claus Process
The Claus process is the most significant gas desulfurizing process, recovering elemental sulfur from gaseous hydrogen sulfide. First patented in 1883 by the chemist Carl Friedrich Claus, the Claus process has become the industry standard. The multi-step Claus process recovers sulfur from the gaseous hydrogen sulfide found in raw natural gas and from the by-product gases containing hydrogen sulfide derived from refining crude oil and other industrial processes. The by-product gases mainly originate from physical and chemical gas treatment units ( Selexol, Rectisol, Purisol and amine scrubbers) in refineries, natural gas processing plants and gasification or synthesis gas plants. These by-product gases may also contain hydrogen cyanide, hydrocarbons, sulfur dioxide or ammonia. Gases with an H2S content of over 25% are suitable for the recovery of sulfur in straight-through Claus plants while alternate configurations such as a split-flow set up or feed and air preheatin ...
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Sulfur
Sulfur ( American spelling and the preferred IUPAC name) or sulphur ( Commonwealth spelling) is a chemical element; it has symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with the chemical formula S8. Elemental sulfur is a bright yellow, crystalline solid at room temperature. Sulfur is the tenth most abundant element by mass in the universe and the fifth most common on Earth. Though sometimes found in pure, native form, sulfur on Earth usually occurs as sulfide and sulfate minerals. Being abundant in native form, sulfur was known in ancient times, being mentioned for its uses in ancient India, ancient Greece, China, and ancient Egypt. Historically and in literature sulfur is also called brimstone, which means "burning stone". Almost all elemental sulfur is produced as a byproduct of removing sulfur-containing contaminants from natural gas and petroleum.. Downloahere Th ...
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