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Orthosilicic Acid
Orthosilicic acid () is an inorganic compound with the formula . Although rarely observed, it is the key compound of silica and silicates and the Precursor (chemistry), precursor to other silicic acids . Silicic acids play important roles in biomineralization and technology.N. N. Greenwood, A. Earnshaw, ''Chemistry of the Elements'', 2nd ed., Butterworth-Heinemann, Oxford, UK, 1997. Isolation Typically orthosilicic acid is assumed to be a product of the hydrolysis of the ortho esters , as is practiced in sol-gel syntheses. These conditions are however too vigorous to allow isolation of the parent acid. Orthosilicic acid can be produced by Pd-catalyzed hydrogenolysis of tetrabenzoxysilicon: : The acid was crystallized from a solution of dimethylacetamide and tetrabutylammonium chloride. As established by X-ray crystallography, the chloride anions interact with the acid via hydrogen bonds. Otherwise, the structure consists of the expected tetrahedral silicon center. React ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Inorganic Compound
In chemistry, an inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds, that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as '' inorganic chemistry''. Inorganic compounds comprise most of the Earth's crust, although the compositions of the deep mantle remain active areas of investigation. Some simple carbon compounds are often considered inorganic. Examples include the allotropes of carbon (graphite, diamond, buckminsterfullerene, etc.), carbon monoxide, carbon dioxide, carbides, and the following salts of inorganic anions: carbonates, cyanides, cyanates, and thiocyanates. Many of these are normal parts of mostly organic systems, including organisms; describing a chemical as inorganic does not necessarily mean that it does not occur within living things. History Friedrich Wöhler's conversion of ammonium cyanate into urea in 1828 is often cited as the starting point of modern ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Biogeochemical Cycle
A biogeochemical cycle (or more generally a cycle of matter) is the pathway by which a chemical substance cycles (is turned over or moves through) the biotic and the abiotic compartments of Earth. The biotic compartment is the biosphere and the abiotic compartments are the atmosphere, hydrosphere and lithosphere. There are biogeochemical cycles for chemical elements, such as for calcium, carbon, hydrogen, mercury, nitrogen, oxygen, phosphorus, selenium, iron and sulfur, as well as molecular cycles, such as for water and silica. There are also macroscopic cycles, such as the rock cycle, and human-induced cycles for synthetic compounds such as polychlorinated biphenyls (PCBs). In some cycles there are reservoirs where a substance can remain or be sequestered for a long period of time. Overview Energy flows directionally through ecosystems, entering as sunlight (or inorganic molecules for chemoautotrophs) and leaving as heat during the many transfers between trophic levels. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
World Ocean Atlas
The World Ocean Atlas (WOA) is a data product of the Ocean Climate Laboratory of the National Oceanographic Data Center (U.S.). The WOA consists of a climatology of fields of ''in situ'' ocean properties for the World Ocean. It was first produced in 1994 (based on the earlier ''Climatological Atlas of the World Ocean''), with later editions at roughly four year intervals in 1998, 2001, 2005, 2009, and 2013. Dataset The fields that make up the WOA dataset consist of objectively-analysed global grids at 1 ° spatial resolution. The fields are three-dimensional, and data are typically interpolated onto 33 standardised vertical intervalsStandardised intervals are at 0, 10, 20, 30, 50, 75, 100, 125, 150, 200, 250, 300, 400, 500, 600, 700, 800, 900, 1000, 1100, 1200, 1300, 1400, 1500, 1750, 2000, 2500, 3000, 3500, 4000, 4500, 5000, 5500 m from the surface (0 m) to the abyssal seafloor (5500 m). In terms of temporal resolution, averaged fields are produced for annual, seasonal and ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Antarctic Circumpolar Current
The Antarctic Circumpolar Current (ACC) is an ocean current that flows clockwise (as seen from the South Pole) from west to east around Antarctica. An alternative name for the ACC is the West Wind Drift. The ACC is the dominant circulation feature of the Southern Ocean and has a mean transport estimated at 100–150 Sverdrups (Sv, million m3/s), or possibly even higher, making it the largest ocean current. The current is circumpolar due to the lack of any landmass connecting with Antarctica and this keeps warm ocean waters away from Antarctica, enabling that continent to maintain its huge ice sheet. Associated with the Circumpolar Current is the Antarctic Convergence, where the cold Antarctic waters meet the warmer waters of the subantarctic, creating a zone of upwelling nutrients. These nurture high levels of phytoplankton with associated copepods and krill, and resultant foodchains supporting fish, whales, seals, penguins, albatrosses, and a wealth of other species. The ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ocean
The ocean (also the sea or the world ocean) is the body of salt water that covers approximately 70.8% of the surface of Earth and contains 97% of Earth's water. An ocean can also refer to any of the large bodies of water into which the world ocean is conventionally divided."Ocean." ''Merriam-Webster.com Dictionary'', Merriam-Webster, [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Frustule
A frustule is the hard and porous cell wall or external layer of diatoms. The frustule is composed almost purely of silica, made from silicic acid, and is coated with a layer of organic substance, which was referred to in the early literature on diatoms as pectin, a fiber most commonly found in cell walls of plants. This layer is actually composed of several types of polysaccharides.Progress in Phycological Research: v. 7 (1991) by F.E. Round (Volume editor), David J. Chapman (Volume editor) The frustule's structure is usually composed of two overlapping sections known as thecae (or less formally as valves). The joint between the two thecae is supported by bands of silica (girdle bands) that hold them together. This overlapping allows for some internal expansion room and is essential during the reproduction process. The frustule also contains many pores called areolae and slits that provide the diatom access to the external environment for processes such as waste removal and muci ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cell Wall
A cell wall is a structural layer surrounding some types of cells, just outside the cell membrane. It can be tough, flexible, and sometimes rigid. It provides the cell with both structural support and protection, and also acts as a filtering mechanism. Cell walls are absent in many eukaryotes, including animals, but are present in some other ones like fungi, algae and plants, and in most prokaryotes (except mollicute bacteria). A major function is to act as pressure vessels, preventing over-expansion of the cell when water enters. The composition of cell walls varies between taxonomic group and species and may depend on cell type and developmental stage. The primary cell wall of land plants is composed of the polysaccharides cellulose, hemicelluloses and pectin. Often, other polymers such as lignin, suberin or cutin are anchored to or embedded in plant cell walls. Algae possess cell walls made of glycoproteins and polysaccharides such as carrageenan and agar that are absent ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Biogenic Silica
Biogenic silica (bSi), also referred to as opal, biogenic opal, or amorphous opaline silica, forms one of the most widespread biogenic minerals. For example, microscopic particles of silica called phytoliths can be found in grasses and other plants. Silica is an amorphous metal oxide formed by complex inorganic polymerization processes. This is opposed to the other major biogenic minerals, comprising carbonate and phosphate, which occur in nature as crystalline iono-covalent solids (e.g. salts) whose precipitation is dictated by solubility equilibria.Coradin, T., Lopez, P.J. (2003). "Biogenic Silica Patterning: Simple Chemistry or Subtle Biology?" ChemBioChem 3: 1-9. Chemically, bSi is hydrated silica (SiO2·''n''H2O), which is essential to many plants and animals. Diatoms in both fresh and salt water extract dissolved silica from the water to use as a component of their cell walls. Likewise, some holoplanktonic protozoa (Radiolaria), some sponges, and some plants (leaf phytolith ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Polymer
A polymer (; Greek '' poly-'', "many" + ''-mer'', "part") is a substance or material consisting of very large molecules called macromolecules, composed of many repeating subunits. Due to their broad spectrum of properties, both synthetic and natural polymers play essential and ubiquitous roles in everyday life. Polymers range from familiar synthetic plastics such as polystyrene to natural biopolymers such as DNA and proteins that are fundamental to biological structure and function. Polymers, both natural and synthetic, are created via polymerization of many small molecules, known as monomers. Their consequently large molecular mass, relative to small molecule compounds, produces unique physical properties including toughness, high elasticity, viscoelasticity, and a tendency to form amorphous and semicrystalline structures rather than crystals. The term "polymer" derives from the Greek word πολύς (''polus'', meaning "many, much") and μέρος (''meros'' ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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