Minthostachys Mollis
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Minthostachys Mollis
''Minthostachys mollis'' is a medicinal plant restricted to the South American Andes from Peru Venezuela to Bolivia. It is the most variable and widely distributed species of the genus ''Minthostachys''. It is known by the common names muña, tipo, tipollo, or poleo. Medicinal uses In the indigenous medicine traditions of the Andes, the plant is made into tea and used medicinally as a carminative and aphrodisiac. Etymology Its common name ''"muña"'' comes from Quechua. Chemical characteristics The principal components of essential oil are as follows: *pulegone *menthone *menthol *(−)- β-pinene *(−)-α-pinene *limonene *isomenthone *piperic acid *eucalyptol *carvone In the flowering tops 19 compounds were identified in the essential oil, predominantly 29% neomenthol, 24% menthone, 20% menthol, and 8% piperitone Piperitone is a natural monoterpene ketone which is a component of some essential oils. Both stereoisomers, the D-form and the L-form, are known. The D-form ha ...
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Kunth
Carl Sigismund Kunth (18 June 1788 – 22 March 1850), also Karl Sigismund Kunth or anglicized as Charles Sigismund Kunth, was a German botanist. He is known for being one of the first to study and categorise plants from the American continents, publishing ''Nova genera et species plantarum quas in peregrinatione ad plagam aequinoctialem orbis novi collegerunt Bonpland et Humboldt'' (7 vols., Paris, 1815–1825). Born in Leipzig, Kunth became a merchant's clerk in Berlin in 1806. After meeting Alexander von Humboldt, who helped him attend lectures at the University of Berlin, Kunth became interested in botany. Kunth worked as Humboldt's assistant in Paris from 1813 to 1819. He classified plants that had been collected by Humboldt and Aimé Bonpland during their journey through the Americas. When Kunth returned to Berlin in 1820, he became Professor of Botany at the University of Berlin, as well as the Vice President of the Berlin botanical garden. In 1829, he was elected membe ...
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Menthone
Menthone is a monoterpene with a minty flavor that occurs naturally in a number of essential oils. ''l''-Menthone (or (2''S'',5''R'')-''trans''-2-isopropyl-5-methylcyclohexanone), shown at right, is the most abundant in nature of the four possible stereoisomers. It is structurally related to menthol, which has a secondary alcohol in place of the carbonyl. Menthone is used in flavoring, perfume and cosmetics for its characteristic aromatic and minty odor. Occurrence Menthone is a constituent of the essential oils of pennyroyal, peppermint, ''Mentha arvensis'', ''Pelargonium'' geraniums, and others. In most essential oils, it is a minor compound; it was first synthesized by oxidation of menthol in 1881 before it was found in essential oils in 1891. Structure and preparation 2-Isopropyl-5-methylcyclohexanone has two asymmetric carbon centers, meaning that it can have four different stereoisomers: (2''S'',5''S''), (2''R'',5''S''), (2''S'',5''R'') and (2''R'',5''R''). The ''S'','' ...
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Lamiaceae
The Lamiaceae ( ) or Labiatae are a family of flowering plants commonly known as the mint, deadnettle or sage family. Many of the plants are aromatic in all parts and include widely used culinary herbs like basil, mint, rosemary, sage, savory, marjoram, oregano, hyssop, thyme, lavender, and perilla, as well as other medicinal herbs such as catnip, salvia, bee balm, wild dagga, and oriental motherwort. Some species are shrubs, trees (such as teak), or, rarely, vines. Many members of the family are widely cultivated, not only for their aromatic qualities, but also their ease of cultivation, since they are readily propagated by stem cuttings. Besides those grown for their edible leaves, some are grown for decorative foliage. Others are grown for seed, such as ''Salvia hispanica'' (chia), or for their edible tubers, such as ''Plectranthus edulis'', ''Plectranthus esculentus'', '' Plectranthus rotundifolius'', and '' Stachys affinis'' (Chinese artichoke). Many are also grown orn ...
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Piperitone
Piperitone is a natural monoterpene ketone which is a component of some essential oils. Both stereoisomers, the D-form and the L-form, are known. The D-form has a peppermint-like aroma and has been isolated from the oils of plants from the genera ''Cymbopogon'', ''Andropogon'', and ''Mentha''. The L-form has been isolated from Sitka spruce. Piperitone is used as the principal raw material for the production of synthetic menthol and thymol. The primary source of D/L-piperitone is from ''Eucalyptus dives'', produced mainly in South Africa South Africa, officially the Republic of South Africa (RSA), is the southernmost country in Africa. It is bounded to the south by of coastline that stretch along the South Atlantic and Indian Oceans; to the north by the neighbouring countri ....Boland, D.J., Brophy, J.J., and A.P.N. House, ''Eucalyptus Leaf Oils'', 1991, {{ISBN, 0-909605-69-6 References Ketones Monoterpenes Cyclohexenes ...
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Neomenthol
Menthol is an organic compound, more specifically a monoterpenoid, made synthetically or obtained from the oils of corn mint, peppermint, or other mints. It is a waxy, clear or white crystalline substance, which is solid at room temperature and melts slightly above. The main form of menthol occurring in nature is (−)-menthol, which is assigned the (1''R'',2''S'',5''R'') configuration. Menthol has local anesthetic and counterirritant qualities, and it is widely used to relieve minor throat irritation. Menthol also acts as a weak κ-opioid receptor agonist. Structure Natural menthol exists as one pure stereoisomer, nearly always the (1''R'',2''S'',5''R'') form (bottom left corner of the diagram below). The eight possible stereoisomers are: : In the natural compound, the isopropyl group is in the ''trans'' orientation to both the methyl and hydroxyl groups. Thus, it can be drawn in any of the ways shown: : The (+)- and (−)-enantiomers of menthol are the most stable among ...
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Carvone
Carvone is a member of a family of chemicals called terpenoids. Carvone is found naturally in many essential oils, but is most abundant in the oils from seeds of caraway (''Carum carvi''), spearmint (''Mentha spicata''), and dill. Uses Both carvones are used in the food and flavor industry. ''R''-(−)-Carvone is also used for air freshening products and, like many essential oils, oils containing carvones are used in aromatherapy and alternative medicine. ''S''-(+)-Carvone has shown a suppressant effect against high-fat diet induced weight gain in mice. Food applications As the compound most responsible for the flavor of caraway, dill and spearmint, carvone has been used for millennia in food. Wrigley's Spearmint Gum and spearmint flavored Life Savers are major users of natural spearmint oil from ''Mentha spicata''. Caraway seed is extracted with alcohol to make the European drink Kümmel. Agriculture ''S''-(+)-Carvone is also used to prevent premature sprouting of potatoes ...
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Eucalyptol
Eucalyptol is a monoterpenoid. A colorless liquid, it is a bicyclic ether. Eucalyptol has a fresh mint-like smell and a spicy, cooling taste. It is insoluble in water, but miscible with organic solvents. Eucalyptol makes up ~70% - 90% of eucalyptus oil. Eucalyptol forms crystalline adducts with hydrohalic acids, ''o''-cresol, resorcinol, and phosphoric acid. Formation of these adducts is useful for purification. In 1870, F. S. Cloez identified and ascribed the name "eucalyptol" to the dominant portion of ''Eucalyptus globulus'' oil. Uses Because of its pleasant, spicy aroma and taste, eucalyptol is used in flavorings, fragrances, and cosmetics. Cineole-based eucalyptus oil is used as a flavouring at low levels (0.002%) in various products, including baked goods, confectionery, meat products, and beverages. In a 1994 report released by five top cigarette companies, eucalyptol was listed as one of the 599 additives to cigarettes. It is claimed to be added to improve the f ...
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Piperic Acid
Piperic acid is a chemical often obtained by the base-hydrolysis of the alkaloid piperine from black pepper, followed by acidification of the corresponding salt. Piperic acid is an intermediate in the synthesis of other compounds such as piperonal, and as-such may be used to produce fragrances, perfumes flavorants and drugs as well as other useful compounds. Preparation Piperic acid can be prepared from the commercially-available alkaloid piperine, a cyclic amide containing a piperidine group, by reacting it with a hydroxide such as potassium hydroxide, then acidifying the formed piperate salt with hydrochloric acid or another acid. The toxic compound piperidine is given off during the base-hydrolysis of piperine and as-such, safety precautions should be taken. : Reactions Reaction of piperic acid with strong oxidizers such as potassium permanganate or ozone, or a halogen such as bromine followed by sodium hydroxide causes oxidative cleavage of the double-bonds, yielding piperona ...
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Isomenthone
Menthone is a monoterpene with a minty flavor that occurs naturally in a number of essential oils. ''l''-Menthone (or (2''S'',5''R'')-''trans''-2-isopropyl-5-methylcyclohexanone), shown at right, is the most abundant in nature of the four possible stereoisomers. It is structurally related to menthol, which has a secondary alcohol in place of the carbonyl. Menthone is used in flavoring, perfume and cosmetics for its characteristic aromatic and minty odor. Occurrence Menthone is a constituent of the essential oils of pennyroyal, peppermint, ''Mentha arvensis'', ''Pelargonium'' geraniums, and others. In most essential oils, it is a minor compound; it was first synthesized by oxidation of menthol in 1881 before it was found in essential oils in 1891. Structure and preparation 2-Isopropyl-5-methylcyclohexanone has two asymmetric carbon centers, meaning that it can have four different stereoisomers: (2''S'',5''S''), (2''R'',5''S''), (2''S'',5''R'') and (2''R'',5''R''). The ''S'','' ...
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Limonene
Limonene is a colorless liquid aliphatic hydrocarbon classified as a cyclic monoterpene, and is the major component in the oil of citrus fruit peels. The -isomer, occurring more commonly in nature as the fragrance of oranges, is a flavoring agent in food manufacturing. It is also used in chemical synthesis as a precursor to carvone and as a renewables-based solvent in cleaning products. The less common -isomer has a piny, turpentine-like odor, and is found in the edible parts of such plants as caraway, dill, and bergamot orange plants. Limonene takes its name from Italian ''limone'' ("lemon"). Limonene is a chiral molecule, and biological sources produce one enantiomer: the principal industrial source, citrus fruit, contains -limonene ((+)-limonene), which is the (''R'')-enantiomer. Racemic limonene is known as dipentene. -Limonene is obtained commercially from citrus fruits through two primary methods: centrifugal separation or steam distillation. Chemical reactions Limon ...
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α-pinene
α-Pinene is an organic compound of the terpene class, one of two isomers of pinene. It is an alkene and it contains a reactive four-membered ring. It is found in the oils of many species of many coniferous trees, notably the pine. It is also found in the essential oil of rosemary (''Rosmarinus officinalis'') and ''Satureja myrtifolia'' (also known as ''Zoufa'' in some regions). Both enantiomers are known in nature; (1''S'',5''S'')- or (−)-α-pinene is more common in European pines, whereas the (1''R'',5''R'')- or (+)-α-isomer is more common in North America. The racemic mixture is present in some oils such as eucalyptus oil and orange peel oil. Reactivity : Commercially important derivatives of alpha-pinene are linalool, geraniol, nerol, a-terpineol, and camphene. α-Pinene 1 is reactive owing to the presence of the four-membered ring adjacent to the alkene. The compound is prone to skeletal rearrangements such as the Wagner–Meerwein rearrangement. Acids typic ...
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