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Mason–Weaver Equation
The Mason–Weaver equation (named after Max Mason and Warren Weaver) describes the sedimentation and diffusion of solutes under a uniform force, usually a gravitational field. Assuming that the gravitational field is aligned in the ''z'' direction (Fig. 1), the Mason–Weaver equation may be written : \frac = D \frac + sg \frac where ''t'' is the time, ''c'' is the solute concentration (moles per unit length in the ''z''-direction), and the parameters ''D'', ''s'', and ''g'' represent the solute diffusion constant, sedimentation coefficient and the (presumed constant) acceleration of gravity, respectively. The Mason–Weaver equation is complemented by the boundary conditions : D \frac + s g c = 0 at the top and bottom of the cell, denoted as z_a and z_b, respectively (Fig. 1). These boundary conditions correspond to the physical requirement that no solute pass through the top and bottom of the cell, i.e., that the flux there be zero. The cell is assumed to be rectangular a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Max Mason
Charles Max Mason (–), better known as Max Mason, was an American mathematician. Mason was president of the University of Chicago (1925–1928) and president of the Rockefeller Foundation (1929–1936). Mason's mathematical research interests included differential equations, the calculus of variations, and electromagnetic theory. Education *B.Litt., 1898, University of Wisconsin-Madison *Ph.D., Mathematics, University of Göttingen, 1903. **Dissertation: "Randwertaufgaben bei gewöhnlichen Differentialgleichungen" ( Boundary value functions with ordinary differential equations) **Advisor: Hilbert Career * Massachusetts Institute of Technology (MIT), 1903–1904, Instructor of Mathematics. * Yale University, 1904–1908, Assistant Professor of Mathematics. * University of Wisconsin–Madison, 1908–1909, University of Wisconsin–Madison, Associate Professor of Mathematics. * University of Wisconsin–Madison, 1909–1925, Professor of Physics. ** National Research Counc ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Velocity
Velocity is the directional speed of an object in motion as an indication of its rate of change in position as observed from a particular frame of reference and as measured by a particular standard of time (e.g. northbound). Velocity is a fundamental concept in kinematics, the branch of classical mechanics that describes the motion of bodies. Velocity is a physical vector quantity; both magnitude and direction are needed to define it. The scalar absolute value ( magnitude) of velocity is called , being a coherent derived unit whose quantity is measured in the SI ( metric system) as metres per second (m/s or m⋅s−1). For example, "5 metres per second" is a scalar, whereas "5 metres per second east" is a vector. If there is a change in speed, direction or both, then the object is said to be undergoing an ''acceleration''. Constant velocity vs acceleration To have a ''constant velocity'', an object must have a constant speed in a constant direction. Constant dire ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Boltzmann Constant
The Boltzmann constant ( or ) is the proportionality factor that relates the average relative kinetic energy of particles in a gas with the thermodynamic temperature of the gas. It occurs in the definitions of the kelvin and the gas constant, and in Planck's law of black-body radiation and Boltzmann's entropy formula, and is used in calculating thermal noise in resistors. The Boltzmann constant has dimensions of energy divided by temperature, the same as entropy. It is named after the Austrian scientist Ludwig Boltzmann. As part of the 2019 redefinition of SI base units, the Boltzmann constant is one of the seven " defining constants" that have been given exact definitions. They are used in various combinations to define the seven SI base units. The Boltzmann constant is defined to be exactly . Roles of the Boltzmann constant Macroscopically, the ideal gas law states that, for an ideal gas, the product of pressure and volume is proportional to the product of ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Einstein Relation (kinetic Theory)
In physics (specifically, the kinetic theory of gases), the Einstein relation is a previously unexpected connection revealed independently by William Sutherland in 1904, Albert Einstein in 1905, and by Marian Smoluchowski in 1906 in their works on Brownian motion. The more general form of the equation is D = \mu \, k_\text T, where * is the diffusion coefficient; * is the "mobility", or the ratio of the particle's terminal drift velocity to an applied force, ; * is the Boltzmann constant; * is the absolute temperature. This equation is an early example of a fluctuation-dissipation relation. Two frequently used important special forms of the relation are: * Einstein–Smoluchowski equation, for diffusion of charged particles: D = \frac * Stokes–Einstein equation, for diffusion of spherical particles through a liquid with low Reynolds number: D = \frac Here * is the electrical charge of a particle; * is the electrical mobility of the charged particle; * is the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Drag Coefficient
In fluid dynamics, the drag coefficient (commonly denoted as: c_\mathrm, c_x or c_) is a dimensionless quantity that is used to quantify the drag or resistance of an object in a fluid environment, such as air or water. It is used in the drag equation in which a lower drag coefficient indicates the object will have less aerodynamic or hydrodynamic drag. The drag coefficient is always associated with a particular surface area. The drag coefficient of any object comprises the effects of the two basic contributors to fluid dynamic drag: skin friction and form drag. The drag coefficient of a lifting airfoil or hydrofoil also includes the effects of lift-induced drag. The drag coefficient of a complete structure such as an aircraft also includes the effects of interference drag. Definition The drag coefficient c_\mathrm d is defined as c_\mathrm d = \dfrac where: * F_\mathrm d is the drag force, which is by definition the force component in the direction of the flow vel ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Buoyant Mass
Buoyancy (), or upthrust, is an upward force exerted by a fluid that opposes the weight of a partially or fully immersed object. In a column of fluid, pressure increases with depth as a result of the weight of the overlying fluid. Thus the pressure at the bottom of a column of fluid is greater than at the top of the column. Similarly, the pressure at the bottom of an object submerged in a fluid is greater than at the top of the object. The pressure difference results in a net upward force on the object. The magnitude of the force is proportional to the pressure difference, and (as explained by Archimedes' principle) is equivalent to the weight of the fluid that would otherwise occupy the submerged volume of the object, i.e. the displaced fluid. For this reason, an object whose average density is greater than that of the fluid in which it is submerged tends to sink. If the object is less dense than the liquid, the force can keep the object afloat. This can occur only in a non- ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Partial Specific Volume
The partial specific volume \bar, express the variation of the extensive volume of a mixture in respect to composition of the masses. It is the partial derivative of volume with respect to the mass of the component of interest. :V=\sum _^n m_i \bar, where \bar is the partial specific volume of a component i defined as: :\bar=\left( \frac \right)_. The PSV is usually measured in milliLiters (mL) per gram The gram (originally gramme; SI unit symbol g) is a unit of mass in the International System of Units (SI) equal to one one thousandth of a kilogram. Originally defined as of 1795 as "the absolute weight of a volume of pure water equal to ... (g), proteins > 30 kDa can be assumed to have a partial specific volume of 0.708 mL/g. Experimental determination is possible by measuring the natural frequency of a U-shaped tube filled successively with air, buffer and protein solution. Properties The sum of partial specific volumes of a mixture or solution is an inverse of dens ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Terminal Velocity
Terminal velocity is the maximum velocity (speed) attainable by an object as it falls through a fluid ( air is the most common example). It occurs when the sum of the drag force (''Fd'') and the buoyancy is equal to the downward force of gravity (''FG'') acting on the object. Since the net force on the object is zero, the object has zero acceleration. In fluid dynamics an object is moving at its terminal velocity if its speed is constant due to the restraining force exerted by the fluid through which it is moving. As the speed of an object increases, so does the drag force acting on it, which also depends on the substance it is passing through (for example air or water). At some speed, the drag or force of resistance will equal the gravitational pull on the object (buoyancy is considered below). At this point the object stops accelerating and continues falling at a constant speed called the terminal velocity (also called settling velocity). An object moving downward faster than ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Solutes
In chemistry, a solution is a special type of homogeneous mixture composed of two or more substances. In such a mixture, a solute is a substance dissolved in another substance, known as a solvent. If the attractive forces between the solvent and solute particles are greater than the attractive forces holding the solute particles together, the solvent particles pull the solute particles apart and surround them. These surrounded solute particles then move away from the solid solute and out into the solution. The mixing process of a solution happens at a scale where the effects of chemical polarity are involved, resulting in interactions that are specific to solvation. The solution usually has the state of the solvent when the solvent is the larger fraction of the mixture, as is commonly the case. One important parameter of a solution is the concentration, which is a measure of the amount of solute in a given amount of solution or solvent. The term "aqueous solution" is used whe ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Molecule
A molecule is a group of two or more atoms held together by attractive forces known as chemical bonds; depending on context, the term may or may not include ions which satisfy this criterion. In quantum physics, organic chemistry, and biochemistry, the distinction from ions is dropped and ''molecule'' is often used when referring to polyatomic ions. A molecule may be homonuclear, that is, it consists of atoms of one chemical element, e.g. two atoms in the oxygen molecule (O2); or it may be heteronuclear, a chemical compound composed of more than one element, e.g. water (molecule), water (two hydrogen atoms and one oxygen atom; H2O). In the kinetic theory of gases, the term ''molecule'' is often used for any gaseous particle regardless of its composition. This relaxes the requirement that a molecule contains two or more atoms, since the noble gases are individual atoms. Atoms and complexes connected by non-covalent interactions, such as hydrogen bonds or ionic bonds, are ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Mechanical Equilibrium
In classical mechanics, a particle is in mechanical equilibrium if the net force on that particle is zero. By extension, a physical system made up of many parts is in mechanical equilibrium if the net force on each of its individual parts is zero. In addition to defining mechanical equilibrium in terms of force, there are many alternative definitions for mechanical equilibrium which are all mathematically equivalent. In terms of momentum, a system is in equilibrium if the momentum of its parts is all constant. In terms of velocity, the system is in equilibrium if velocity is constant. In a rotational mechanical equilibrium the angular momentum of the object is conserved and the net torque is zero. More generally in conservative systems, equilibrium is established at a point in configuration space where the gradient of the potential energy with respect to the generalized coordinates is zero. If a particle in equilibrium has zero velocity, that particle is in static equilibriu ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Density
Density (volumetric mass density or specific mass) is the substance's mass per unit of volume. The symbol most often used for density is ''ρ'' (the lower case Greek letter rho), although the Latin letter ''D'' can also be used. Mathematically, density is defined as mass divided by volume: : \rho = \frac where ''ρ'' is the density, ''m'' is the mass, and ''V'' is the volume. In some cases (for instance, in the United States oil and gas industry), density is loosely defined as its weight per unit volume, although this is scientifically inaccurate – this quantity is more specifically called specific weight. For a pure substance the density has the same numerical value as its mass concentration. Different materials usually have different densities, and density may be relevant to buoyancy, purity and packaging. Osmium and iridium are the densest known elements at standard conditions for temperature and pressure. To simplify comparisons of density across different syst ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
