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Inverse Gas Chromatography
Inverse gas chromatography is a physical characterization analytical technique that is used in the analysis of the surfaces of solids. Inverse gas chromatography or IGC is a highly sensitive and versatile gas phase technique developed over 40 years ago to study the surface and bulk properties of particulate and fibrous materials. In IGC the roles of the stationary (solid) and mobile (gas or vapor) phases are inverted from traditional analytical gas chromatography (GC); IGC is considered a materials characterization technique (of the solid) rather than an analytical technique (of a gas mixture). In GC, a standard column is used to separate and characterize a mixture of several gases or vapors. In IGC, a single standard gas or vapor (probe molecule) is injected into a column packed with the solid sample under investigation. During an IGC experiment a pulse or constant concentration of a known gas or vapor (probe molecule) is injected down the column at a fixed carrier gas flow r ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Analytical Technique
Analytic or analytical may refer to: Chemistry * Analytical chemistry, the analysis of material samples to learn their chemical composition and structure * Analytical technique, a method that is used to determine the concentration of a chemical compound or chemical element * Analytical concentration Mathematics * Abstract analytic number theory, the application of ideas and techniques from analytic number theory to other mathematical fields * Analytic combinatorics, a branch of combinatorics that describes combinatorial classes using generating functions * Analytic element method, a numerical method used to solve partial differential equations * Analytic expression or analytic solution, a mathematical expression using well-known operations that lend themselves readily to calculation * Analytic geometry, the study of geometry based on numerical coordinates rather than axioms * Analytic number theory, a branch of number theory that uses methods from mathematical analysis Mat ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Flory–Rehner Equation
In polymer science Flory–Rehner equation is an equation that describes the mixing of polymer and liquid molecules as predicted by the equilibrium swelling theory of Flory and Rehner. It describes the equilibrium swelling of a lightly crosslinked polymer in terms of crosslink density and the quality of the solvent. The Flory–Rehner equation is written as: : -\left \ln+\nu_2+ \chi_1 \nu_2^2 \right= V_1 n \left(\nu_2^\frac-\frac\right) where, \nu_2 is the volume fraction of polymer in the swollen mass, V_1 the molar volume of the solvent, n is the number of network chain segments bounded on both ends by crosslinks, and \chi_1 is the Flory solvent-polymer interaction term. In its full form, the Flory–Rehner equation is written as: : -\left \ln+\nu_2+ \chi_1 \nu_2^2 \right= \frac \left(1-\frac\frac\right) \left(\nu_2^\frac-\frac\right) where \bar is the specific volume of the polymer; M is the primary molecular mass; f is the crosslink functionality (4 for perfect network); ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sessile Drop Technique
image:Contact angle.svg, 400px, An illustration of the sessile drop technique with a liquid droplet partially wetting a solid substrate. is the contact angle, and represent the solid–gas, gas–liquid, and liquid–solid interfaces, respectively. In materials science, the sessile drop technique is a method used for the characterization of solid surface energy, surface energies, and in some cases, aspects of liquid surface energies. The main premise of the method is that by placing a droplet of liquid with a known surface energy and contact angle, the surface energy of the solid substrate can be calculated. The liquid used for such experiments is referred to as the probe liquid, and the use of several different probe liquids is required. Probe liquid The surface energy is measured in units of joules per square meter, which is equivalent in the case of liquids to surface tension, measured in newtons per meter. The overall surface tension/energy of a liquid can be acquired throu ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Material Characterization
Characterization, when used in materials science, refers to the broad and general process by which a material's structure and properties are probed and measured. It is a fundamental process in the field of materials science, without which no scientific understanding of engineering materials could be ascertained. The scope of the term often differs; some definitions limit the term's use to techniques which study the microscopic structure and properties of materials, while others use the term to refer to any materials analysis process including macroscopic techniques such as mechanical testing, thermal analysis and density calculation. The scale of the structures observed in materials characterization ranges from angstroms, such as in the imaging of individual atoms and chemical bonds, up to centimeters, such as in the imaging of coarse grain structures in metals. While many characterization techniques have been practiced for centuries, such as basic optical microscopy, new technique ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Adhesion
Adhesion is the tendency of dissimilar particles or interface (matter), surfaces to cling to one another. (Cohesion (chemistry), Cohesion refers to the tendency of similar or identical particles and surfaces to cling to one another.) The forces that cause adhesion and cohesion can be divided into several types. The intermolecular forces responsible for the function of various kinds of stickers and sticky tape fall into the categories of chemical adhesion, dispersive adhesion, and diffusive adhesion. In addition to the cumulative magnitudes of these intermolecular forces, there are also certain emergent mechanical effects. Surface energy Surface energy is conventionally defined as the work (physics), work that is required to build an area of a particular surface. Another way to view the surface energy is to relate it to the work required to cleave a bulk sample, creating two surfaces. If the new surfaces are identical, the surface energy γ of each surface is equal to h ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Metakaolin
Metakaolin is the anhydrous calcined form of the clay mineral kaolinite. Rocks that are rich in kaolinite are known as china clay or kaolin, traditionally used in the manufacture of porcelain. The particle size of metakaolin is smaller than cement particles, but not as fine as silica fume. Kaolinite sources The quality and reactivity of metakaolin is strongly dependent of the characteristics of the raw material used. Metakaolin can be produced from a variety of primary and secondary sources containing kaolinite:Metakaolin is a dehydrated form of kaolinite, a type of clay mineral. Kaolinite-rich minerals are also referred to as china clay or kaolin, which are traditionally utilized in the production of porcelain. The grain size of metakaolin is less than that of cement particles, but it's not as minuscule as silica fume. * High purity kaolin deposits * Kaolinite deposits or tropical soils of lower purity * Paper sludge waste (if containing kaolinite) * Oil sand tailings (if con ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nanomaterials
Nanomaterials describe, in principle, chemical substances or materials of which a single unit is sized (in at least one dimension) between 1 and 100 nm (the usual definition of nanoscale). Nanomaterials research takes a materials science-based approach to nanotechnology, leveraging advances in materials metrology and synthesis which have been developed in support of microfabrication research. Materials with structure at the nanoscale often have unique optical, electronic, thermo-physical or mechanical properties. Nanomaterials are slowly becoming commercialized and beginning to emerge as commodities. Definition In ISO/TS 80004, ''nanomaterial'' is defined as the "material with any external dimension in the nanoscale or having internal structure or surface structure in the nanoscale", with ''nanoscale'' defined as the "length range approximately from 1 nm to 100 nm". This includes both ''nano-objects'', which are discrete pieces of material, and ''nanostructu ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Carbon Fibers
Carbon fibers American and British English spelling differences, or carbon fibres (alternatively CF, graphite fiber or graphite fibre) are fibers about in diameter and composed mostly of carbon atoms. Carbon fibers have several advantages: high stiffness, high tensile strength, high strength to weight ratio, high chemical resistance, high-temperature tolerance, and low thermal expansion. These properties have made carbon fiber very popular in aerospace, civil engineering, military, motorsports, and other competition sports. However, they are relatively expensive compared to similar fibers, such as glass fiber, basalt fibers, or plastic fibers. To produce a carbon fiber, the carbon atoms are bonded together in crystals that are more or less aligned parallel to the fiber's long axis as the crystal alignment gives the fiber a high strength-to-volume ratio (in other words, it is strong for its size). Several thousand carbon fibers are bundled together to form a tow (fibre), tow, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Amorphous
In condensed matter physics and materials science, an amorphous solid (or non-crystalline solid) is a solid that lacks the long-range order that is a characteristic of a crystal. The terms "glass" and "glassy solid" are sometimes used synonymously with amorphous solid; however, these terms refer specifically to amorphous materials that undergo a glass transition. Examples of amorphous solids include glasses, metallic glasses, and certain types of plastics and polymers. Etymology The term "Amorphous" comes from the Greek language, Greek ''a'' ("without"), and ''morphé'' ("shape, form"). Structure Amorphous materials have an internal structure of molecular-scale structural blocks that can be similar to the basic structural units in the crystalline phase of the same compound. Unlike in crystalline materials, however, no long-range regularity exists: amorphous materials cannot be described by the repetition of a finite unit cell. Statistical measures, such as the atomic density ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Crystalline
A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macroscopic single crystals are usually identifiable by their geometrical shape, consisting of flat faces with specific, characteristic orientations. The scientific study of crystals and crystal formation is known as crystallography. The process of crystal formation via mechanisms of crystal growth is called crystallization or solidification. The word ''crystal'' derives from the Ancient Greek word (), meaning both "ice" and " rock crystal", from (), "icy cold, frost". Examples of large crystals include snowflakes, diamonds, and table salt. Most inorganic solids are not crystals but polycrystals, i.e. many microscopic crystals fused together into a single solid. Polycrystals include most metals, rocks, ceramics, and ice. A third categor ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Triboelectric Charging
The triboelectric effect (also known as triboelectricity, triboelectric charging, triboelectrification, or tribocharging) describes electric charge transfer between two objects when they contact or slide against each other. It can occur with different materials, such as the sole of a shoe on a carpet, or between two pieces of the same material. It is ubiquitous, and occurs with differing amounts of charge transfer (tribocharge) for all solid materials. There is evidence that tribocharging can occur between combinations of solids, liquids and gases, for instance liquid flowing in a solid tube or an aircraft flying through air. Often static electricity is a consequence of the triboelectric effect when the charge stays on one or both of the objects and is not conducted away. The term triboelectricity has been used to refer to the field of study or the general phenomenon of the triboelectric effect, or to the static electricity that results from it. When there is no sliding, triboc ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Thermodynamic
Thermodynamics is a branch of physics that deals with heat, work, and temperature, and their relation to energy, entropy, and the physical properties of matter and radiation. The behavior of these quantities is governed by the four laws of thermodynamics, which convey a quantitative description using measurable macroscopic physical quantities but may be explained in terms of microscopic constituents by statistical mechanics. Thermodynamics applies to various topics in science and engineering, especially physical chemistry, biochemistry, chemical engineering, and mechanical engineering, as well as other complex fields such as meteorology. Historically, thermodynamics developed out of a desire to increase the efficiency of early steam engines, particularly through the work of French physicist Sadi Carnot (1824) who believed that engine efficiency was the key that could help France win the Napoleonic Wars. Scots-Irish physicist Lord Kelvin was the first to formulate a concise d ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
