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Faraday Constant
In physical chemistry, the Faraday constant (symbol , sometimes stylized as ℱ) is a physical constant defined as the quotient of the total electric charge () by the amount () of elementary charge carriers in any given sample of matter: it is expressed in units of coulombs per mole (C/mol). As such, it represents the " molar elementary charge", that is, the electric charge of one mole of elementary carriers (e.g., protons). It is named after the English scientist Michael Faraday. Since the 2019 revision of the SI, the Faraday constant has an exactly defined value, the product of the elementary charge (, in coulombs) and the Avogadro constant (, in reciprocal moles): : Derivation The Faraday constant can be thought of as the proportionality factor between the charge in coulombs (used in physics and in practical electrical measurements) and the amount of substance in moles (used in chemistry), and is therefore of particular use in electrochemistry, particularly in ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Michael Faraday
Michael Faraday (; 22 September 1791 – 25 August 1867) was an English chemist and physicist who contributed to the study of electrochemistry and electromagnetism. His main discoveries include the principles underlying electromagnetic induction, diamagnetism, and electrolysis. Although Faraday received little formal education, as a self-made man, he was one of the most influential scientists in history. It was by his research on the magnetic field around a Electrical conductor, conductor carrying a direct current that Faraday established the concept of the electromagnetic field in physics. Faraday also established that magnetism could Faraday effect, affect rays of light and that there was an underlying relationship between the two phenomena. the 1911 ''Encyclopædia Britannica''. He similarly discovered the principles of electromagnetic induction, diamagnetism, and the Faraday's laws of electrolysis, laws of electrolysis. His inventions of electric motor, electromagnetic rotar ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electrolysis
In chemistry and manufacturing, electrolysis is a technique that uses Direct current, direct electric current (DC) to drive an otherwise non-spontaneous chemical reaction. Electrolysis is commercially important as a stage in the separation of chemical element, elements from naturally occurring sources such as ores using an electrolytic cell. The voltage that is needed for electrolysis to occur is called the decomposition potential. The word "lysis" means to separate or break, so in terms, electrolysis would mean "breakdown via electricity." Etymology The word "electrolysis" was introduced by Michael Faraday in 1834, using the Greek language, Greek words "amber", which since the 17th century was associated with electrical phenomena, and ' meaning "dissolution". Nevertheless, electrolysis, as a tool to study chemical reactions and obtain pure chemical element, elements, precedes the coinage of the term and formal description by Faraday. History In the early nineteenth century, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electrochemical Concepts
Electrochemistry is the branch of physical chemistry concerned with the relationship between Electric potential, electrical potential difference and identifiable chemical change. These reactions involve Electron, electrons moving via an electronically conducting phase (typically an external electrical circuit, but not necessarily, as in Electroless nickel-phosphorus plating, electroless plating) between electrodes separated by an ionically conducting and electronically insulating electrolyte (or ionic chemical species, species in a Solution (chemistry), solution). When a chemical reaction is driven by an electrical Voltage, potential difference, as in electrolysis, or if a potential difference results from a chemical reaction as in an electric battery or fuel cell, it is called an ''electrochemical'' reaction. Unlike in other chemical reactions, in electrochemical reactions electrons are not transferred directly between atoms, ions, or molecules, but via the aforementioned electron ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Faraday Cup
A Faraday cup is a metal (conductive) cup designed to catch charged particles. The resulting current can be measured and used to determine the number of ions or electrons hitting the cup. The Faraday cup was named after Michael Faraday who first theorized ions around 1830. Examples of devices which use Faraday cups include space probes (Voyager 1, & 2, Parker Solar Probe, etc.) and mass spectrometers. Faraday cups can also be used to measure charged aerosol particles. Principle of operation When a beam or packet of ions or electrons (e.g. from an electron beam) hits the metallic body of the cup, the apparatus gains a small net charge. The cup can then be discharged to measure a small current proportional to the charge carried by the impinging ions or electrons. By measuring the electric current (the number of electrons flowing through the circuit per second) in the cup, the number of charges can be determined. For a continuous beam of ions (assumed to be singly charged) or ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Faraday's Laws Of Electrolysis
Faraday's laws of electrolysis are quantitative relationships based on the electrochemical research published by Michael Faraday in 1833. First law Michael Faraday reported that the mass () of a substance deposited or liberated at an electrode is directly proportional to the charge (, for which the SI unit is the ampere-second or coulomb). m \propto Q \quad \implies \quad \frac = Z Here, the constant of proportionality, , is called the electro-chemical equivalent (ECE) of the substance. Thus, the ECE can be defined as the mass of the substance deposited or liberated per unit charge. Second law Faraday discovered that when the same amount of electric current is passed through different electrolytes connected in series, the masses of the substances deposited or liberated at the electrodes are directly proportional to their respective chemical equivalent/ equivalent weight (). This turns out to be the molar mass () divided by the valence () : \begin & m \propto E; \quad ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Faraday Efficiency
In electrochemistry, Faraday efficiency (also called faradaic efficiency, faradaic yield, coulombic efficiency, or current efficiency) describes the efficiency with which charge (electrons) is transferred in a system facilitating an electrochemical reaction. The word "Faraday" in this term has two interrelated aspects: first, the historic unit for charge is the faraday (F), but has since been replaced by the coulomb (C); and secondly, the related Faraday's constant () correlates charge with moles of matter and electrons (amount of substance). This phenomenon was originally understood through Michael Faraday's work and expressed in his laws of electrolysis. Sources of faradaic loss Faradaic losses are experienced by both electrolytic and galvanic cells when electrons or ions participate in unwanted side reactions. These losses appear as heat and/or chemical byproducts. An example can be found in the oxidation of water to oxygen at the positive electrode in electrolysis. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electrical Capacitance
Capacitance is the ability of an object to store electric charge. It is measured by the change in charge in response to a difference in electric potential, expressed as the ratio of those quantities. Commonly recognized are two closely related notions of capacitance: ''self capacitance'' and ''mutual capacitance''. An object that can be electrically charged exhibits self capacitance, for which the electric potential is measured between the object and ground. Mutual capacitance is measured between two components, and is particularly important in the operation of the capacitor, an elementary linear electronic component designed to add capacitance to an electric circuit. The capacitance between two conductors depends only on the geometry; the opposing surface area of the conductors and the distance between them; and the permittivity of any dielectric material between them. For many dielectric materials, the permittivity, and thus the capacitance, is independent of the potential di ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Farad
The farad (symbol: F) is the unit of electrical capacitance, the ability of a body to store an electrical charge, in the International System of Units, International System of Units (SI), equivalent to 1 coulomb per volt (C/V). It is named after the English physicist Michael Faraday (1791–1867). In SI base units 1 F = 1 kilogram, kg−1⋅meter, m−2⋅second, s4⋅ampere, A2. Definition The capacitance of a capacitor is one farad when one coulomb of charge changes the potential between the plates by one volt. Equally, one farad can be described as the capacitance which stores a one-coulomb charge across a potential difference of one volt. The relationship between capacitance, charge, and potential difference is linear. For example, if the potential difference across a capacitor is halved, the quantity of charge stored by that capacitor will also be halved. For most applications, the farad is an impractically large unit of capacitance. Most electrical and electron ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Capacitance
Capacitance is the ability of an object to store electric charge. It is measured by the change in charge in response to a difference in electric potential, expressed as the ratio of those quantities. Commonly recognized are two closely related notions of capacitance: ''self capacitance'' and ''mutual capacitance''. An object that can be electrically charged exhibits self capacitance, for which the electric potential is measured between the object and ground. Mutual capacitance is measured between two components, and is particularly important in the operation of the capacitor, an elementary linear electronic component designed to add capacitance to an electric circuit. The capacitance between two conductors depends only on the geometry; the opposing surface area of the conductors and the distance between them; and the permittivity of any dielectric material between them. For many dielectric materials, the permittivity, and thus the capacitance, is independent of the potential ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Farad
The farad (symbol: F) is the unit of electrical capacitance, the ability of a body to store an electrical charge, in the International System of Units, International System of Units (SI), equivalent to 1 coulomb per volt (C/V). It is named after the English physicist Michael Faraday (1791–1867). In SI base units 1 F = 1 kilogram, kg−1⋅meter, m−2⋅second, s4⋅ampere, A2. Definition The capacitance of a capacitor is one farad when one coulomb of charge changes the potential between the plates by one volt. Equally, one farad can be described as the capacitance which stores a one-coulomb charge across a potential difference of one volt. The relationship between capacitance, charge, and potential difference is linear. For example, if the potential difference across a capacitor is halved, the quantity of charge stored by that capacitor will also be halved. For most applications, the farad is an impractically large unit of capacitance. Most electrical and electron ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electrical Charge
Electricity is the set of physical phenomena associated with the presence and motion of matter possessing an electric charge. Electricity is related to magnetism, both being part of the phenomenon of electromagnetism, as described by Maxwell's equations. Common phenomena are related to electricity, including lightning, static electricity, electric heating, electric discharges and many others. The presence of either a positive or negative electric charge produces an electric field. The motion of electric charges is an electric current and produces a magnetic field. In most applications, Coulomb's law determines the force acting on an electric charge. Electric potential is the Work (physics), work done to move an electric charge from one point to another within an electric field, typically measured in volts. Electricity plays a central role in many modern technologies, serving in electric power where electric current is used to energise equipment, and in electronics dealing w ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Perchloric Acid
Perchloric acid is a mineral acid with the formula H Cl O4. It is an oxoacid of chlorine. Usually found as an aqueous solution, this colorless compound is a stronger acid than sulfuric acid, nitric acid and hydrochloric acid. It is a powerful oxidizer when hot, but aqueous solutions up to approximately 70% by weight at room temperature are generally safe, only showing strong acid features and no oxidizing properties. Perchloric acid is useful for preparing perchlorate salts, especially ammonium perchlorate, an important rocket fuel component. Perchloric acid is dangerously corrosive and readily forms potentially explosive mixtures. History Perchloric acid was first synthesized (together with potassium perchlorate) by Austrian chemist and called "oxygenated chloric acid" in mid-1810s. French pharmacist Georges-Simon Serullas introduced the modern designation along with discovering its solid monohydrate, which he mistook for an anhydride. Berzelius produced dilute perchloric acid ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
