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Evolved Gas Analysis
Evolved gas analysis (EGA) is a method used to study the gas evolved from a heated sample that undergoes decomposition or desorption. It is either possible just to detect evolved gases using evolved gas detection (EGD) or to analyse explicitly which gases evolved using evolved gas analysis (EGA). Therefore different analytical methods can be employed such as mass spectrometry, Fourier transform spectroscopy, gas chromatography, or optical in-situ evolved gas analysis. By coupling the thermal analysis instrument, e. g. TGA (thermogravimetry) or DSC (differential scanning calorimetry), with a fast Quadrupole Mass Spectrometer (QMS) the detection of gas separation and identification of the separated components are possible in exact time correlation with the other thermal analysis signals. DSC/TGA-QMS or TGA-QMS yields information on the composition (mass numbers of elements and molecules) of the evolved gases. It allows fast and easy interpretation of atomic/inorganic vapors and standa ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Desorption
Desorption is the physical process where a previously adsorbed substance is released from a surface. This happens when a molecule gains enough energy to overcome the activation barrier of the bounding energy that keeps it in the surface. There are a lot of different types of desorption, depending on the mechanism that separates the adsorbate from the substrate; therefore there is no one equation that describes the process. Note that desorption is the opposite of adsorption, which differs from absorption because it refers to substances being stuck to the surface, as opposed to being absorbed into the bulk. Desorption can occur after a reaction between a catalyst and an adsorbed compound; or during stripping or chromatography which are types of separation processes. Desorption mechanisms Depending on the nature of the adsorbent-to-surface bond, there are a multitude of mechanisms for desorption. The surface bond of a sorbant can be cleaved thermally, through chemical reacti ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Mass Spectrometry
Mass spectrometry (MS) is an analytical technique that is used to measure the mass-to-charge ratio of ions. The results are presented as a '' mass spectrum'', a plot of intensity as a function of the mass-to-charge ratio. Mass spectrometry is used in many different fields and is applied to pure samples as well as complex mixtures. A mass spectrum is a type of plot of the ion signal as a function of the mass-to-charge ratio. These spectra are used to determine the elemental or isotopic signature of a sample, the masses of particles and of molecules, and to elucidate the chemical identity or structure of molecules and other chemical compounds. In a typical MS procedure, a sample, which may be solid, liquid, or gaseous, is ionized, for example by bombarding it with a beam of electrons. This may cause some of the sample's molecules to break up into positively charged fragments or simply become positively charged without fragmenting. These ions (fragments) are then separated acco ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fourier Transform Spectroscopy
Fourier-transform spectroscopy is a measurement technique whereby spectra are collected based on measurements of the coherence of a radiative source, using time-domain or space-domain measurements of the radiation, electromagnetic or not. It can be applied to a variety of types of ''spectroscopy'' including optical spectroscopy, infrared spectroscopy ( FTIR, FT-NIRS), nuclear magnetic resonance (NMR) and magnetic resonance spectroscopic imaging (MRSI), mass spectrometry and electron spin resonance spectroscopy. There are several methods for measuring the temporal coherence of the light (see: field-autocorrelation), including the continuous-wave and the pulsed Fourier-transform spectrometer or Fourier-transform spectrograph. The term "Fourier-transform spectroscopy" reflects the fact that in all these techniques, a Fourier transform is required to turn the raw data into the actual spectrum, and in many of the cases in optics involving interferometers, is based on the Wiene ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Gas Chromatography
Gas chromatography (GC) is a common type of chromatography used in analytical chemistry for separating and analyzing compounds that can be vaporized without decomposition. Typical uses of GC include testing the purity of a particular substance, or separating the different components of a mixture. In preparative chromatography, GC can be used to prepare pure compounds from a mixture. Gas chromatography is also sometimes known as vapor-phase chromatography (VPC), or gas–liquid partition chromatography (GLPC). These alternative names, as well as their respective abbreviations, are frequently used in scientific literature. Gas chromatography is the process of separating compounds in a mixture by injecting a gaseous or liquid sample into a mobile phase, typically called the carrier gas, and passing the gas through a stationary phase. The mobile phase is usually an inert gas or an unreactive gas such as helium, argon, nitrogen or hydrogen. The stationary phase is a microscopic l ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Thermogravimetry
Thermogravimetric analysis or thermal gravimetric analysis (TGA) is a method of thermal analysis in which the mass of a sample is measured over time as the temperature changes. This measurement provides information about physical phenomena, such as phase transitions, absorption, adsorption and desorption; as well as chemical phenomena including chemisorptions, thermal decomposition, and solid-gas reactions (e.g., oxidation or reduction). Thermogravimetric analyzer Thermogravimetric analysis (TGA) is conducted on an instrument referred to as a thermogravimetric analyzer. A thermogravimetric analyzer continuously measures mass while the temperature of a sample is changed over time. Mass, temperature, and time are considered base measurements in thermogravimetric analysis while many additional measures may be derived from these three base measurements. A typical thermogravimetric analyzer consists of a precision balance with a sample pan located inside a furnace with a programmab ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Differential Scanning Calorimetry
Differential scanning calorimetry (DSC) is a thermoanalytical technique in which the difference in the amount of heat required to increase the temperature of a sample and reference is measured as a function of temperature. Both the sample and reference are maintained at nearly the same temperature throughout the experiment. Generally, the temperature program for a DSC analysis is designed such that the sample holder temperature increases linearly as a function of time. The reference sample should have a well-defined heat capacity over the range of temperatures to be scanned. The technique was developed by E. S. Watson and M. J. O'Neill in 1962, and introduced commercially at the 1963 Pittsburgh Conference on Analytical Chemistry and Applied Spectroscopy. The first adiabatic differential scanning calorimeter that could be used in biochemistry was developed by P. L. Privalov and D. R. Monaselidze in 1964 at Institute of Physics in Tbilisi, Georgia. The term DSC was coined to descr ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Phoenix Lander
''Phoenix'' was an uncrewed space probe that landed on the surface of Mars on May 25, 2008, and operated until November 2, 2008. ''Phoenix'' was operational on Mars for sols ( days). Its instruments were used to assess the local habitability and to research the history of water on Mars. The mission was part of the Mars Scout Program; its total cost was $420 million, including the cost of launch. The multi-agency program was led by the Lunar and Planetary Laboratory at the University of Arizona, with project management by NASA's Jet Propulsion Laboratory. Academic and industrial partners included universities in the United States, Canada, Switzerland, Denmark, Germany, the United Kingdom, NASA, the Canadian Space Agency, the Finnish Meteorological Institute, Lockheed Martin Space Systems, MacDonald Dettwiler & Associates (MDA) and other aerospace companies. It was the first NASA mission to Mars led by a public university. ''Phoenix'' was NASA's sixth successful landing ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Curiosity (rover)
''Curiosity'' is a car-sized Mars rover designed to explore the Gale crater on Mars as part of NASA's Mars Science Laboratory (MSL) mission. ''Curiosity'' was launched from Cape Canaveral (CCAFS) on November 26, 2011, at 15:02:00 UTC and landed on Aeolis Palus inside Gale crater on Mars on August 6, 2012, 05:17:57 UTC. The Bradbury Landing site was less than from the center of the rover's touchdown target after a journey. Mission goals include an investigation of the Martian climate and geology, assessment of whether the selected field site inside Gale has ever offered environmental conditions favorable for microbial life (including investigation of the role of water), and planetary habitability studies in preparation for human exploration. In December 2012, ''Curiosity'' two-year mission was extended indefinitely, and on August 5, 2017, NASA celebrated the fifth anniversary of the ''Curiosity'' rover landing. On August 6, 2022, a detailed overview of accomplishme ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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