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Differential Optical Absorption Spectroscopy
In atmospheric chemistry, differential optical absorption spectroscopy (DOAS) is used to measure concentrations of trace gases. When combined with basic optical spectrometers such as prisms or diffraction gratings and automated, ground-based observation platforms, it presents a cheap and powerful means for the measurement of trace gas species such as ozone and nitrogen dioxide. Typical setups allow for detection limits corresponding to optical depths of 0.0001 along lightpaths of up to typically 15 km and thus allow for the detection also of weak absorbers, such as water vapour, Nitrous acid, Formaldehyde, Tetraoxygen, Iodine oxide, Bromine oxide and Chlorine oxide. Theory DOAS instruments are often divided into two main groups: passive and active ones. The active DOAS system such as longpath(LP)-systems and cavity-enhanced(CE) DOAS systems have their own light-source, whereas passive ones use the sun as their light source, e.g. MAX(Multi-axial)-DOAS. Also the moon can be use ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Atmospheric Chemistry
Atmospheric chemistry is a branch of atmospheric science in which the chemistry of the Earth's atmosphere and that of other planets is studied. It is a multidisciplinary approach of research and draws on environmental chemistry, physics, meteorology, computer modeling, oceanography, geology and volcanology and other disciplines. Research is increasingly connected with other areas of study such as climatology. The composition and chemistry of the Earth's atmosphere is of importance for several reasons, but primarily because of the interactions between the atmosphere and living organisms. The composition of the Earth's atmosphere changes as result of natural processes such as volcano emissions, lightning and bombardment by solar particles from corona. It has also been changed by human activity and some of these changes are harmful to human health, crops and ecosystems. Examples of problems which have been addressed by atmospheric chemistry include acid rain, ozone depletion, photo ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chemical Substance
A chemical substance is a form of matter having constant chemical composition and characteristic properties. Some references add that chemical substance cannot be separated into its constituent elements by physical separation methods, i.e., without breaking chemical bonds. Chemical substances can be simple substances (substances consisting of a single chemical element), chemical compounds, or alloys. Chemical substances are often called 'pure' to set them apart from mixtures. A common example of a chemical substance is pure water; it has the same properties and the same ratio of hydrogen to oxygen whether it is isolated from a river or made in a laboratory. Other chemical substances commonly encountered in pure form are diamond (carbon), gold, table salt (sodium chloride) and refined sugar (sucrose). However, in practice, no substance is entirely pure, and chemical purity is specified according to the intended use of the chemical. Chemical substances exist as solids, liquids, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Wavelength
In physics, the wavelength is the spatial period of a periodic wave—the distance over which the wave's shape repeats. It is the distance between consecutive corresponding points of the same phase on the wave, such as two adjacent crests, troughs, or zero crossings, and is a characteristic of both traveling waves and standing waves, as well as other spatial wave patterns. The inverse of the wavelength is called the spatial frequency. Wavelength is commonly designated by the Greek letter ''lambda'' (λ). The term ''wavelength'' is also sometimes applied to modulated waves, and to the sinusoidal envelopes of modulated waves or waves formed by interference of several sinusoids. Assuming a sinusoidal wave moving at a fixed wave speed, wavelength is inversely proportional to frequency of the wave: waves with higher frequencies have shorter wavelengths, and lower frequencies have longer wavelengths. Wavelength depends on the medium (for example, vacuum, air, or water) that a wav ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Optical Depth
In physics, optical depth or optical thickness is the natural logarithm of the ratio of incident to ''transmitted'' radiant power through a material. Thus, the larger the optical depth, the smaller the amount of transmitted radiant power through the material. Spectral optical depth or spectral optical thickness is the natural logarithm of the ratio of incident to transmitted spectral radiant power through a material. Optical depth is dimensionless, and in particular is not a length, though it is a monotonically increasing function of optical path length, and approaches zero as the path length approaches zero. The use of the term "optical density" for optical depth is discouraged. In chemistry, a closely related quantity called "absorbance" or "decadic absorbance" is used instead of optical depth: the common logarithm of the ratio of incident to transmitted radiant power through a material, that is the optical depth divided by ln 10. Mathematical definitions Optical depth O ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Atmosphere
An atmosphere () is a layer of gas or layers of gases that envelop a planet, and is held in place by the gravity of the planetary body. A planet retains an atmosphere when the gravity is great and the temperature of the atmosphere is low. A stellar atmosphere is the outer region of a star, which includes the layers above the opaque photosphere; stars of low temperature might have outer atmospheres containing compound molecules. The atmosphere of Earth is composed of nitrogen (78%), oxygen (21%), argon (0.9%), carbon dioxide (0.04%) and trace gases. Most organisms use oxygen for respiration; lightning and bacteria perform nitrogen fixation to produce ammonia that is used to make nucleotides and amino acids; plants, algae, and cyanobacteria use carbon dioxide for photosynthesis. The layered composition of the atmosphere minimises the harmful effects of sunlight, ultraviolet radiation, the solar wind, and cosmic rays to protect organisms from genetic damage. The current comp ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Invertible Matrix
In linear algebra, an -by- square matrix is called invertible (also nonsingular or nondegenerate), if there exists an -by- square matrix such that :\mathbf = \mathbf = \mathbf_n \ where denotes the -by- identity matrix and the multiplication used is ordinary matrix multiplication. If this is the case, then the matrix is uniquely determined by , and is called the (multiplicative) ''inverse'' of , denoted by . Matrix inversion is the process of finding the matrix that satisfies the prior equation for a given invertible matrix . A square matrix that is ''not'' invertible is called singular or degenerate. A square matrix is singular if and only if its determinant is zero. Singular matrices are rare in the sense that if a square matrix's entries are randomly selected from any finite region on the number line or complex plane, the probability that the matrix is singular is 0, that is, it will "almost never" be singular. Non-square matrices (-by- matrices for which ) do not hav ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Spectral Resolution
The spectral resolution of a spectrograph, or, more generally, of a frequency spectrum, is a measure of its ability to resolve features in the electromagnetic spectrum. It is usually denoted by \Delta\lambda, and is closely related to the resolving power of the spectrograph, defined as R = \frac, where \Delta\lambda is the smallest difference in wavelengths that can be distinguished at a wavelength of \lambda. For example, the Space Telescope Imaging Spectrograph (STIS) can distinguish features 0.17 nm apart at a wavelength of 1000 nm, giving it a resolution of 0.17 nm and a resolving power of about 5,900. An example of a high resolution spectrograph is the ''Cryogenic High-Resolution IR Echelle Spectrograph'' (CRIRES+) installed at ESO's Very Large Telescope, which has a spectral resolving power of up to 100,000. Doppler effect The spectral resolution can also be expressed in terms of physical quantities, such as velocity; then it describes the difference between vel ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Equation
In mathematics, an equation is a formula that expresses the equality of two expressions, by connecting them with the equals sign . The word ''equation'' and its cognates in other languages may have subtly different meanings; for example, in French an ''équation'' is defined as containing one or more variables, while in English, any well-formed formula consisting of two expressions related with an equals sign is an equation. ''Solving'' an equation containing variables consists of determining which values of the variables make the equality true. The variables for which the equation has to be solved are also called unknowns, and the values of the unknowns that satisfy the equality are called solutions of the equation. There are two kinds of equations: identities and conditional equations. An identity is true for all values of the variables. A conditional equation is only true for particular values of the variables. An equation is written as two expressions, connected by a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Column Density
The area density (also known as areal density, surface density, superficial density, areic density, mass thickness, column density, or density thickness) of a two-dimensional object is calculated as the mass per unit area. The SI derived unit is the kilogram per square metre (kg·m−2). A related '' area number density'' can be defined by replacing mass in by number of particles or other countable quantity. In the paper and fabric industries, it is called grammage and is expressed in grams per square meter (g/m2); for paper in particular, it may be expressed as pounds per ream of standard sizes ("basis ream"). Formulation Area density can be calculated as: \rho_A = \frac or \rho_A = \rho \cdot l where, Column density A special type of area density is called ''column (mass) density'' (also ''columnar mass density''), denoted ''ρ''A or ''σ''. It is the mass of substance per unit area integrated along a path; It is obtained integrating volumetric density \rho ov ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Constant (mathematics)
In mathematics, the word constant conveys multiple meanings. As an adjective, it refers to non-variance (i.e. unchanging with respect to some other value); as a noun, it has two different meanings: * A fixed and well-defined number or other non-changing mathematical object. The terms '' mathematical constant'' or '' physical constant'' are sometimes used to distinguish this meaning. * A function whose value remains unchanged (i.e., a constant function). Such a constant is commonly represented by a variable which does not depend on the main variable(s) in question. For example, a general quadratic function is commonly written as: :a x^2 + b x + c\, , where , and are constants (or parameters), and a variable—a placeholder for the argument of the function being studied. A more explicit way to denote this function is :x\mapsto a x^2 + b x + c \, , which makes the function-argument status of (and by extension the constancy of , and ) clear. In this example , and are co ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Integral
In mathematics Mathematics is an area of knowledge that includes the topics of numbers, formulas and related structures, shapes and the spaces in which they are contained, and quantities and their changes. These topics are represented in modern mathematics ..., an integral assigns numbers to functions in a way that describes Displacement (geometry), displacement, area, volume, and other concepts that arise by combining infinitesimal data. The process of finding integrals is called integration. Along with Derivative, differentiation, integration is a fundamental, essential operation of calculus,Integral calculus is a very well established mathematical discipline for which there are many sources. See and , for example. and serves as a tool to solve problems in mathematics and physics involving the area of an arbitrary shape, the length of a curve, and the volume of a solid, among others. The integrals enumerated here are those termed definite integrals, which can be int ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cross Section (physics)
In physics, the cross section is a measure of the probability that a specific process will take place when some kind of radiant excitation (e.g. a particle beam, sound wave, light, or an X-ray) intersects a localized phenomenon (e.g. a particle or density fluctuation). For example, the Rutherford cross-section is a measure of probability that an alpha particle will be deflected by a given angle during an interaction with an atomic nucleus. Cross section is typically denoted ( sigma) and is expressed in units of area, more specifically in barns. In a way, it can be thought of as the size of the object that the excitation must hit in order for the process to occur, but more exactly, it is a parameter of a stochastic process. In classical physics, this probability often converges to a deterministic proportion of excitation energy involved in the process, so that, for example, with light scattering off of a particle, the cross section specifies the amount of optical power scattere ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
