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Direct Dye
A substantive dye or direct dye is a dye that adheres to its substrate, typically a textile, by non-ionic forces. Overview The amount of this attraction is known as "substantivity": the higher the substantivity the greater the attraction of the dye for the fiber. Substantive dyes work best on textiles with high contents of cellulose, such as cotton. In contrast to direct dyes, wool and leather goods are dyed by the process of ion exchange, exploiting the cationic nature of proteins near neutral pH. The development of substantive dyes helped make mordant dyes obsolete. Substantive dyes are set in a slightly basic or neutral environment at temperatures close to boiling point. They are set by formation of aggregates of dyes within interstices of the fibres. Aggregation is enhanced by extended aromatic rings.Klaus Hunger, Peter Mischke, Wolfgang Rieper, Roderich Raue, Klaus Kunde, Aloys Engel. "Azo Dyes". ''Ullmann's Encyclopedia of Industrial Chemistry''. Weinheim: Wiley-VCH . Gal ...
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Fiber
Fiber (spelled fibre in British English; from ) is a natural or artificial substance that is significantly longer than it is wide. Fibers are often used in the manufacture of other materials. The strongest engineering materials often incorporate fibers, for example carbon fiber and ultra-high-molecular-weight polyethylene. Synthetic fibers can often be produced very cheaply and in large amounts compared to natural fibers, but for clothing natural fibers have some benefits, such as comfort, over their synthetic counterparts. Natural fibers Natural fibers develop or occur in the fiber shape, and include those produced by plants, animals, and geological processes. They can be classified according to their origin: * Vegetable fibers are generally based on arrangements of cellulose, often with lignin: examples include cotton, hemp, jute, flax, abaca, piña, ramie, sisal, bagasse, and banana. Plant fibers are employed in the manufacture of paper and textile ...
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Ion Exchange
Ion exchange is a reversible interchange of one species of ion present in an insoluble solid with another of like charge present in a solution surrounding the solid. Ion exchange is used in softening or demineralizing of water, purification of chemicals, and separation of substances. Ion exchange usually describes a process of purification of aqueous solutions using solid polymeric ion-exchange resin. More precisely, the term encompasses a large variety of processes where ions are exchanged between two electrolytes. Aside from its use to purify drinking water, the technique is widely applied for purification and separation of a variety of industrially and medicinally important chemicals. Although the term usually refers to applications of synthetic (human-made) resins, it can include many other materials such as soil. Typical ion exchangers are ion-exchange resins (functionalized porous or gel polymer), zeolites, montmorillonite, clay, and soil humus. Ion exchangers are ei ...
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Mordant
A mordant or dye fixative is a substance used to set (i.e., bind) dyes on fabrics. It does this by forming a coordination complex with the dye, which then attaches to the fabric (or tissue). It may be used for dyeing fabrics or for intensifying stains in cell or tissue preparations. Although mordants are still used, especially by small batch dyers, they have been largely displaced in industry by substantive dyes.} The term mordant comes from the Latin ''mordere'', "to bite". In the past, it was thought that a mordant helped the dye "bite" onto the fiber so that it would hold fast during washing. A mordant is often a polyvalent metal ion, and one example is chromium (III). The resulting coordination complex of dye and ion is colloidal and can be either acidic or alkaline. Common dye mordants Mordants include tannic acid, oxalic acid, alum, chrome alum, sodium chloride, and certain salts of aluminium, chromium, copper, iron, iodine, potassium, sodium, tungsten, and tin. Io ...
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Direct Blue 1
Direct Blue 1 is an organic compound that is one of many azo dye Azo dyes are organic compounds bearing the functional group R−N=N−R′, in which R and R′ are usually aryl and substituted aryl groups. They are a commercially important family of azo compounds, i.e. compounds containing the C−N=N−C l ...s. This salt is used as a substantive dye for textiles with high contents of cellulose, i.e. cotton. It is prepared by the azo coupling of the aminonaphthalene and diazotized derivative of ''o''-dianisidine.Klaus Hunger, Peter Mischke, Wolfgang Rieper, Roderich Raue, Klaus Kunde, Aloys Engel: "Azo Dyes" in ''Ullmann's Encyclopedia of Industrial Chemistry'', 2005, Wiley-VCH, Weinheim.. References Azo dyes Naphthalenes Phenol ethers Sulfonates Organic sodium salts {{Ether-stub ...
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Direct Blue 15
Direct Blue 15 is an organic compound that is classified as an azo dye. It is a dark blue water soluble solid. It is a popular substantive dye, which means that it useful for dying cotton and related cellulosic materials. It is produced by azo coupling In organic chemistry, an azo coupling is an organic reaction, reaction between a diazonium compound () and another aromatic compound that produces an azo compound (). In this electrophilic aromatic substitution reaction, the aryldiazonium cation ... of o-dianisidine with the appropriate naphthalene disulfonate.. References {{Reflist Azo dyes Naphthalenesulfonic acids 1-Naphthols Naphthylamines ...
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Reactive Dye
In a reactive dye, a chromophore (an atom or group whose presence is responsible for the colour of a compound) contains a substituent that reacts with the substrate. Reactive dyes have good fastness properties owing to the covalent bonding that occurs during dyeing. Reactive dyeing is the most important method for coloring cellulose fibers. Reactive dyes can also be applied on wool and nylon; in the latter case they are applied under weakly acidic conditions. Reactive dyes have a low utilization degree compared to other types of dyestuff, since the functional group also bonds to water, creating hydrolysis.Horst Tappe, Walter Helmling, Peter Mischke, Karl Rebsamen, Uwe Reiher, Werner Russ, Ludwig Schläfer and Petra Vermehren "Reactive Dyes"in Ullmann's Encyclopedia of Industrial Chemistry 2000, Wiley-VCH, Weinheim. Usage Reactive dyes had been tested in the late 1800s involving both adding functionalized dyes to the substrate and then activating the substrate first followed by ...
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