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Degenerate Orbitals
In quantum mechanics, an energy level is degenerate if it corresponds to two or more different measurable states of a quantum system. Conversely, two or more different states of a quantum mechanical system are said to be degenerate if they give the same value of energy upon measurement. The number of different states corresponding to a particular energy level is known as the ''degree of degeneracy'' (or simply the ''degeneracy'') of the level. It is represented mathematically by the Hamiltonian for the system having more than one linearly independent eigenstate with the same energy eigenvalue. When this is the case, energy alone is not enough to characterize what state the system is in, and other quantum numbers are needed to characterize the exact state when distinction is desired. In classical mechanics, this can be understood in terms of different possible trajectories corresponding to the same energy. Degeneracy plays a fundamental role in quantum statistical mechanics. For a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Quantum Mechanics
Quantum mechanics is the fundamental physical Scientific theory, theory that describes the behavior of matter and of light; its unusual characteristics typically occur at and below the scale of atoms. Reprinted, Addison-Wesley, 1989, It is the foundation of all quantum physics, which includes quantum chemistry, quantum field theory, quantum technology, and quantum information science. Quantum mechanics can describe many systems that classical physics cannot. Classical physics can describe many aspects of nature at an ordinary (macroscopic and Microscopic scale, (optical) microscopic) scale, but is not sufficient for describing them at very small submicroscopic (atomic and subatomic) scales. Classical mechanics can be derived from quantum mechanics as an approximation that is valid at ordinary scales. Quantum systems have Bound state, bound states that are Quantization (physics), quantized to Discrete mathematics, discrete values of energy, momentum, angular momentum, and ot ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Scalar (physics)
Scalar quantities or simply scalars are physical quantities that can be described by a single pure number (a ''scalar'', typically a real number), accompanied by a unit of measurement, as in "10cm" (ten centimeters). Examples of scalar are length, mass, charge, volume, and time. Scalars may represent the magnitude of physical quantities, such as speed is to velocity. Scalars do not represent a direction. Scalars are unaffected by changes to a vector space basis (i.e., a coordinate rotation) but may be affected by translations (as in relative speed). A change of a vector space basis changes the description of a vector in terms of the basis used but does not change the vector itself, while a scalar has nothing to do with this change. In classical physics, like Newtonian mechanics, rotations and reflections preserve scalars, while in relativity, Lorentz transformations or space-time translations preserve scalars. The term "scalar" has origin in the multiplication o ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Normalizable Wave Function
In quantum physics, a wave function (or wavefunction) is a mathematical description of the quantum state of an isolated quantum system. The most common symbols for a wave function are the Greek letters and (lower-case and capital psi, respectively). Wave functions are complex-valued. For example, a wave function might assign a complex number to each point in a region of space. The Born rule provides the means to turn these complex probability amplitudes into actual probabilities. In one common form, it says that the squared modulus of a wave function that depends upon position is the probability density of measuring a particle as being at a given place. The integral of a wavefunction's squared modulus over all the system's degrees of freedom must be equal to 1, a condition called ''normalization''. Since the wave function is complex-valued, only its relative phase and relative magnitude can be measured; its value does not, in isolation, tell anything about the magnitudes or d ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Bound States
A bound state is a composite of two or more fundamental building blocks, such as particles, atoms, or bodies, that behaves as a single object and in which energy is required to split them. In quantum physics, a bound state is a quantum state of a particle subject to a potential such that the particle has a tendency to remain localized in one or more regions of space. The potential may be external or it may be the result of the presence of another particle; in the latter case, one can equivalently define a bound state as a state representing two or more particles whose interaction energy exceeds the total energy of each separate particle. One consequence is that, given a potential vanishing at infinity, negative-energy states must be bound. The energy spectrum of the set of bound states are most commonly discrete, unlike scattering states of free particles, which have a continuous spectrum. Although not bound states in the strict sense, metastable states with a net positive i ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Wave Function
In quantum physics, a wave function (or wavefunction) is a mathematical description of the quantum state of an isolated quantum system. The most common symbols for a wave function are the Greek letters and (lower-case and capital psi (letter), psi, respectively). Wave functions are complex number, complex-valued. For example, a wave function might assign a complex number to each point in a region of space. The Born rule provides the means to turn these complex probability amplitudes into actual probabilities. In one common form, it says that the squared modulus of a wave function that depends upon position is the probability density function, probability density of measurement in quantum mechanics, measuring a particle as being at a given place. The integral of a wavefunction's squared modulus over all the system's degrees of freedom must be equal to 1, a condition called ''normalization''. Since the wave function is complex-valued, only its relative phase and relative magnitud ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Analytical Expression
In mathematics, an expression or equation is in closed form if it is formed with constants, variables, and a set of functions considered as ''basic'' and connected by arithmetic operations (, and integer powers) and function composition. Commonly, the basic functions that are allowed in closed forms are ''n''th root, exponential function, logarithm, and trigonometric functions. However, the set of basic functions depends on the context. For example, if one adds polynomial roots to the basic functions, the functions that have a closed form are called elementary functions. The ''closed-form problem'' arises when new ways are introduced for specifying mathematical objects, such as limits, series, and integrals: given an object specified with such tools, a natural problem is to find, if possible, a ''closed-form expression'' of this object; that is, an expression of this object in terms of previous ways of specifying it. Example: roots of polynomials The quadratic ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Orthonormal
In linear algebra, two vectors in an inner product space are orthonormal if they are orthogonal unit vectors. A unit vector means that the vector has a length of 1, which is also known as normalized. Orthogonal means that the vectors are all perpendicular to each other. A set of vectors form an orthonormal set if all vectors in the set are mutually orthogonal and all of unit length. An orthonormal set which forms a basis is called an ''orthonormal basis''. Intuitive overview The construction of orthogonality of vectors is motivated by a desire to extend the intuitive notion of perpendicular vectors to higher-dimensional spaces. In the Cartesian plane, two vectors are said to be ''perpendicular'' if the angle between them is 90° (i.e. if they form a right angle). This definition can be formalized in Cartesian space by defining the dot product and specifying that two vectors in the plane are orthogonal if their dot product is zero. Similarly, the construction of the norm of ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Dimension
In physics and mathematics, the dimension of a mathematical space (or object) is informally defined as the minimum number of coordinates needed to specify any point within it. Thus, a line has a dimension of one (1D) because only one coordinate is needed to specify a point on itfor example, the point at 5 on a number line. A surface, such as the boundary of a cylinder or sphere, has a dimension of two (2D) because two coordinates are needed to specify a point on itfor example, both a latitude and longitude are required to locate a point on the surface of a sphere. A two-dimensional Euclidean space is a two-dimensional space on the plane. The inside of a cube, a cylinder or a sphere is three-dimensional (3D) because three coordinates are needed to locate a point within these spaces. In classical mechanics, space and time are different categories and refer to absolute space and time. That conception of the world is a four-dimensional space but not the one that w ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Vector Subspace
Vector most often refers to: * Euclidean vector, a quantity with a magnitude and a direction * Disease vector, an agent that carries and transmits an infectious pathogen into another living organism Vector may also refer to: Mathematics and physics * Vector (mathematics and physics) ** Row and column vectors, single row or column matrices ** Vector quantity ** Vector space ** Vector field, a vector for each point Molecular biology * Vector (molecular biology), a DNA molecule used as a vehicle to artificially carry foreign genetic material into another cell ** Cloning vector, a small piece of DNA into which a foreign DNA fragment can be inserted for cloning purposes ** Shuttle vector, a plasmid constructed so that it can propagate in two different host species ** Viral vector, a tool commonly used by molecular biologists to deliver genetic materials into cells Computer science * Vector, a one-dimensional array data structure ** Distance-vector routing protocol, a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Kernel (linear Algebra)
In mathematics, the kernel of a linear map, also known as the null space or nullspace, is the part of the domain which is mapped to the zero vector of the co-domain; the kernel is always a linear subspace of the domain. That is, given a linear map between two vector spaces and , the kernel of is the vector space of all elements of such that , where denotes the zero vector in , or more symbolically: \ker(L) = \left\ = L^(\mathbf). Properties The kernel of is a linear subspace of the domain .Linear algebra, as discussed in this article, is a very well established mathematical discipline for which there are many sources. Almost all of the material in this article can be found in , , and Strang's lectures. In the linear map L : V \to W, two elements of have the same image in if and only if their difference lies in the kernel of , that is, L\left(\mathbf_1\right) = L\left(\mathbf_2\right) \quad \text \quad L\left(\mathbf_1-\mathbf_2\right) = \mathbf. From this, it follows ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Linear Combination
In mathematics, a linear combination or superposition is an Expression (mathematics), expression constructed from a Set (mathematics), set of terms by multiplying each term by a constant and adding the results (e.g. a linear combination of ''x'' and ''y'' would be any expression of the form ''ax'' + ''by'', where ''a'' and ''b'' are constants). The concept of linear combinations is central to linear algebra and related fields of mathematics. Most of this article deals with linear combinations in the context of a vector space over a field (mathematics), field, with some generalizations given at the end of the article. Definition Let ''V'' be a vector space over the field ''K''. As usual, we call elements of ''V'' ''vector space, vectors'' and call elements of ''K'' ''scalar (mathematics), scalars''. If v1,...,v''n'' are vectors and ''a''1,...,''a''''n'' are scalars, then the ''linear combination of those vectors with those scalars as coefficients'' is :a_1 \mathbf v_1 + a_2 \mathbf ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
