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Tungstate Minerals
In chemistry, a tungstate is a Chemical compound, compound that contains an oxyanion of tungsten or is a mixed oxide containing tungsten. The simplest tungstate ion is , "orthotungstate". Many other tungstates belong to a large group of polyatomic ions that are termed polyoxometalates, ("POMs"), and specifically termed isopolyoxometalates as they contain, along with oxygen and maybe hydrogen, only one other element. Almost all useful tungsten ores are tungstates. Structures Orthotungstates feature tetrahedral W(VI) centres with short W–O distances of 1.79 Ångström, Å. Structurally, they resemble sulfates. Six-coordinate, octahedral tungsten dominates in the polyoxotungstates. In these compounds, the W–O distances are elongated. Some examples of tungstate ions: * (hydrogentungstate) * polymeric ions of various structures in , and Wells A.F. (1984) ''Structural Inorganic Chemistry'' 5th edition Oxford Science Publications * (paratungstate A) * (tungstate Y)Jon A. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Scheelite
Scheelite is a calcium tungstate mineral with the chemical formula Ca W O4. It is an important ore of tungsten (wolfram). Scheelite is originally named after Swedish chemist Carl Wilhelm Scheele (1742–1786). Well-formed crystals are sought by collectors and are occasionally fashioned into gemstones when suitably free of flaws. Scheelite has been synthesized using the Czochralski process; the material produced may be used to imitate diamond, as a scintillator, or as a solid-state lasing medium. It was also used in radium paint in the same fashion as was zinc sulphide, and Thomas Edison invented a fluoroscope with a calcium tungstate-coated screen, making the images six times brighter than those with barium platinocyanide; the latter chemical allowed Röntgen to discover X-rays in early November 1895. The semi-precious stone marketed as 'blue scheelite' is actually a rock type consisting mostly of calcite and dolomite, with occasional traces of yellow-orange scheel ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Oxidizer
An oxidizing agent (also known as an oxidant, oxidizer, electron recipient, or electron acceptor) is a substance in a redox chemical reaction that gains or " accepts"/"receives" an electron from a (called the , , or ''electron donor''). In other words, an oxidizer is any substance that oxidizes another substance. The oxidation state, which describes the degree of loss of electrons, of the oxidizer decreases while that of the reductant increases; this is expressed by saying that oxidizers "undergo reduction" and "are reduced" while reducers "undergo oxidation" and "are oxidized". Common oxidizing agents are oxygen, hydrogen peroxide, and the halogens. In one sense, an oxidizing agent is a chemical species that undergoes a chemical reaction in which it gains one or more electrons. In that sense, it is one component in an oxidation–reduction (redox) reaction. In the second sense, an oxidizing agent is a chemical species that transfers electronegative atoms, usually oxygen, to ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chromate And Dichromate
Chromate salts contain the chromate anion, . Dichromate salts contain the dichromate anion, . They are oxyanions of chromium in the +6 oxidation state and are moderately strong oxidizing agents. In an aqueous solution, chromate and dichromate ions can be interconvertible. Chemical properties Potassium-chromate-sample.jpg, Potassium chromate Potassium-dichromate-sample.jpg, Potassium dichromate Chromates react with hydrogen peroxide, giving products in which peroxide, , replaces one or more oxygen atoms. In acid solution the unstable blue peroxo complex Chromium(VI) oxide peroxide, , is formed; it is an uncharged covalent molecule, which may be extracted into ether. Addition of pyridine results in the formation of the more stable complex . Acid–base properties In aqueous solution, chromate and dichromate anions exist in a chemical equilibrium. : The predominance diagram shows that the position of the equilibrium depends on both pH and the analytical concentration o ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Molybdenum Blue
Molybdenum blue is a term applied to: *reduced heteropolymolybdate complexes, polyoxometalates containing Mo(V), Mo(VI), and a hetero atom such as phosphorus or silicon *reduced isopolymolybdate complexes, polyoxometalates containing Mo(V), Mo(VI) formed when solutions of Mo(VI) are reduced *a blue pigment containing molybdenum(VI) oxide The "heteropoly-molybdenum blues", are used extensively in analytical chemistry and as catalysts. The formation of "isopoly-molybdenum blues" which are intense blue has been used as a sensitive test for reducing reagents. They have recently been shown to contain very large anionic species based on the so-called "big wheel" containing 154 Mo atoms, with a formula o154O462H14(H2O)70sup>14−.''From Scheele and Berzelius to MÜller: polyoxometalates (POMs) revisited and the "missing link" between the bottom up and top down approaches'' P. Gouzerh, M. Che; ''L'Actualité Chimique'', 2006, 298, 9 The molybdenum blue pigment is historically documente ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Powellite
Powellite is a calcium molybdate mineral with formula CaMoO4. Powellite crystallizes with tetragonal – dipyramidal crystal structure as transparent adamantine blue, greenish-brown, yellow-to-grey typically anhedral forms. It exhibits distinct cleavage, and has a brittle-to-conchoidal fracture. It has a Mohs hardness of 3.5 to 4 and a specific gravity of 4.25. It forms a solid solution series with scheelite (calcium tungstate, CaWO4). It has refractive index values of nω=1.974 and nε=1.984. Powellite was first described by William Harlow Melville in 1891 for an occurrence in the Peacock Mine, Adams County, Idaho, and named for American explorer and geologist, John Wesley Powell (1834–1902). It occurs in hydrothermal ore deposits of molybdenum within the near-surface oxidized zones. It also appears as a rare mineral phase in pegmatite, tactite and basalt. Minerals found in association with powellite include molybdenite, ferrimolybdite, stilbite, laumontite and apophyllite ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Wolframite
Wolframite is an iron, manganese, and tungstate mineral with a chemical formula of that is the intermediate mineral between ferberite ( rich) and hübnerite ( rich). Along with scheelite, the wolframite series are the most important tungsten ore minerals. Wolframite is found in quartz veins and pegmatites associated with granitic intrusives. Associated minerals include cassiterite, scheelite, bismuth, quartz, pyrite, galena, sphalerite, and arsenopyrite. This mineral was historically found in Europe in Bohemia, Saxony, and in the UK in Devon and Cornwall. China reportedly has the world's largest supply of tungsten ore with about 60%. Other producers are Spain, Canada, Portugal, Russia, Australia, Thailand, South Korea, Rwanda, Bolivia, the United States, and the Democratic Republic of the Congo. Properties The wolframite series is mainly formed through magmatic-hydrothermal processes associated with felsic magmas, namely skarns, or through metamorphic processes. In the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Molybdate
In chemistry, a molybdate is a compound containing an oxyanion with molybdenum in its highest oxidation state of +6: . Molybdenum can form a very large range of such oxyanions, which can be discrete structures or polymeric extended structures, although the latter are only found in the solid state. The larger oxyanions are members of group of compounds termed ''polyoxometalates'', and because they contain only one type of metal atom are often called ''isopolymetalates''. The discrete molybdenum oxyanions range in size from the simplest , found in potassium molybdate up to extremely large structures found in isopoly-molybdenum blues that contain for example 154 Mo atoms. The behaviour of molybdenum is different from the other elements in group 6. Chromium only forms the chromates, , , and ions which are all based on tetrahedral chromium. Tungsten is similar to molybdenum and forms many tungstates containing 6 coordinate tungsten. Examples of molybdate anions Examples of ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chemistry
Chemistry is the scientific study of the properties and behavior of matter. It is a physical science within the natural sciences that studies the chemical elements that make up matter and chemical compound, compounds made of atoms, molecules and ions: their composition, structure, properties, behavior and the changes they undergo during chemical reaction, reactions with other chemical substance, substances. Chemistry also addresses the nature of chemical bonds in chemical compounds. In the scope of its subject, chemistry occupies an intermediate position between physics and biology. It is sometimes called the central science because it provides a foundation for understanding both Basic research, basic and Applied science, applied scientific disciplines at a fundamental level. For example, chemistry explains aspects of plant growth (botany), the formation of igneous rocks (geology), how atmospheric ozone is formed and how environmental pollutants are degraded (ecology), the prop ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ångström
The angstrom (; ) is a unit of length equal to m; that is, one ten-billionth of a metre, a hundred-millionth of a centimetre, 0.1 nanometre, or 100 picometres. The unit is named after the Swedish physicist Anders Jonas Ångström (1814–1874). It was originally spelled with Swedish letters, as Ångström and later as ångström (). The latter spelling is still listed in some dictionaries, but is now rare in English texts. Some popular US dictionaries list only the spelling ''angstrom''. The unit's symbol is Å, which is a letter of the Swedish alphabet, regardless of how the unit is spelled. However, "A" or "A.U." may be used in less formal contexts or typographically limited media. The angstrom is often used in the natural sciences and technology to express sizes of atoms, molecules, microscopic biological structures, and lengths of chemical bonds, arrangement of atoms in crystals, wavelengths of electromagnetic radiation, and dimensions of integrated circuit part ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
