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Silanes
In organosilicon chemistry, silanes are a diverse class of charge-neutral organic compounds with the general formula . The R substituents can be any combination of organic or inorganic groups. Most silanes contain Si-C bonds, and are discussed under organosilicon compounds. Some contain Si-H bonds and are discussed under hydrosilanes. Examples *Silane , the parent. * Binary silicon-hydrogen compounds (which are sometimes called silanes also) includes silane itself but also compounds with Si-Si bonds including disilane and longer chains. *Silanes with one, two, three, or four Si-H bonds are called hydrosilanes. Silane is again the parent member. Examples: triethylsilane () and triethoxysilane (). * Polysilanes are organosilicon compounds with the formula . They feature Si-Si bonds. Attracting more interest are the organic derivatives such as polydimethylsilane . Dodecamethylcyclohexasilane is an oligomer of such materials. Formally speaking, polysilanes also include co ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Binary Silicon-hydrogen Compounds
Silanes are saturated chemical compounds with the empirical formula . They are hydrosilanes, a class of compounds that includes compounds with and other bonds. All contain tetrahedral silicon and terminal hydrides. They only have and single bonds. The bond lengths are 146.0 pm for a bond and 233 pm for a bond. The structures of the silanes are analogues of the alkanes, starting with silane, , the analogue of methane, continuing with disilane , the analogue of ethane, etc. They are mainly of theoretical or academic interest. Inventory 132px, cyclopentane.html" ;"title="Cyclopentasilane is structurally similar to cyclopentane">Cyclopentasilane is structurally similar to cyclopentane, just larger. The simplest isomer of a silane is the one in which the silicon atoms are arranged in a single chain with no branches. This isomer is sometimes called the ''n''-isomer (''n'' for "normal", although it is not necessarily the most common). However the chain of silicon atoms ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Silane
Silane (Silicane) is an inorganic compound with chemical formula . It is a colorless, pyrophoric gas with a sharp, repulsive, pungent smell, somewhat similar to that of acetic acid. Silane is of practical interest as a precursor to elemental silicon. Silanes with alkyl groups are effective water repellents for mineral surfaces such as concrete and masonry. Silanes with both organic and inorganic attachments are used as coupling agents. They are commonly used to apply coatings to surfaces or as an adhesion promoter. Production Commercial-scale routes Silane can be produced by several routes. Typically, it arises from the reaction of hydrogen chloride with magnesium silicide: : It is also prepared from metallurgical-grade silicon in a two-step process. First, silicon is treated with hydrogen chloride at about 300 °C to produce trichlorosilane, HSiCl3, along with hydrogen gas, according to the chemical equation : The trichlorosilane is then converted to a mixture ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Disilane
Disilane is a chemical compound with general chemical formula Si2R6 that was first identified in 1902 by Henri Moissan and Samuel Smiles (1877–1953) where R = H. Moissan and Smiles reported disilane as being among the products formed by the action of dilute acids on metal silicides. Although these reactions had been previously investigated by Friedrich Woehler and Heinrich Buff between 1857 and 1858, Moissan and Smiles were the first to explicitly identify disilane. They referred to disilane as ''silicoethane''. Higher members of the homologous series formed in these reactions were subsequently identified by Carl Somiesky (sometimes spelled "Karl Somieski") and Alfred Stock. At standard temperature and pressure, disilane is a colourless, acrid gas. Disilane and ethane have similar structures, although disilane is much more reactive. Other compounds of the general formula (X = hydrogen, halogen, alkyl, aryl, and mixtures of these groups) are called disilanes. Disilane is a group ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Silanes
In organosilicon chemistry, silanes are a diverse class of charge-neutral organic compounds with the general formula . The R substituents can be any combination of organic or inorganic groups. Most silanes contain Si-C bonds, and are discussed under organosilicon compounds. Some contain Si-H bonds and are discussed under hydrosilanes. Examples *Silane , the parent. * Binary silicon-hydrogen compounds (which are sometimes called silanes also) includes silane itself but also compounds with Si-Si bonds including disilane and longer chains. *Silanes with one, two, three, or four Si-H bonds are called hydrosilanes. Silane is again the parent member. Examples: triethylsilane () and triethoxysilane (). * Polysilanes are organosilicon compounds with the formula . They feature Si-Si bonds. Attracting more interest are the organic derivatives such as polydimethylsilane . Dodecamethylcyclohexasilane is an oligomer of such materials. Formally speaking, polysilanes also include co ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hydrosilanes
Hydrosilanes are tetravalent silicon compounds containing one or more Si-H bond. The parent hydrosilane is silane (SiH4). Commonly, hydrosilane refers to organosilicon derivatives. Examples include phenylsilane (PhSiH3) and triethoxysilane ((C2H5O)3SiH). Polymers and oligomers terminated with hydrosilanes are resins that are used to make useful materials like caulks. Synthesis Trichlorosilane is produced commercially by the reaction of hydrogen chloride with silicon: :Si + 3 HCl → HSiCl3 + H2 Many alkoxy hydrosilanes are generated by alcoholysis of trichlorosilane. One example is triethoxysilane: :HSiCl3 + 3EtOH → HSi(OEt)3 + 3 HCl Organohydrosilanes can be prepared by partial hydrosilation of silane itself: :SiH4 + 3 C2H4 → HSi(C2H5)3 In the laboratory, hydrosilanes classically are prepared by treating chlorosilanes with hydride reagents, such as lithium aluminium hydride: :4ClSi(C2H5)3 + LiAlH4 → 4HSi(C2H5)3 + LiAlCl4 Structure The silicon-to-hydrogen bond is longer ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
