Europium
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Europium
Europium is a chemical element; it has symbol Eu and atomic number 63. It is a silvery-white metal of the lanthanide series that reacts readily with air to form a dark oxide coating. Europium is the most chemically reactive, least dense, and softest of the lanthanides. It is soft enough to be cut with a knife. Europium was discovered in 1896, provisionally designated as Σ; in 1901, it was named after the continent of Europe. Europium usually assumes the oxidation state +3, like other members of the lanthanide series, but compounds having oxidation state +2 are also common. All europium compounds with oxidation state +2 are slightly reducing. Europium has no significant biological role and is relatively non-toxic compared to other heavy metals. Most applications of europium exploit the phosphorescence of europium compounds. Europium is one of the rarest of the rare-earth elements on Earth.Stwertka, Albert. ''A Guide to the Elements'', Oxford University Press, 1996, p. 156. Ety ...
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Europium(III) Oxide
Europium is a chemical element; it has symbol Eu and atomic number 63. It is a silvery-white metal of the lanthanide series that reacts readily with air to form a dark oxide coating. Europium is the most chemically reactive, least dense, and softest of the lanthanides. It is soft enough to be cut with a knife. Europium was discovered in 1896, provisionally designated as Σ; in 1901, it was named after the continent of Europe. Europium usually assumes the oxidation state +3, like other members of the lanthanide series, but compounds having oxidation state +2 are also common. All europium compounds with oxidation state +2 are slightly reducing. Europium has no significant biological role and is relatively non-toxic compared to other heavy metals. Most applications of europium exploit the phosphorescence of europium compounds. Europium is one of the rarest of the rare-earth elements on Earth.Stwertka, Albert. ''A Guide to the Elements'', Oxford University Press, 1996, p. 156. ...
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Lanthanide
The lanthanide () or lanthanoid () series of chemical elements comprises at least the 14 metallic chemical elements with atomic numbers 57–70, from lanthanum through ytterbium. In the periodic table, they fill the 4f orbitals. Lutetium (element 71) is also sometimes considered a lanthanide, despite being a d-block element and a transition metal. The informal chemical symbol Ln is used in general discussions of lanthanide chemistry to refer to any lanthanide. All but one of the lanthanides are f-block elements, corresponding to the filling of the 4f electron shell. Lutetium is a d-block element (thus also a transition metal), and on this basis its inclusion has been questioned; however, like its congeners scandium and yttrium in group 3, it behaves similarly to the other 14. The term rare-earth element or rare-earth metal is often used to include the stable group 3 elements Sc, Y, and Lu in addition to the 4f elements. All lanthanide elements form trivalent cations, Ln3+, ...
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Cubic Crystal System
In crystallography, the cubic (or isometric) crystal system is a crystal system where the unit cell is in the shape of a cube. This is one of the most common and simplest shapes found in crystals and minerals. There are three main varieties of these crystals: *Primitive cubic (abbreviated ''cP'' and alternatively called simple cubic) *Body-centered cubic (abbreviated ''cI'' or bcc) *Face-centered cubic (abbreviated ''cF'' or fcc) Note: the term fcc is often used in synonym for the ''cubic close-packed'' or ccp structure occurring in metals. However, fcc stands for a face-centered cubic Bravais lattice, which is not necessarily close-packed when a motif is set onto the lattice points. E.g. the diamond and the zincblende lattices are fcc but not close-packed. Each is subdivided into other variants listed below. Although the ''unit cells'' in these crystals are conventionally taken to be cubes, the primitive unit cells often are not. Bravais lattices The three Bravais latices ...
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Europium Anomaly
The europium anomaly refers to the enrichment or depletion of the europium concentration in a mineral or rock compared to neighboring rare-earth elements also present in the material. This anomaly is typically evaluated relative to a common standard such as a chondrite or mid-ocean ridge basalt (MORB). In geochemistry a europium anomaly is said to be "positive" if the Eu concentration in the mineral is enriched relative to the other rare-earth elements (REEs), and is said to be "negative" if Eu is depleted relative to the other REEs. Oxidation States and Partitioning Behavior Most REEs exist in the trivalent state (3+), but europium and cerium (Ce) exhibit additional oxidation states that affect their geochemical behavior. Europium can be reduced to Eu²⁺, especially under reducing magmatic conditions making it immiscible with other REEs. Meanwhile, cerium may be oxidized to Ce⁴⁺. These alternate valences impact how the elements partition between minerals. Eu (2+) cations ...
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Rare-earth Elements
The rare-earth elements (REE), also called the rare-earth metals or rare earths, and sometimes the lanthanides or lanthanoids (although scandium and yttrium, which do not belong to this series, are usually included as rare earths), are a set of 17 nearly indistinguishable lustrous silvery-white soft heavy metals. Compounds containing rare earths have diverse applications in electrical and electronic components, lasers, glass, magnetic materials, and industrial processes. The term "rare-earth" is a misnomer because they are not actually scarce, but historically it took a long time to isolate these elements. They are relatively plentiful in the entire Earth's crust (cerium being the 25th-most-abundant element at 68 parts per million, more abundant than copper), but in practice they are spread thinly as trace impurities, so to obtain rare earths at usable purity requires processing enormous amounts of raw ore at great expense; thus the name "rare" earths. Scandium and yttrium are ...
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Europium(II) Sulfate
Europium(II) sulfate is the inorganic compound with the formula EuSO4. Two polymorphs are known, α and the more stable β. Both are colorless. The β polymorph is isostructural with barium sulfate Barium sulfate (or sulphate) is the inorganic compound with the chemical formula Ba SO4. It is a white crystalline solid that is odorless and insoluble in water. It occurs in nature as the mineral barite, which is the main commercial source of ..., hence it is insoluble in water. The salt is generated by addition of soluble europium(II) salts to dilute sulfuric acid. References {{Sulfates Europium(II) compounds Sulfates ...
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Eugène-Anatole Demarçay
Eugène-Anatole Demarçay (1 January 1852 – 5 March 1903) was a French chemist who designed an apparatus to produce a spark using an induction coil and used it to generate the spectra of rare earth elements which he examined using spectroscopy, thus detecting the element europium in 1896, and isolated it as the oxide europia in 1901. He helped Marie Curie to confirm the existence of another new element, radium, in 1898. Education Eugène-Anatole Demarçay was born to Camille Demarçay (1815–1893) and Cécile Lainé (1829–1916) at 152 boulevard Haussman, Paris. His grandfather Marc-Jean Demarçay (1772–1839) had been a general in the French Revolution. Demarçay studied at the Lycée Condorcet, spent time in England, and in 1870 entered the École Polytechnique in Palaiseau near Paris. Demarçay studied under Jean Baptiste Dumas (1800–1884) and served for several years as an assistant to Auguste André Thomas Cahours at the École Polytechnique. In 1876, he studie ...
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Heavy Metal (chemistry)
upright=1.2, Crystals of lead.html" ;"title="osmium, a heavy metal nearly twice as dense as lead">osmium, a heavy metal nearly twice as dense as lead Heavy metals is a controversial and ambiguous term for metallic elements with relatively high density, densities, atomic weights, or atomic numbers. The criteria used, and whether metalloids are included, vary depending on the author and context and it has been argued that the term "heavy metal" should be avoided. A heavy metal may be defined on the basis of density, atomic number or chemical behaviour. More specific definitions have been published, none of which have been widely accepted. The definitions surveyed in this article encompass up to 96 out of the 118 known chemical elements; only mercury, lead and bismuth meet all of them. Despite this lack of agreement, the term (plural or singular) is widely used in science. A density of more than 5 g/cm3 is sometimes quoted as a commonly used criterion and is used in the b ...
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Symbol (chemistry)
Chemical symbols are the abbreviations used in chemistry, mainly for chemical elements; but also for functional groups, chemical compounds, and other entities. Element symbols for chemical elements, also known as atomic symbols, normally consist of one or two letters from the Latin alphabet and are written with the first letter capitalised. History Earlier symbols for chemical elements stem from classical Latin and Greek words. For some elements, this is because the material was known in ancient times, while for others, the name is a more recent invention. For example, Pb is the symbol for lead (''plumbum'' in Latin); Hg is the symbol for mercury (''hydrargyrum'' in Greek); and He is the symbol for helium (a Neo-Latin name) because helium was not known in ancient Roman times. Some symbols come from other sources, like W for tungsten (''Wolfram'' in German) which was not known in Roman times. A three-letter temporary symbol may be assigned to a newly synthesized (or not yet ...
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Electron Shell
In chemistry and atomic physics, an electron shell may be thought of as an orbit that electrons follow around an atom's nucleus. The closest shell to the nucleus is called the "1 shell" (also called the "K shell"), followed by the "2 shell" (or "L shell"), then the "3 shell" (or "M shell"), and so on further and further from the nucleus. The shells correspond to the principal quantum numbers (''n'' = 1, 2, 3, 4 ...) or are labeled alphabetically with the letters used in X-ray notation (K, L, M, ...). Each period on the conventional periodic table of elements represents an electron shell. Each shell can contain only a fixed number of electrons: the first shell can hold up to two electrons, the second shell can hold up to eight electrons, the third shell can hold up to 18, continuing as the general formula of the ''n''th shell being able to hold up to 2( ''n''2) electrons.
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Electron Configuration
In atomic physics and quantum chemistry, the electron configuration is the distribution of electrons of an atom or molecule (or other physical structure) in atomic or molecular orbitals. For example, the electron configuration of the neon atom is , meaning that the 1s, 2s, and 2p subshells are occupied by two, two, and six electrons, respectively. Electronic configurations describe each electron as moving independently in an orbital, in an average field created by the nuclei and all the other electrons. Mathematically, configurations are described by Slater determinants or configuration state functions. According to the laws of quantum mechanics, a level of energy is associated with each electron configuration. In certain conditions, electrons are able to move from one configuration to another by the emission or absorption of a quantum of energy, in the form of a photon. Knowledge of the electron configuration of different atoms is useful in understanding the structu ...
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