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Copper–copper(II) Sulfate Electrode
The copper–copper(II) sulfate electrode is a reference electrode of the first kind, based on the redox reaction with participation of the metal (copper) and its salt, copper(II) sulfate. It is used for measuring electrode potential and is the most commonly used reference electrode for testing cathodic protection corrosion control systems. The corresponding equation can be presented as follow: :Cu2+ + 2e− → Cu0(metal) This reaction is characterized by reversible and fast electrode kinetics, meaning that a sufficiently high current can be passed through the electrode with 100% efficiency of the redox reaction ( dissolution of the metal or cathodic deposition of the copper-ions). The Nernst equation below shows the dependence of the potential of the copper-copper(II) sulfate electrode on the activity or concentration copper-ions: : E=0.337 + \frac \ln a_ Protopopoff, et al, p. 15, Eq 2 The potential of a copper–copper sulfate electrode is +0.314 volt with respect to the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Concentration
In chemistry, concentration is the abundance of a constituent divided by the total volume of a mixture. Several types of mathematical description can be distinguished: '' mass concentration'', '' molar concentration'', '' number concentration'', and '' volume concentration''. The concentration can refer to any kind of chemical mixture, but most frequently refers to solutes and solvents in solutions. The molar (amount) concentration has variants, such as normal concentration and osmotic concentration. Dilution is reduction of concentration, e.g. by adding solvent to a solution. The verb to concentrate means to increase concentration, the opposite of dilute. Etymology ''Concentration-'', ''concentratio'', action or an act of coming together at a single place, bringing to a common center, was used in post-classical Latin in 1550 or earlier, similar terms attested in Italian (1589), Spanish (1589), English (1606), French (1632). Qualitative description Often in informal, non- ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Buffer Solution
A buffer solution is a solution where the pH does not change significantly on dilution or if an acid or base is added at constant temperature. Its pH changes very little when a small amount of strong acid or base is added to it. Buffer solutions are used as a means of keeping pH at a nearly constant value in a wide variety of chemical applications. In nature, there are many living systems that use buffering for pH regulation. For example, the bicarbonate buffering system is used to regulate the pH of blood, and bicarbonate also acts as a buffer in the ocean. Principles of buffering Buffer solutions resist pH change because of a chemical equilibrium between the weak acid HA and its conjugate base A−: When some strong acid is added to an equilibrium mixture of the weak acid and its conjugate base, hydrogen ions (H+) are added, and the equilibrium is shifted to the left, in accordance with Le Chatelier's principle. Because of this, the hydrogen ion concentration increas ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Copper Coulometer
The copper coulometer is a coulometer consisting of two identical copper electrodes immersed in a slightly acidic pH-buffered solution of copper(II) sulfate ( copper-copper(II) sulfate electrode). Passing of current through the element leads to the anodic dissolution of the metal on anode and simultaneous deposition of copper ions on the cathode. These reactions have 100% efficiency over a wide range of current density. Calculation The amount of electric charge (quantity of electricity) passed through the cell can easily be determined by measuring the change in mass of either electrode and calculating: :Q = \frac, where: *Q is the quantity of electricity (coulombs) *\Delta m is the mass transported (gm) *z_ is the charge of the copper ions, equal to +2 *F is the Faraday constant (96485.3383 coulombs per mole) *M_ is the atomic weight of copper, equal to 63.546 grams per mole. Although this apparatus is interesting from a theoretical and historical point of view, present-day ele ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Daniell Cell
The Daniell cell is a type of electrochemical cell invented in 1836 by John Frederic Daniell, a British chemist and meteorologist, and consists of a copper pot filled with a copper (II) sulfate solution, in which is immersed an unglazed earthenware container filled with sulfuric acid and a zinc electrode. He was searching for a way to eliminate the hydrogen bubble problem found in the voltaic pile, and his solution was to use a second electrolyte to consume the hydrogen produced by the first. Zinc sulfate may be substituted for the sulfuric acid. The Daniell cell was a great improvement over the existing technology used in the early days of battery development. A later variant of the Daniell cell called the gravity cell or crowfoot cell was invented in the 1860s by a Frenchman named Callaud and became a popular choice for electrical telegraphy. The Daniell cell is also the historical basis for the contemporary definition of the volt, which is the unit of electromotive force in ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Half Cell
In electrochemistry, a half-cell is a structure that contains a conductive electrode and a surrounding conductive electrolyte separated by a naturally occurring Helmholtz double layer. Chemical reactions within this layer momentarily pump electric charges between the electrode and the electrolyte, resulting in a potential difference between the electrode and the electrolyte. The typical anode reaction involves a metal atom in the electrode being dissolved and transported as a positive ion across the double layer, causing the electrolyte to acquire a net positive charge while the electrode acquires a net negative charge. The growing potential difference creates an intense electric field within the double layer, and the potential rises in value until the field halts the net charge-pumping reactions. This self-limiting action occurs almost instantly in an isolated half-cell; in applications two dissimilar half-cells are appropriately connected to constitute a Galvanic cell. A standa ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Voltmeter
A voltmeter is an instrument used for measuring electric potential difference between two points in an electric circuit. It is connected in parallel. It usually has a high resistance so that it takes negligible current from the circuit. Analog voltmeters move a pointer across a scale in proportion to the voltage measured and can be built from a galvanometer and series resistor. Meters using amplifiers can measure tiny voltages of microvolts or less. Digital voltmeters give a numerical display of voltage by use of an analog-to-digital converter. Voltmeters are made in a wide range of styles, some separately powered (e.g. by battery), and others powered by the measured voltage source itself. Instruments permanently mounted in a panel are used to monitor generators or other fixed apparatus. Portable instruments, usually equipped to also measure current and resistance in the form of a multimeter are standard test instruments used in electrical and electronics work. Any meas ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electrolyte
An electrolyte is a substance that conducts electricity through the movement of ions, but not through the movement of electrons. This includes most soluble Salt (chemistry), salts, acids, and Base (chemistry), bases, dissolved in a polar solvent like water. Upon dissolving, the substance separates into cations and anions, which disperse uniformly throughout the solvent. Solid-state electrolytes also exist. In medicine and sometimes in chemistry, the term electrolyte refers to the substance that is dissolved. Electrically, such a solution is neutral. If an electric potential is applied to such a solution, the cations of the solution are drawn to the electrode that has an abundance of electrons, while the anions are drawn to the electrode that has a deficit of electrons. The movement of anions and cations in opposite directions within the solution amounts to a current. Some gases, such as hydrogen chloride (HCl), under conditions of high temperature or low pressure can also functi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Standard Hydrogen Electrode
In electrochemistry, the standard hydrogen electrode (abbreviated SHE), is a redox electrode which forms the basis of the thermodynamic scale of oxidation-reduction potentials. Its absolute electrode potential is estimated to be at 25 °C, but to form a basis for comparison with all other electrochemical reactions, hydrogen's standard electrode potential () is declared to be zero volts at any temperature. Potentials of all other electrodes are compared with that of the standard hydrogen electrode at the same temperature. Nernst equation for SHE The hydrogen electrode is based on the redox half cell corresponding to the reduction of two hydrated protons, into one gaseous hydrogen molecule, General equation for a reduction reaction: : \underset + z\ce\ \underset The reaction quotient () of the half-reaction is the ratio between the chemical activities () of the reduced form (the reductant, ) and the oxidized form (the oxidant, ). : Q_r = \frac Considering the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Volt
The volt (symbol: V) is the unit of electric potential, Voltage#Galvani potential vs. electrochemical potential, electric potential difference (voltage), and electromotive force in the International System of Units, International System of Units (SI). Definition One volt is defined as the electric potential between two points of a electrical conductor, conducting wire when an electric current of one ampere dissipates one watt of power (physics), power between those points. It can be expressed in terms of SI base units (metre, m, kilogram, kg, second, s, and ampere, A) as : \text = \frac = \frac = \frac = \text\text^2\text^. Equivalently, it is the potential difference between two points that will impart one joule of energy per coulomb of charge that passes through it. It can be expressed in terms of SI base units (metre, m, kilogram, kg, second, s, and ampere, A) as : \text = \frac = \frac = \frac = \text\text^2\text^. It can also be expressed as amperes times ohms (curre ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Activity (chemistry)
In thermodynamics, activity (symbol ) is a measure of the "effective concentration" of a species in a mixture, in the sense that the species' chemical potential depends on the activity of a real solution in the same way that it would depend on concentration for an ideal solution. The term "activity" in this sense was coined by the American chemist Gilbert N. Lewis in 1907. By convention, activity is treated as a dimensionless quantity, although its value depends on customary choices of standard state for the species. The activity of pure substances in condensed phases (solids and liquids) is taken as = 1. Activity depends on temperature, pressure and composition of the mixture, among other things. For gases, the activity is the effective partial pressure, and is usually referred to as fugacity. The difference between activity and other measures of concentration arises because the interactions between different types of molecules in non-ideal gases or solutions are differen ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Reference Electrode
A reference electrode is an electrode that has a stable and well-known electrode potential. The overall chemical reaction taking place in a cell is made up of two independent half-reactions, which describe chemical changes at the two electrodes. To focus on the reaction at the working electrode, the reference electrode is standardized with constant (buffered or saturated) concentrations of each participant of the redox reaction. There are many ways reference electrodes are used. The simplest is when the reference electrode is used as a half-cell to build an electrochemical cell. This allows the potential of the other half cell to be determined. An accurate and practical method to measure an electrode's potential in isolation ( absolute electrode potential) has yet to be developed. Aqueous reference electrodes Common reference electrodes and potential with respect to the standard hydrogen electrode (SHE): * Standard hydrogen electrode (SHE) (E = 0.000 V) activity of H+ = 1 ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
