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Conducting Polymer
Conductive polymers or, more precisely, intrinsically conducting polymers (ICPs) are organic polymers that conduct electricity. Such compounds may have metallic conductivity or can be semiconductors. The main advantage of conductive polymers is that they are easy to process, mainly by dispersion. Conductive polymers are generally not thermoplastics, ''i.e.'', they are not thermoformable. But, like insulating polymers, they are organic materials. They can offer high electrical conductivity but do not show similar mechanical properties to other commercially available polymers. The electrical properties can be fine-tuned using the methods of organic synthesis and by advanced dispersion techniques. History Polyaniline was first described in the mid-19th century by Henry Letheby, who investigated the electrochemical and chemical oxidation products of aniline in acidic media. He noted that the reduced form was colourless but the oxidized forms were deep blue. The first highly-conduc ...
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Semiconductors
A semiconductor is a material with electrical conductivity between that of a conductor and an insulator. Its conductivity can be modified by adding impurities (" doping") to its crystal structure. When two regions with different doping levels are present in the same crystal, they form a semiconductor junction. The behavior of charge carriers, which include electrons, ions, and electron holes, at these junctions is the basis of diodes, transistors, and most modern electronics. Some examples of semiconductors are silicon, germanium, gallium arsenide, and elements near the so-called "metalloid staircase" on the periodic table. After silicon, gallium arsenide is the second-most common semiconductor and is used in laser diodes, solar cells, microwave-frequency integrated circuits, and others. Silicon is a critical element for fabricating most electronic circuits. Semiconductor devices can display a range of different useful properties, such as passing current more easily in one ...
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Electroluminescent
Electroluminescence (EL) is an optical and electrical phenomenon, in which a material emits light in response to the passage of an electric current or to a strong electric field. This is distinct from black body light emission resulting from heat (incandescence), chemical reactions ( chemiluminescence), reactions in a liquid ( electrochemiluminescence), sound ( sonoluminescence), or other mechanical action ( mechanoluminescence), or organic electroluminescence. Mechanism Electroluminescence is the result of radiative recombination of electrons and holes in a material, usually a semiconductor. The excited electrons release their energy as photons – light. Prior to recombination, electrons and holes may be separated either by doping the material to form a p-n junction (in semiconductor electroluminescent devices such as light-emitting diodes) or through excitation by impact of high-energy electrons accelerated by a strong electric field (as with the phosphors in electrolu ...
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Poly(p-phenylene Vinylene)
Poly(''p''-phenylene vinylene) (PPV, or polyphenylene vinylene) is a Conducting polymers, conducting polymer of the rigid-rod polymer family. PPV is the only polymer of this type that can be processed into a highly ordered crystalline thin film. PPV and its derivatives are electrically conducting upon doping. Although insoluble in water, its precursors can be manipulated in aqueous solution. The small optical band gap and its bright yellow fluorescence makes PPV a candidate in applications such as light-emitting diodes (LED) and photovoltaic devices. Moreover, PPV can be doped to form electrically conductive materials. Its physical and electronic properties can be altered by the inclusion of functional side groups. Preparation PPVs can be synthesized by a variety of methods, the details of which determine purity and molecular weight. The most popular methods proceed via p-xylylene intermediates after a base induced elimination from α,α'-disubstituted para-xylenes. : Other me ...
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Polyaniline
Polyaniline (PANI) is a conducting polymer and organic semiconductor of the semi-flexible rod polymer family. The compound has been of interest since the 1980s because of its electrical conductivity and mechanical properties. Polyaniline is one of the most studied conducting polymers. Historical development Polyaniline was discovered in the 19th century by F. Ferdinand Runge (1794–1867), Carl Fritzsche (1808–1871), John Lightfoot (1831–1872), and Henry Letheby (1816–1876). Lightfoot studied the oxidation of aniline, which had been isolated only 20 years previously. He developed the first commercially successful route to the dye called Aniline black. The first definitive report of polyaniline did not occur until 1862, which included an electrochemical method for the determination of small quantities of aniline. From the early 20th century on, occasional reports about the structure of PANI were published. Polymerized from the inexpensive aniline, polyaniline can be fou ...
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Polyacetylene
Polyacetylene (IUPAC name: polyethyne) usually refers to an organic polymer with the repeating unit . The name refers to its conceptual construction from polymerization of acetylene to give a chain with repeating olefin groups. This compound is conceptually important, as the discovery of polyacetylene and its high Ionic conductivity (solid state), conductivity upon doping (semiconductor), doping helped to launch the field of organic conductive polymers. The high electrical conductivity discovered by Hideki Shirakawa, Alan Heeger, and Alan MacDiarmid for this polymer led to intense interest in the use of organic compounds in microelectronics (organic semiconductors). This discovery was recognized by the Nobel Prize in Chemistry in 2000. Early work in the field of polyacetylene research was aimed at using doped polymers as easily processable and lightweight "plastic metals". Despite the promise of this polymer in the field of conductive polymers, many of its properties such as insta ...
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OLED
An organic light-emitting diode (OLED), also known as organic electroluminescent (organic EL) diode, is a type of light-emitting diode (LED) in which the emissive electroluminescent layer is an organic compound film that emits light in response to an electric current. This organic layer is situated between two electrodes; typically, at least one of these electrodes is transparent. OLEDs are used to create digital displays in devices such as television screens, computer monitors, and portable systems such as smartphones and handheld game consoles. A major area of research is the development of white OLED devices for use in solid-state lighting applications. There are two main families of OLED: those based on small molecules and those employing polymers. Adding mobile ions to an OLED creates a light-emitting electrochemical cell (LEC) which has a slightly different mode of operation. An OLED display can be driven with a passive-matrix (PMOLED) or active-matrix ( AMOLED) c ...
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Nobel Prize In Chemistry
The Nobel Prize in Chemistry () is awarded annually by the Royal Swedish Academy of Sciences to scientists in the various fields of chemistry. It is one of the five Nobel Prizes established by the will of Alfred Nobel in 1895, awarded for outstanding contributions in chemistry, physics, literature, peace, and physiology or medicine. This award is administered by the Nobel Foundation and awarded by the Royal Swedish Academy of Sciences on proposal of the Nobel Committee for Chemistry, which consists of five members elected by the Academy. The award is presented in Stockholm at an annual ceremony on December 10th, the anniversary of Nobel's death. The first Nobel Prize in Chemistry was awarded in 1901 to Jacobus Henricus van 't Hoff, of the Netherlands, "for his discovery of the laws of chemical dynamics and osmotic pressure in solutions". From 1901 to 2024, the award has been bestowed on a total of 195 individuals. The 2024 Nobel Prize in Chemistry was awarded to Demis Hassabis ...
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Hideki Shirakawa
is a Japanese chemist, engineer, and Professor Emeritus at the University of Tsukuba and Zhejiang University. He is best known for his discovery of conductive polymers. He was co-recipient of the 2000 Nobel Prize in Chemistry jointly with Alan MacDiarmid and Alan Heeger. Early life and education Hideki Shirakawa was born in Tokyo, Japan, the second son of a military doctor. He had one elder and one younger brother and sister. Olympic marathoner champion Naoko Takahashi is his second cousin-niece. He lived in Manchukuo and Taiwan during childhood. Around third grade, he moved to Takayama, Gifu, which is the hometown of his mother. Shirakawa graduated from Tokyo Institute of Technology (Tokyo Tech) with a bachelor's degree in chemical engineering in 1961, and his doctorate in 1966. Afterward, he obtained the post of assistant in Chemical Resources Laboratory at Tokyo Tech. Career While employed as an assistant at Tokyo Institute of Technology (Tokyo Tech) in Japan, Sh ...
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Alan MacDiarmid
Alan Graham MacDiarmid, ONZ FRS (14 April 1927 – 7 February 2007) was a New Zealand-born American chemist, and one of three recipients of the Nobel Prize for Chemistry in 2000. Early life and education MacDiarmid was born in Masterton, New Zealand, as one of five children – three brothers and two sisters. His family was relatively poor, and the Great Depression made life difficult in Masterton, due to which his family shifted to Lower Hutt, a few miles from Wellington, New Zealand. At around age ten, he developed an interest in chemistry from one of his father's old textbooks, and he taught himself from this book and from library books. MacDiarmid was educated at Hutt Valley High School and Victoria University of Wellington. In 1943, MacDiarmid passed the University of New Zealand's University Entrance Exam and its Medical Preliminary Exam. He then took up a part-time job as a "lab boy" or janitor at Victoria University of Wellington during his studies for a BSc degre ...
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Alan J
Alan may refer to: People *Alan (surname), an English and Kurdish surname * Alan (given name), an English given name ** List of people with given name Alan ''Following are people commonly referred to solely by "Alan" or by a homonymous name.'' * Alan (Chinese singer) (born 1987), female Chinese singer of Tibetan ethnicity, active in both China and Japan * Alan (Mexican singer) (born 1973), Mexican singer and actor * Alan (wrestler) (born 1975), a.k.a. Gato Eveready, who wrestles in Asistencia Asesoría y Administración * Alan (footballer, born 1979) (Alan Osório da Costa Silva), Brazilian footballer * Alan (footballer, born 1998) (Alan Cardoso de Andrade), Brazilian footballer * Alan I, King of Brittany (died 907), "the Great" * Alan II, Duke of Brittany (c. 900–952) * Alan III, Duke of Brittany(997–1040) * Alan IV, Duke of Brittany (c. 1063–1119), a.k.a. Alan Fergant ("the Younger" in Breton language) * Alan of Tewkesbury, 12th century abbott * Alan of Lynn (c. 1348–142 ...
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Polaron
A polaron is a quasiparticle used in condensed matter physics to understand the interactions between electrons and atoms in a solid material. The polaron concept was proposed by Lev Landau in 1933 and Solomon Pekar in 1946 to describe an electron moving in a dielectric crystal where the ions, atoms displace from their equilibrium positions to effectively screen the charge of an electron, known as a phonon cloud. This lowers the electron mobility and increases the electron's effective mass (solid-state physics), effective mass. The general concept of a polaron has been extended to describe other interactions between the electrons and ions in metals that result in a bound state, or a lowering of energy compared to the non-interacting system. Major theoretical work has focused on solving Herbert Fröhlich, Fröhlich and Holstein hamiltonian (quantum mechanics), Hamiltonians. This is still an active field of research to find exact numerical solutions to the case of one or two electro ...
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