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Chemical Affinity
In chemical physics and physical chemistry, chemical affinity is the electronic property by which dissimilar chemical species are capable of forming chemical compounds. Chemical affinity can also refer to the tendency of an atom or compound to combine by chemical reaction with atoms or compounds of unlike composition. History Early theories The idea of ''affinity'' is extremely old. Many attempts have been made at identifying its origins. The majority of such attempts, however, except in a general manner, end in futility since "affinities" lie at the basis of all Magic (paranormal), magic, thereby pre-dating science. Physical chemistry, however, was one of the first branches of science to study and formulate a "theory of affinity". The name ''affinitas'' was first used in the sense of chemical relation by German philosopher Albertus Magnus near the year 1250. Later, those as Robert Boyle, John Mayow, Johann Glauber, Isaac Newton, and Georg Stahl put forward ideas on elective ...
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Chemical Physics
Chemical physics is a branch of physics that studies chemical processes from a physical point of view. It focuses on understanding the physical properties and behavior of chemical systems, using principles from both physics and chemistry. This field investigates physicochemical phenomena using techniques from atomic and molecular physics and condensed matter physics. The United States Department of Education defines chemical physics as "A program that focuses on the scientific study of structural phenomena combining the disciplines of physical chemistry and atomic/molecular physics. Includes instruction in heterogeneous structures, alignment and surface phenomena, quantum theory, mathematical physics, statistical and classical mechanics, chemical kinetics, and laser physics." Distinction between chemical physics and physical chemistry While at the interface of physics and chemistry, chemical physics is distinct from physical chemistry as it focuses more on using physical ...
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Philology
Philology () is the study of language in Oral tradition, oral and writing, written historical sources. It is the intersection of textual criticism, literary criticism, history, and linguistics with strong ties to etymology. Philology is also defined as the study of literary texts and oral and written records, the establishment of their authentication, authenticity and their original form, and the determination of their meaning. A person who pursues this kind of study is known as a philologist. In older usage, especially British, philology is more general, covering comparative linguistics, comparative and historical linguistics. Classical philology studies classical languages. Classical philology principally originated from the Library of Pergamum and the Library of Alexandria around the fourth century BC, continued by Greeks and Romans throughout the Roman Empire, Roman and Byzantine Empire. It was eventually resumed by European scholars of the Renaissance humanism, Renaissance, ...
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Elective Affinities
''Elective Affinities'' (German: ''Die Wahlverwandtschaften''), also translated under the title ''Kindred by Choice'', is the third novel by Johann Wolfgang von Goethe, published in 1809. Situated around the city of Weimar, the book relates the story of Eduard and Charlotte, an aristocratic couple enjoying an idyllic but somewhat mundane life on a secluded estate; although it is the second marriage for both, their relationship deteriorates after they invite Eduard's friend Captain Otto and Charlotte's orphaned niece, Ottilie, to live with them in their mansion. The invitation to Ottilie and the Captain is described as an "experiment", as it indeed is. The house and its surrounding gardens are described as "a chemical retort in which the human elements are brought together for the reader to observe the resulting reaction." As if in a chemical reaction, each of the spouses experiences a strong new attraction, which is reciprocated: Charlotte, who represents reason, to the sensible a ...
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Johann Wolfgang Von Goethe
Johann Wolfgang (von) Goethe (28 August 1749 – 22 March 1832) was a German polymath who is widely regarded as the most influential writer in the German language. His work has had a wide-ranging influence on Western literature, literary, Political philosophy#European Enlightenment, political, and Western philosophy, philosophical thought in the Western world from the late 18th century to the present.. A poet, playwright, novelist, scientist, statesman, theatre-director, and critic, Johann Wolfgang von Goethe bibliography, his works include plays, poetry and aesthetic criticism, as well as treatises on botany, anatomy, and colour. Goethe took up residence in Weimar in 1775 following the success of his first novel, ''The Sorrows of Young Werther'' (1774), and joined a thriving intellectual and cultural environment under the patronage of Duchess Anna Amalia of Brunswick-Wolfenbüttel, Duchess Anna Amalia that formed the basis of Weimar Classicism. He was ennobled by Karl August, G ...
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Théophile De Donder
Theophilus is a male given name with a range of alternative spellings. Its origin is the Greek word Θεόφιλος from θεός (''theós'', "God") and φιλία (''philía'', "love or affection") can be translated as "Love of God" or "Friend of God", i.e., it is a theophoric name, synonymous with the name '' Amadeus'' which originates from Latin, Gottlieb in German and Bogomil or Bogumił in Slavic. Theophilus may refer to: People Arts * Theophilus Cibber (1703–1758), English actor, playwright, author, son of the actor-manager Colley Cibber * Theophilus Clarke (1776?–1831), English painter * Theophilos Hatzimihail (c. 1870–1934), Greek folk painter from Lesbos * Theophilus Presbyter (1070–1125), Benedictine monk, and author of the best-known medieval "how-to" guide to several arts, including oil painting — thought to be a pseudonym of Roger of Helmarshausen Historical * Theophilos (emperor) (c. 812–842), Byzantine Emperor (reigned 829–842), the second of th ...
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Thermodynamic Free Energy
In thermodynamics, the thermodynamic free energy is one of the state functions of a thermodynamic system. The change in the free energy is the maximum amount of work that the system can perform in a process at constant temperature, and its sign indicates whether the process is thermodynamically favorable or forbidden. Since free energy usually contains potential energy, it is not absolute but depends on the choice of a zero point. Therefore, only relative free energy values, or changes in free energy, are physically meaningful. The free energy is the portion of any first-law energy that is available to perform thermodynamic work at constant temperature, ''i.e.'', work mediated by thermal energy. Free energy is subject to irreversible loss in the course of such work. Since first-law energy is always conserved, it is evident that free energy is an expendable, second-law kind of energy. Several free energy functions may be formulated based on system criteria. Free energy ...
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Merle Randall
Merle Randall (January 29, 1888 – March 17, 1950) was an American physical chemist famous for his work with Gilbert N. Lewis, over a period of 25 years, in measuring reaction heat of chemical compounds and determining their corresponding free energy. Together, their 1923 textbook ''"Thermodynamics and the Free Energy of Chemical Substances"'' became a classic work in the field of chemical thermodynamics. In 1932, Merle Randall authored two scientific papers with Mikkel Frandsen: ''"The Standard Electrode Potential of Iron and the Activity Coefficient of Ferrous Chloride,"'' and ''"Determination of the Free Energy of Ferrous Hydroxide from Measurements of Electromotive Force."'' Education Randall completed his Ph.D. at the Massachusetts Institute of Technology in 1912 with a dissertation on ''"Studies in Free Energy"''.Randall, Merle (1912). ''Studies in Free Energy''. Ph.D. Thesis/dissertation — Massachusetts Institute of Technology. Related Based on work by J. Willard ...
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Gilbert N
Gilbert may refer to: People and fictional characters *Gilbert (given name), including a list of people and fictional characters * Gilbert (surname), including a list of people Places Australia * Gilbert River (Queensland) * Gilbert River (South Australia) Kiribati * Gilbert Islands, a chain of atolls and islands in the Pacific Ocean United States * Gilbert, Arizona, a town * Gilbert, Arkansas, a town * Gilbert, Florida, the airport of Winterhaven * Gilbert, Iowa, a city * Gilbert, Louisiana, a village * Gilbert, Michigan, and unincorporated community * Gilbert, Minnesota, a city * Gilbert, Nevada, ghost town * Gilbert, Ohio, an unincorporated community * Gilbert, Pennsylvania, an unincorporated community * Gilbert, South Carolina, a town * Gilbert, West Virginia, a town * Gilbert, Wisconsin, an unincorporated community * Mount Gilbert (other), various mountains * Gilbert River (Oregon) Outer space * Gilbert (lunar crater) * Gilbert (Martian crater) Arts a ...
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Antoine Lavoisier
Antoine-Laurent de Lavoisier ( ; ; 26 August 17438 May 1794), When reduced without charcoal, it gave off an air which supported respiration and combustion in an enhanced way. He concluded that this was just a pure form of common air and that it was the air itself "undivided, without alteration, without decomposition" which combined with metals on calcination. After returning from Paris, Priestley took up once again his investigation of the air from mercury calx. His results now showed that this air was not just an especially pure form of common air but was "five or six times better than common air, for the purpose of respiration, inflammation, and ... every other use of common air". He called the air dephlogisticated air, as he thought it was common air deprived of its phlogiston. Since it was therefore in a state to absorb a much greater quantity of phlogiston given off by burning bodies and respiring animals, the greatly enhanced combustion of substances and the greater ease ...
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Torbern Olof Bergman
Torbern Olof Bergman (''KVO'') (20 March 17358 July 1784) was a Swedish chemist and mineralogist noted for his 1775 ''Dissertation on Elective Attractions'', containing the largest chemical affinity tables ever published. Bergman was the first chemist to use the A, B, C, etc., system of notation for chemical species. Early life and education Torbern was born on 20 March 1735, the son of Barthold Bergman and Sara Hägg. He enrolled at the University of Uppsala at age 17. His father wished him to read either law or divinity, while he himself was anxious to study mathematics and natural science; in the effort to please both himself and his father, he overworked himself and harmed his health. During a period of enforced abstinence from study, he amused himself with field botany and entomology. He was able to send Linnaeus specimens of several new kinds of insects, and in 1756 he succeeded in proving that, contrary to the opinion of that naturalist, the so-called ''Coccus aquaticus'' ...
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