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Cavansite
Cavansite, whose name is derived from its chemical composition, ''calcium vanadium silicate'', is a deep blue hydrous calcium vanadium phyllosilicate mineral, occurring as a secondary mineral in basaltic and andesitic rocks along with a variety of zeolite minerals. Discovered in 1967 in Malheur County, Oregon, cavansite is a relatively rare mineral. It is polymorphic with the even rarer mineral, pentagonite. It is most frequently found in Pune, India and in the Deccan Traps, a large igneous province. Uses of cavansite Although cavansite contains vanadium, and could thus be a possible ore source for the element, it is not generally considered an ore mineral. However, because of its rich color and relative rarity, cavansite is a sought-after collector's mineral. Associated minerals * Members of the apophyllite group * Members of the zeolite group, particularly stilbite * babingtonite, Ca2 Fe2 Si5 O14 OH * quartz, Si O2 * calcite Calcite is a carbonate mineral and the most s ...
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Oxovanadium
The vanadyl or oxovanadium(IV) cation, VO2+, is a functional group that is common in the coordination chemistry of vanadium. Complexes containing this functional group are characteristically blue and paramagnetic. A triple bond is proposed to exist between the V4+ and O2− centers. The description of the bonding in the vanadyl ion was central to the development of modern ligand-field theory. Natural occurrence Minerals Cavansite and pentagonite are vanadyl-containing minerals. Water VO2+, often in an ionic pairing with sodium (NaH2VO4), is the second most abundant transition metal in seawater, with its concentration only being exceeded by molybdenum. In the ocean the average concentration is 30  nM. Some mineral water springs also contain the ion in high concentrations. For example, springs near Mount Fuji often contain as much as 54 μg per liter. Vanadyl containing compounds Oxovanadium(IV) * vanadyl acetylacetonate, VO(acac)2 * vanadyl sulfate pentahydrate, ...
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Silicate Mineral
Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust. In mineralogy, silica (silicon dioxide, ) is usually considered a silicate mineral. Silica is found in nature as the mineral quartz, and its polymorphs. On Earth, a wide variety of silicate minerals occur in an even wider range of combinations as a result of the processes that have been forming and re-working the crust for billions of years. These processes include partial melting, crystallization, fractionation, metamorphism, weathering, and diagenesis. Living organisms also contribute to this geologic cycle. For example, a type of plankton known as diatoms construct their exoskeletons ("frustules") from silica extracted from seawater. The frustules of dead diatoms are a major constituent of deep ocean sediment, and of diatomaceous earth. General structure A silicate mineral is generally ...
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Pentagonite
Pentagonite is a rare silicate mineral with formula Ca(VO)Si4O10·4(H2O). It was named for the unusual twinning which produces an apparent five-fold symmetry. It is a dimorph of cavansite. Pentagonite was first described in 1973 for an occurrence in Lake Owyhee State Park, Malheur County, Oregon. It has also been reported from the Pune district of India. It occurs as fracture and cavity fillings in tuff and basalt. It occurs with cavansite, heulandite, stilbite, analcime, apophyllite and calcite Calcite is a Carbonate minerals, carbonate mineral and the most stable Polymorphism (materials science), polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on .... References Phyllosilicates Orthorhombic minerals Minerals in space group 36 Vanadium minerals {{silicate-mineral-stub ...
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Water
Water (chemical formula ) is an inorganic, transparent, tasteless, odorless, and nearly colorless chemical substance, which is the main constituent of Earth's hydrosphere and the fluids of all known living organisms (in which it acts as a solvent). It is vital for all known forms of life, despite not providing food, energy or organic micronutrients. Its chemical formula, H2O, indicates that each of its molecules contains one oxygen and two hydrogen atoms, connected by covalent bonds. The hydrogen atoms are attached to the oxygen atom at an angle of 104.45°. "Water" is also the name of the liquid state of H2O at standard temperature and pressure. A number of natural states of water exist. It forms precipitation in the form of rain and aerosols in the form of fog. Clouds consist of suspended droplets of water and ice, its solid state. When finely divided, crystalline ice may precipitate in the form of snow. The gaseous state of water is steam or water vapor. W ...
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Carbonate
A carbonate is a salt of carbonic acid (H2CO3), characterized by the presence of the carbonate ion, a polyatomic ion with the formula . The word ''carbonate'' may also refer to a carbonate ester, an organic compound containing the carbonate group C(=O)(O–)2. The term is also used as a verb, to describe carbonation: the process of raising the concentrations of carbonate and bicarbonate ions in water to produce carbonated water and other carbonated beverageseither by the addition of carbon dioxide gas under pressure or by dissolving carbonate or bicarbonate salts into the water. In geology and mineralogy, the term "carbonate" can refer both to carbonate minerals and carbonate rock (which is made of chiefly carbonate minerals), and both are dominated by the carbonate ion, . Carbonate minerals are extremely varied and ubiquitous in chemically precipitated sedimentary rock. The most common are calcite or calcium carbonate, CaCO3, the chief constituent of limestone (as ...
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Calcite
Calcite is a carbonate mineral and the most stable polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on the Mohs scale of mineral hardness, based on scratch hardness comparison. Large calcite crystals are used in optical equipment, and limestone composed mostly of calcite has numerous uses. Other polymorphs of calcium carbonate are the minerals aragonite and vaterite. Aragonite will change to calcite over timescales of days or less at temperatures exceeding 300 °C, and vaterite is even less stable. Etymology Calcite is derived from the German ''Calcit'', a term from the 19th century that came from the Latin word for lime, ''calx'' (genitive calcis) with the suffix "-ite" used to name minerals. It is thus etymologically related to chalk. When applied by archaeologists and stone trade professionals, the term alabaster is used not just as in geology and mineralogy, where it is ...
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Quartz
Quartz is a hard, crystalline mineral composed of silica ( silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical formula of SiO2. Quartz is the second most abundant mineral in Earth's continental crust, behind feldspar. Quartz exists in two forms, the normal α-quartz and the high-temperature β-quartz, both of which are chiral. The transformation from α-quartz to β-quartz takes place abruptly at . Since the transformation is accompanied by a significant change in volume, it can easily induce microfracturing of ceramics or rocks passing through this temperature threshold. There are many different varieties of quartz, several of which are classified as gemstones. Since antiquity, varieties of quartz have been the most commonly used minerals in the making of jewelry and hardstone carvings, especially in Eurasia. Quartz is the mineral definin ...
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Hydroxide
Hydroxide is a diatomic anion with chemical formula OH−. It consists of an oxygen and hydrogen atom held together by a single covalent bond, and carries a negative electric charge. It is an important but usually minor constituent of water. It functions as a base, a ligand, a nucleophile, and a catalyst. The hydroxide ion forms salts, some of which dissociate in aqueous solution, liberating solvated hydroxide ions. Sodium hydroxide is a multi-million-ton per annum commodity chemical. The corresponding electrically neutral compound HO• is the hydroxyl radical. The corresponding covalently bound group –OH of atoms is the hydroxy group. Both the hydroxide ion and hydroxy group are nucleophiles and can act as catalysts in organic chemistry. Many inorganic substances which bear the word ''hydroxide'' in their names are not ionic compounds of the hydroxide ion, but covalent compounds which contain hydroxy groups. Hydroxide ion The hydroxide ion is a nat ...
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Iron
Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in front of oxygen (32.1% and 30.1%, respectively), forming much of Earth's outer and inner core. It is the fourth most common element in the Earth's crust. In its metallic state, iron is rare in the Earth's crust, limited mainly to deposition by meteorites. Iron ores, by contrast, are among the most abundant in the Earth's crust, although extracting usable metal from them requires kilns or furnaces capable of reaching or higher, about higher than that required to smelt copper. Humans started to master that process in Eurasia during the 2nd millennium BCE and the use of iron tools and weapons began to displace copper alloys, in some regions, only around 1200 BCE. That event is considered the transition from the Bronze Age to the ...
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Babingtonite
Babingtonite is a calcium iron manganese inosilicate mineral with the formula Ca2( Fe, Mn)Fe Si5 O14(O H). It is unusual in that iron(III) completely replaces the aluminium so typical of silicate minerals. It is a very dark green to black translucent (in thin crystals or splinters) mineral crystallizing in the triclinic system with typically radial short prismatic clusters and druzy coatings. It occurs with zeolite minerals in cavities in volcanic rocks. Babingtonite contains both iron(II) and iron(III) and shows weak magnetism. It has a Mohs hardness of 5.5 to 6 and a specific gravity of 3.3. It was first described in 1824 from samples from Arendal, Aust-Agder, Norway (which is its type locality) and was named after the Irish physician and mineralogist William Babington (1757–1833). It is the official mineral (mineral emblem) of the Commonwealth of Massachusetts. The first published report of babingtonite in Massachusetts was by Francis Alger in 1844, who credited Thomas Nutt ...
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Stilbite
Stilbite is the name of a series of tectosilicate minerals of the zeolite group. Prior to 1997, stilbite was recognized as a mineral species, but a reclassification in 1997 by the International Mineralogical Association changed it to a series name, with the mineral species being named: * Stilbite-Ca * Stilbite-Na Stilbite-Ca, by far the more common of the two, is a hydrous calcium sodium and aluminium silicate, Na Ca4( Si27 Al9) O72·28( H2 O). In the case of stilbite-Na, sodium dominates over calcium. The species are visually indistinguishable, and the series name stilbite is still used whenever testing has not been performed. History At one time heulandite and stilbite were considered to be identical minerals. After they were found to be two separate species, in 1818, the name desmine ("a bundle") was proposed for stilbite, and this name is still employed in Germany. The English name "stilbite" is from the Greek stilbein = to shine, because of the pearly luster of the f ...
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Apophyllite
The name apophyllite refers to a specific group of phyllosilicates, a class of minerals. Originally, the group name referred to a specific mineral, but was redefined in 1978 to stand for a class of minerals of similar chemical makeup that comprise a solid solution series, and includes the members fluorapophyllite-(K), fluorapophyllite-(Na), hydroxyapophyllite-(K). The name apophyllite is derived from the Greek ἀποφυλλίζω ''apophylliso,'' meaning "it flakes off", a reference to this class's tendency to flake apart when heated, due to water loss. Exfoliation of apophyllite is also possible by treating it with acids or simply by rubbing it. These minerals are typically found as secondary minerals in vesicles in basalt or other volcanic rocks. A recent change (2008) in the nomenclature system used for this group was approved by the International Mineralogical Association, removing the prefixes from the species names and using suffixes to designate the species.Burke, E.A.J ...
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