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Aramid
Aramid fibers, short for aromatic polyamide, are a class of heat-resistant and strong synthetic fibers. They are used in aerospace and military applications, for ballistic-rated bulletproof vest, body armor cloth, fabric and ballistic composites, in marine cordage, marine hull reinforcement, as an asbestos substitute, and in various lightweight consumer items ranging from phone cases to tennis rackets. The chain molecules in the fibers are highly oriented along the fiber axis. As a result, a higher proportion of the chemical bond contributes more to fiber strength than in many other synthetic fibres in the world. Aramids have a very high melting point (>). Common aramid brand names include Kevlar, Nomex, and Twaron. Terminology and chemical structure The term ''aramid'' is shortened from ''aromatic polyamide''. It was introduced in 1972, accepted in 1974 by the Federal Trade Commission of the USA as the name of a generic category of fiber distinct from nylon, and adopted by t ...
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Twaron
Twaron (a brand name of Teijin Aramid) is a para-aramid, high-performance yarn. It is a heat-resistant fibre, helps in ballistic protection and cut protection. Twaron was developed in the early 1970s by the Dutch company Akzo Nobel's division Enka BV, later Akzo Industrial Fibers. The research name of the para-aramid fibre was originally Fiber X, but it was soon called Arenka. Although the Dutch para-aramid fiber was developed only a short time after DuPont's Kevlar, the introduction of Twaron as a commercial product came much later than Kevlar due to financial problems at the Akzo company in the 1970s. As of 2000, Twaron had become a global material and had been integrated into the global markets. Twaron has been around for over 30 years. History This is a chronology of the development of Twaron: * In 1960s a research program starts for "Fiber X." * In 1972 the ENKA Research laboratory develops a para-aramid called Arenka. * In 1973 Akzo decides to use sulfuric acid (H2SO4) ...
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Teijin Aramid
Teijin Aramid, formerly known as Teijin Twaron, is a company in The Netherlands that produces various high-strength fibers for industrial purposes, most notably their para-aramid, Twaron. Twaron finds applications in numerous markets, such as automotive (tires, hoses, belts), aerospace, civil engineering, construction, leisure goods (e.g. boats), protective clothing (bullet-, fire- and cut-resistant clothing), optical fiber cables, friction and sealing materials and more. The company has been part of the Japanese Teijin Group since 2000, prior to this they were a division of Akzo Nobel, division Industrial Fibers. Next to Twaron, the company markets Technora, Teijinconex as well. History Twaron is a heat-resistant and strong synthetic fiber, developed in early 1970s by the Dutch company AKZO, division Enka, later Akzo Nobel Industrial Fibers. The research name of the aramid was originally Fiber X, but soon called Arenka. In 1973, Akzo decided to use sulphuric acid (H2SO4) ...
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Bulletproof Vest
A bulletproof vest, also known as a ballistic vest or bullet-resistant vest, is a type of body armor designed to absorb impact and prevent the penetration of firearm projectiles and explosion fragments to the torso. The vest can be either soft—as worn by police officers, security personnel, prison guards, and occasionally private citizens to protect against stabbing attacks or light projectiles—or hard, incorporating metallic or para-aramid components. Soldiers and police tactical units typically wear hard armour, either alone or combined with soft armour, to protect against rifle ammunition or fragmentation. Additional protection includes trauma plates for blunt force and ceramic inserts for high-caliber rounds. Bulletproof vests have evolved over centuries, from early designs like those made for knights and military leaders to modern-day versions. Early ballistic protection used materials like cotton and silk, while contemporary vests employ advanced fibers and cera ...
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Polyamide
A polyamide is a polymer with repeating units linked by amide bonds. Polyamides occur both naturally and artificially. Examples of naturally occurring polyamides are proteins, such as wool and silk. Artificially made polyamides can be made through step-growth polymerization or solid-phase synthesis yielding materials such as nylons, aramids, and sodium polyaspartate. Synthetic polyamides are commonly used in textiles, automotive industry, carpets, kitchen utensils and sportswear due to their high durability and strength. The transportation manufacturing industry is the major consumer, accounting for 35% of polyamide (PA) consumption. Classification Polymers of amino acids are known as polypeptides or proteins. According to the composition of their main chain, synthetic polyamides are classified as follows: All polyamides are made by the formation of an amide function to link two molecules of monomer together. The monomers can be amides themselves (usually in the form of a ...
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Nomex
Nomex is a trademarked term for an inherently flame-resistant fabric with meta-aramid chemistry widely used for industrial applications and fire protection equipment. It was developed in the early 1960s by DuPont and first marketed in 1967. The fabric is often combined with Kevlar to increase its resistance for breakage or tear. Properties Nomex and related aramid polymers are related to nylon, but have aromatic backbones, and hence are more rigid and more durable. Nomex is an example of a '' meta'' variant of the aramids (Kevlar is a '' para'' aramid). Unlike Kevlar, Nomex strands cannot align during filament polymerization and have less strength: its ultimate tensile strength is . However, it has excellent thermal, chemical, and radiation resistance for a polymer material. It can withstand temperatures of up to . Production Nomex is produced by condensation reaction from the monomers ''m''-phenylenediamine and isophthaloyl chloride. It is sold in both fiber and s ...
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Kevlar
Kevlar (para-aramid) is a strong, heat-resistant synthetic fiber, related to other aramids such as Nomex and Technora. Developed by Stephanie Kwolek at DuPont in 1965, the high-strength material was first used commercially in the early 1970s as a replacement for steel in racing tires. It is typically spun into ropes or fabric sheets that can be used as such, or as an ingredient in composite material components. Kevlar has many applications, ranging from bicycle tires and sailcloth#Kevlar, racing sails to bulletproof vests, due to its high Specific strength, tensile strength-to-weight ratio; by this measure it is five times stronger than steel. It is also used to make modern marching drumheads that withstand high impact, and for Mooring, mooring lines and other underwater applications. A similar fiber, Twaron, with the same chemical structure was developed by Akzo in the 1970s. Commercial production started in 1986, and Twaron is manufactured by Teijin Aramid. History Poly- ...
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Kevlar Chemical Structure H-bonds
Kevlar (para-aramid) is a strong, heat-resistant synthetic fiber, related to other aramids such as Nomex and Technora. Developed by Stephanie Kwolek at DuPont in 1965, the high-strength material was first used commercially in the early 1970s as a replacement for steel in racing tires. It is typically spun into ropes or fabric sheets that can be used as such, or as an ingredient in composite material components. Kevlar has many applications, ranging from bicycle tires and racing sails to bulletproof vests, due to its high tensile strength-to-weight ratio; by this measure it is five times stronger than steel. It is also used to make modern marching drumheads that withstand high impact, and for mooring lines and other underwater applications. A similar fiber, Twaron, with the same chemical structure was developed by Akzo in the 1970s. Commercial production started in 1986, and Twaron is manufactured by Teijin Aramid. History Poly-paraphenylene terephthalamide (K29) – ...
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Nylon
Nylon is a family of synthetic polymers characterised by amide linkages, typically connecting aliphatic or Polyamide#Classification, semi-aromatic groups. Nylons are generally brownish in color and can possess a soft texture, with some varieties exhibiting a silk-like appearance. As Thermoplastic, thermoplastics, nylons can be melt-processed into fibres, Thin film, films, and diverse shapes. The properties of nylons are often modified by blending with a variety of additives. Numerous types of nylon are available. One family, designated nylon-XY, is derived from diamines and dicarboxylic acids of carbon chain lengths X and Y, respectively. An important example is nylon-6,6 (). Another family, designated nylon-Z, is derived from amino acid, aminocarboxylic acids with carbon chain length Z. An example is nylon-[6]. Nylon polymers have extensive commercial applications, including uses in textiles and fibres (such as apparel, flooring and rubber reinforcement), molded components fo ...
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Amide
In organic chemistry, an amide, also known as an organic amide or a carboxamide, is a chemical compound, compound with the general formula , where R, R', and R″ represent any group, typically organyl functional group, groups or hydrogen atoms. The amide group is called a peptide bond when it is part of the Polymer backbone, main chain of a protein, and an isopeptide bond when it occurs in a side chain, as in asparagine and glutamine. It can be viewed as a Derivative (chemistry), derivative of a carboxylic acid () with the hydroxyl group () replaced by an amino group (); or, equivalently, an acyl group, acyl (alkanoyl) group () joined to an amino group. Common amides are formamide (), acetamide (), benzamide (), and dimethylformamide (). Some uncommon examples of amides are ''N''-chloroacetamide () and chloroformamide (). Amides are qualified as primary (chemistry), primary, secondary (chemistry), secondary, and tertiary (chemistry), tertiary according to the number of acyl ...
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Cloth
Textile is an umbrella term that includes various fiber-based materials, including fibers, yarns, filaments, threads, and different types of fabric. At first, the word "textiles" only referred to woven fabrics. However, weaving is not the only manufacturing method, and many other methods were later developed to form textile structures based on their intended use. Knitting and non-woven are other popular types of fabric manufacturing. In the contemporary world, textiles satisfy the material needs for versatile applications, from simple daily clothing to bulletproof jackets, spacesuits, and doctor's gowns. Textiles are divided into two groups: consumer textiles for domestic purposes and technical textiles. In consumer textiles, aesthetics and comfort are the most important factors, while in technical textiles, functional properties are the priority. The durability of textiles is an important property, with common cotton or blend garments (such as t-shirts) able to ...
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Asbestos
Asbestos ( ) is a group of naturally occurring, Toxicity, toxic, carcinogenic and fibrous silicate minerals. There are six types, all of which are composed of long and thin fibrous Crystal habit, crystals, each fibre (particulate with length substantially greater than width) being composed of many microscopic "fibrils" that can be released into the atmosphere by Abrasion (mechanical), abrasion and other processes. Inhalation of asbestos fibres can lead to various dangerous lung conditions, including mesothelioma, asbestosis, and lung cancer. As a result of these health effects, asbestos is considered a serious Health hazard, health and safety hazard. Archaeological studies have found evidence of asbestos being used as far back as the Stone Age to strengthen ceramic pots, but large-scale mining began at the end of the 19th century when manufacturers and builders began using asbestos for its desirable physical properties. Asbestos is an excellent Thermal insulation, thermal and In ...
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Arene Substitution Pattern
Arene substitution patterns are part of organic chemistry IUPAC nomenclature and pinpoint the position of substituents other than hydrogen in relation to each other on an aromatic hydrocarbon. ''Ortho'', ''meta'', and ''para'' substitution * In ''ortho''-substitution, two substituents occupy positions next to each other, which may be numbered 1 and 2. In the diagram, these positions are marked R and ''ortho''. * In ''meta''-substitution, the substituents occupy positions 1 and 3 (corresponding to R and ''meta'' in the diagram). * In ''para''-substitution, the substituents occupy the opposite ends (positions 1 and 4, corresponding to R and ''para'' in the diagram). The toluidines serve as an example for these three types of substitution. Synthesis Electron donating groups, for example amino, hydroxyl, alkyl, and phenyl groups tend to be ''ortho''/''para''-directors, and electron withdrawing groups such as nitro, nitrile, and ketone groups, tend to be ''meta''-directors. Pro ...
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