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A Value
400px, The A-value for a methyl group is 1.74 as derived from the chemical equilibrium above. This means it costs of energy to have a methyl group in the axial position compared to the equatorial position. A-values are numerical values used in the determination of the most stable orientation of atoms in a molecule (Conformational isomerism, conformational analysis), as well as a general representation of steric bulk. A-values are derived from energy measurements of the different cyclohexane conformations of a monosubstituted cyclohexane chemical. Substituents on a cyclohexane ring prefer to reside in the equatorial position to the axial. The difference in Gibbs free energy (ΔG) between the higher energy conformation (axial substitution) and the lower energy conformation (equatorial substitution) is the A-value for that particular substituent. Utility A-values help predict the conformation of cyclohexane rings. The most stable conformation will be the one which has the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Pitzer Strain
Pitzer is a surname, and may refer to: * Alexander White Pitzer (1834–1927), American Presbyterian clergyman * Gys Pitzer (1939–2025), South African rugby union player * Kenneth Sanborn Pitzer (1914–1997), American theoretical chemist * Russell Kelly Pitzer (1878–1978), American businessman and philanthropist * Russell Mosher Pitzer (1938–), American theoretical chemist * William Bruce Pitzer (1917–1966), American Naval officer See also * Pitzer College, liberal arts college located in Claremont, California, United States, named after Russell K. Pitzer * Pitzer equations, thermodynamic equations named after Kenneth S. Pitzer {{surname ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Carboxylic Acid
In organic chemistry, a carboxylic acid is an organic acid that contains a carboxyl group () attached to an Substituent, R-group. The general formula of a carboxylic acid is often written as or , sometimes as with R referring to an organyl group (e.g., alkyl, alkenyl, aryl), or hydrogen, or other groups. Carboxylic acids occur widely. Important examples include the amino acids and fatty acids. Deprotonation of a carboxylic acid gives a carboxylate anion. Examples and nomenclature Carboxylic acids are commonly identified by their trivial names. They often have the suffix ''-ic acid''. IUPAC-recommended names also exist; in this system, carboxylic acids have an ''-oic acid'' suffix. For example, butyric acid () is butanoic acid by IUPAC guidelines. For nomenclature of complex molecules containing a carboxylic acid, the carboxyl can be considered position one of the parent chain even if there are other substituents, such as 3-chloropropanoic acid. Alternately, it can be named ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Journal Of The American Chemical Society
The ''Journal of the American Chemical Society'' (also known as JACS) is a weekly peer-reviewed scientific journal that was established in 1879 by the American Chemical Society. The journal has absorbed two other publications in its history, the ''Journal of Analytical and Applied Chemistry'' (July 1893) and the ''American Chemical Journal'' (January 1914). It covers all fields of chemistry. Since 2021, the editor-in-chief is Erick M. Carreira (ETH Zurich). In 2014, the journal moved to a hybrid open access publishing model. Abstracting and indexing The journal is abstracted and indexed in: According to the ''Journal Citation Reports'', the journal has a 2023 impact factor The impact factor (IF) or journal impact factor (JIF) of an academic journal is a type of journal ranking. Journals with higher impact factor values are considered more prestigious or important within their field. The Impact Factor of a journa ... of 14.4. Editors-in-chief The following people are or ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Reaction Rate
The reaction rate or rate of reaction is the speed at which a chemical reaction takes place, defined as proportional to the increase in the concentration of a product per unit time and to the decrease in the concentration of a reactant per unit time. Reaction rates can vary dramatically. For example, the oxidative rusting of iron under Earth's atmosphere is a slow reaction that can take many years, but the combustion of cellulose in a fire is a reaction that takes place in fractions of a second. For most reactions, the rate decreases as the reaction proceeds. A reaction's rate can be determined by measuring the changes in concentration over time. Chemical kinetics is the part of physical chemistry that concerns how rates of chemical reactions are measured and predicted, and how reaction-rate data can be used to deduce probable reaction mechanisms. The concepts of chemical kinetics are applied in many disciplines, such as chemical engineering, enzymology and environmental e ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ax Pos
An axe (; sometimes spelled ax in American English; see spelling differences) is an implement that has been used for thousands of years to shape, split, and cut wood, to harvest timber, and as a weapon. The axe has many forms and specialised uses but generally consists of a head with a handle (also called "haft" or "helve"). Before the modern axe, the stone-age hand axe without a handle was used from 1.5 million years BP. Hafted axes (those with a handle) date only from 6,000 BC. The earliest examples of handled axes have heads of stone with some form of wooden handle attached ( hafted) in a method to suit the available materials and use. Axes made of copper, bronze, iron and steel appeared as these technologies developed. The axe is an example of a simple machine, as it is a type of wedge, or dual inclined plane. This reduces the effort needed by the wood chopper. It splits the wood into two parts by the pressure concentration at the blade. The handle of the axe also ac ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Microstate (statistical Mechanics)
In statistical mechanics, a microstate is a specific configuration of a system that describes the precise positions and momenta of all the individual particles or components that make up the system. Each microstate has a certain probability of occurring during the course of the system's thermal fluctuations. In contrast, the macrostate of a system refers to its macroscopic properties, such as its temperature, pressure, volume and density. Treatments on statistical mechanics define a macrostate as follows: a particular set of values of energy, the number of particles, and the volume of an isolated thermodynamic system is said to specify a particular macrostate of it. In this description, microstates appear as different possible ways the system can achieve a particular macrostate. A macrostate is characterized by a probability distribution of possible states across a certain statistical ensemble of all microstates. This distribution describes the probability of finding the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
