Α-Pinene
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Α-Pinene
α-Pinene is an organic compound of the terpene class. It is one of the two isomers of pinene, the other being β-pinene. An alkene, it contains a strained four-membered ring. It is found in the oils of many species of coniferous trees, notably ''Pinus'' and ''Picea'' species. It is also found in the essential oil of rosemary (''Rosmarinus officinalis'') and ''Satureja myrtifolia'' (also known as ''Zoufa'' in some regions). Both enantiomers are known in nature; (1''S'',5''S'')- or (−)-α-pinene is more common in European pines, whereas the (1''R'',5''R'')- or (+)-α-isomer is more common in North America. The enantiomers' racemic mixture is present in some oils such as eucalyptus oil and orange peel oil. Reactivity : Commercially important derivatives of α-pinene are linalool, geraniol, nerol, α-terpineol, and camphene. α-Pinene 1 demonstrates reactivity arising from the presence of the four-membered ring adjacent to the alkene. The compound is prone to skeletal rearr ...
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Chloroform
Chloroform, or trichloromethane (often abbreviated as TCM), is an organochloride with the formula and a common solvent. It is a volatile, colorless, sweet-smelling, dense liquid produced on a large scale as a precursor to refrigerants and polytetrafluoroethylene (PTFE). Chloroform was once used as an inhalational anesthetic between the 19th century and the first half of the 20th century. It is miscible with many solvents but it is only very slightly soluble in water (only 8 g/L at 20°C). Structure and name The molecule adopts a tetrahedral molecular geometry with C3v symmetry. The chloroform molecule can be viewed as a methane molecule with three hydrogen atoms replaced with three chlorine atoms, leaving a single hydrogen atom. The name "chloroform" is a portmanteau of ''terchloride'' (tertiary chloride, a trichloride) and ''formyle'', an obsolete name for the methylylidene radical (CH) derived from formic acid. Natural occurrence Many kinds of seaweed produce chlor ...
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Pine
A pine is any conifer tree or shrub in the genus ''Pinus'' () of the family Pinaceae. ''Pinus'' is the sole genus in the subfamily Pinoideae. ''World Flora Online'' accepts 134 species-rank taxa (119 species and 15 nothospecies) of pines as current, with additional synonyms, and ''Plants of the World Online'' 126 species-rank taxa (113 species and 13 nothospecies), making it the largest genus among the conifers. The highest species diversity of pines is found in Mexico. Pines are widely species distribution, distributed in the Northern Hemisphere; they occupy large areas of boreal forest, but are found in many habitats, including the Mediterranean Basin, and dry tropical forests in southeast Asia and Central America. Wood from pine trees is one of the most extensively used types of timber, and some pines are widely used as Christmas trees. Description Pine trees are evergreen, coniferous resinous trees (or, rarely, shrubs) growing tall, with the majority of species reachin ...
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Nerol
Nerol is a monoterpenoid alcohol found in many essential oils such as lemongrass and hops. It was originally isolated from neroli oil, hence its name. This colourless liquid is used in perfumery. Like geraniol, nerol has a sweet rose odor but it is considered to be fresher.Karl-Georg Fahlbusch, Franz-Josef Hammerschmidt, Johannes Panten, Wilhelm Pickenhagen, Dietmar Schatkowski, Kurt Bauer, Dorothea Garbe, Horst Surburg "Flavors and Fragrances" in Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH, Weinheim, 2002. Esters and related derivatives of nerol are referred to as neryl, e.g., neryl acetate. Isomeric with nerol is geraniol, which is its ''trans''- or ''E''-isomer. Nerol readily loses water to form a set of C10 compounds called dipentene. Nerol can be synthesized by pyrolysis of beta-pinene, which also affords myrcene. Hydrochlorination of myrcene gives a series of isomeric chlorides. See also *Citral * Citronellol *Geraniol *Linalool Linalool () refers to tw ...
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Geraniol
Geraniol is a monoterpenoid and an alcohol. It is the primary component of citronella oil and is a primary component of rose oil and palmarosa oil. It is a colorless oil, although commercial samples can appear yellow. It has low solubility in water, but it is soluble in common organic solvents. Uses and occurrence In addition to being found in rose oil, palmarosa oil, and citronella oil, it also occurs in small quantities in geranium, lemon, and many other essential oils. With a rose-like scent, it is commonly used in perfumes and in scents such as peach, raspberry, grapefruit, red apple, plum, lime, orange, lemon, watermelon, pineapple, and blueberry. Geraniol is produced by the scent glands of honeybees to mark nectar-bearing flowers and locate the entrances to their hives. It is also commonly used as an insect repellent, especially for mosquitoes. The scent of geraniol is reminiscent of, but chemically unrelated to, 2-ethoxy-3,5-hexadiene, also known as gerani ...
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Linalool
Linalool () refers to two enantiomers of a naturally occurring terpene alcohol found in many flowers and spice plants. Together with geraniol, nerol, and citronellol, linalool is one of the rose alcohols. Linalool has multiple commercial applications, the majority of which are based on its pleasant scent (floral, with a touch of spiciness). A colorless oil, linalool is classified as an acyclic monoterpenoid. In plants, it is a metabolite, a volatile oil component, an antimicrobial agent, and an aroma compound. Linalool has uses in manufacturing of soaps, fragrances, food additives as flavors, household products, and insecticides. Esters of linalool are referred to as linalyl, e.g. linalyl pyrophosphate, an isomer of geranyl pyrophosphate. The word ''linalool'' is based on '' linaloe'' (a type of wood) and the suffix '. In food manufacturing, it may be called ''coriandrol''. Occurrence Both enantiomeric forms are found in nature: (''S'')-linalool is found, for exam ...
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Orange Peel Oil
Orange oil is an essential oil produced by cells within the rind of an orange fruit (''Citrus sinensis'' fruit). In contrast to most essential oils, it is extracted as a by-product of orange juice production by centrifugation, producing a cold-pressed oil. It is composed of mostly (greater than 90%) d-limonene, and is often used in place of pure d-limonene. D-limonene can be extracted from the oil by distillation. Composition The compounds inside an orange oil vary with each different oil extraction. Composition varies as a result of regional and seasonal changes as well as the method used for extraction. Several hundred compounds have been identified with gas chromatograph-mass spectrometry. Most of the substances in the oil belong to the terpene group with limonene being the dominant one. Long chain aliphatic hydrocarbon alcohols and aldehydes like 1-octanol and octanal are second important group of substances. The presence of sinensetin, a flavone, explains the orange colo ...
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Eucalyptus Oil
Eucalyptus oil is the generic name for distilled oil from the leaves of ''Eucalyptus'', a genus of the plant family Myrtaceae, mostly native to Australia but cultivated worldwide. Eucalyptus oil has a history of wide application, as a pharmaceutical, antiseptic, insect repellent, repellent, flavouring and fragrance, as well as having industrial uses. The leaves of selected ''Eucalyptus'' species are steam distillation, steam distilled to extract eucalyptus oil. Types and production In the trade, eucalyptus oils are categorized into three broad types according to their composition and main end-use: medicinal, perfumery and industrial. The most prevalent is the standard cineole-based "oil of eucalyptus", a colourless mobile liquid (which yellows with age), having a penetrating, camphoraceous, woody plant, woody-sweet scent. China produces about 75% of the world output, but most of that is derived from the cineole fractions of Cinnamomum camphora, camphor laurel rather than being ...
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Racemic Mixture
In chemistry, a racemic mixture or racemate () is a mixture that has equal amounts (50:50) of left- and right-handed enantiomers of a chiral molecule or salt. Racemic mixtures are rare in nature, but many compounds are produced industrially as racemates. History The first known racemic mixture was racemic acid, which Louis Pasteur found to be a mixture of the two enantiomeric isomers of tartaric acid. He manually separated the crystals of a mixture, starting from an aqueous solution of the sodium ammonium salt of racemate tartaric acid. Pasteur benefited from the fact that ammonium tartrate salt gives enantiomeric crystals with distinct crystal forms (at 77 Â°F). Reasoning from the macroscopic scale down to the molecular, he reckoned that the molecules had to have non-superimposable mirror images. A sample with only a single enantiomer is an ''enantiomerically pure'' or ''enantiopure'' compound. Etymology The word ''racemic'' derives from Latin , meaning pertaining to a ...
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Enantiomer
In chemistry, an enantiomer (Help:IPA/English, /ɪˈnænti.əmər, ɛ-, -oʊ-/ Help:Pronunciation respelling key, ''ih-NAN-tee-ə-mər''), also known as an optical isomer, antipode, or optical antipode, is one of a pair of molecular entities which are mirror images of each other and non-superposable. Enantiomer molecules are like right and left hands: one cannot be superposed onto the other without first being converted to its mirror image. It is solely a relationship of chirality (chemistry), chirality and the permanent three-dimensional relationships among molecules or other chemical structures: no amount of re-orientation of a molecule as a whole or conformational isomerism, conformational change converts one chemical into its enantiomer. Chemical structures with chirality rotate plane-polarized light. A mixture of equal amounts of each enantiomer, a ''racemic mixture'' or a ''racemate'', does not rotate light. Stereoisomers include both enantiomers and diastereomers. Diaste ...
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Satureja
''Satureja'' is a genus of aromatic plants of the family (biology), family Lamiaceae, related to rosemary and thyme. It is native to Southern Europe, southern and southeastern Europe, North Africa, the Middle East, and Central Asia. Historically, ''Satureja'' was defined broadly and many species of the subtribe Menthinae from throughout the world were included in it. In the modern cladistic era of botany, ''Satureja'' was redefined to a narrower monophyletic genus whose species are all native to Eurasia. Several species are cultivated as culinary herbs called savory, and they have become established in the wild in a few places. Description ''Satureja'' species may be annual plant, annual or perennial plant, perennial. They are low-growing herbs and subshrubs, reaching heights of . The leaf, leaves are long, with flowers forming in whorls on the stem, white to pale pink-violet. Ecology and cultivation ''Satureja'' species are food plants for the larva of some Lepidoptera (butter ...
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Rosmarinus
Rosmarinus ( ) is a small taxonomic clade of woody, perennial herbs with fragrant evergreen needle-like leaves in the family Lamiaceae, native to the Mediterranean Basin. In 2017 the species in the genus ''Rosmarinus'' were moved into the large genus ''Salvia'' based on taxonomic evidence. Thus ''Rosmarinus'' is no longer a genus, but still a monophyletic clade of species within ''Salvia''. Description '' Salvia rosmarinus'' (rosemary), widespread in the Mediterranean region, and '' Salvia jordanii'' (formerly ''Rosmarinus eriocalyx''), native to northwest Africa and southern Spain have long been widely recognized. '' Salvia granatensis'' (formerly ''Rosmarinus tomentosus'') was first recognized as a separate species in 1941. '' Rosmarinus palaui'' was first described as a species in 2002, although recognition of this species remains controversial. Recent research has indicated that while ''S. granatensis'' forms a monophyletic group, this group is nested within a paraphyletic ...
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