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Ze-gen, Inc. was a
renewable energy Renewable energy is energy that is collected from renewable resources that are naturally replenished on a human timescale. It includes sources such as sunlight, wind, the movement of water, and geothermal heat. Although most renewable energy ...
company developing advanced
gasification Gasification is a process that converts biomass- or fossil fuel-based carbonaceous materials into gases, including as the largest fractions: nitrogen (N2), carbon monoxide (CO), hydrogen (H2), and carbon dioxide (). This is achieved by reacting ...
technology to convert waste into
synthesis gas Syngas, or synthesis gas, is a mixture of hydrogen and carbon monoxide, in various ratios. The gas often contains some carbon dioxide and methane. It is principly used for producing ammonia or methanol. Syngas is combustible and can be used as ...
. Founded in 2004, Ze-gen was a venture-backed company based in Boston, Massachusetts. The company aimed to develop innovative technological solutions to reduce
landfills A landfill site, also known as a tip, dump, rubbish dump, garbage dump, or dumping ground, is a site for the disposal of waste materials. Landfill is the oldest and most common form of waste disposal, although the systematic burial of the waste ...
and find beneficial use for waste material by converting
waste to energy Waste-to-energy (WtE) or energy-from-waste (EfW) is the process of generating energy in the form of electricity and/or heat from the primary treatment of waste types, waste, or the processing of waste into a fuel source. WtE is a form of energy ...
and nutrients, using advanced gasification. Today Ze-gen appears to be defunct, and the company website was taken down in 2014.


Technology

The ''liquid metal gasification'' process begins with feed material entering the gasifier through a gas-tight airlock into a refractory-lined vessel containing liquid copper, which is held at about 2200 °F. Material entering into the liquid metal gasifier undergoes a series of thermo-chemical reactions, which are auto-thermal under stable operating conditions. Initially, pyrolysis occurs and volatiles are driven into the headspace of the gasifier. In the subsequent gasification reaction, hydrogen () and
carbon monoxide Carbon monoxide (chemical formula CO) is a colorless, poisonous, odorless, tasteless, flammable gas that is slightly less dense than air. Carbon monoxide consists of one carbon atom and one oxygen atom connected by a triple bond. It is the simple ...
(CO) are favored as final products, along with
carbon dioxide Carbon dioxide (chemical formula ) is a chemical compound made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature. In the air, carbon dioxide is transpar ...
() and a small amount of
methane Methane ( , ) is a chemical compound with the chemical formula (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The relative abundance of methane on Eart ...
(). This product gas is called synthesis gas, also known as
syngas Syngas, or synthesis gas, is a mixture of hydrogen and carbon monoxide, in various ratios. The gas often contains some carbon dioxide and methane. It is principly used for producing ammonia or methanol. Syngas is combustible and can be used as ...
. The inorganic constituents, which are generally lighter than liquid metal, form a
slag Slag is a by-product of smelting (pyrometallurgical) ores and used metals. Broadly, it can be classified as ferrous (by-products of processing iron and steel), ferroalloy (by-product of ferroalloy production) or non-ferrous/base metals (by-prod ...
layer on top of the liquid metal bath and are removed as a vitrified non-leachable slag byproduct. The slag is either recycled or disposed of as an industrial by-product. While some metals and oxides present in the feedstock accumulate in the liquid metal bath, others will exit as vapor and are captured in the gas cleanup process. The syngas produced can be used for several different end-use applications including: steam generation, electricity production, making industrial hydrogen gas, as chemical building blocks for
synthetic diesel Diesel fuel , also called diesel oil, is any liquid fuel specifically designed for use in a diesel engine, a type of internal combustion engine in which fuel ignition takes place without a spark as a result of compression of the inlet air and ...
or
ethanol Ethanol (abbr. EtOH; also called ethyl alcohol, grain alcohol, drinking alcohol, or simply alcohol) is an organic compound. It is an Alcohol (chemistry), alcohol with the chemical formula . Its formula can be also written as or (an ethyl ...
,
synthetic natural gas Substitute natural gas (SNG), or synthetic natural gas, is a fuel gas (predominantly methane, CH4) that can be produced from fossil fuels such as lignite coal, oil shale, or from biofuels (when it is named bio-SNG) or using electricity with power- ...
,
methanol Methanol (also called methyl alcohol and wood spirit, amongst other names) is an organic chemical and the simplest aliphatic alcohol, with the formula C H3 O H (a methyl group linked to a hydroxyl group, often abbreviated as MeOH). It is a ...
, or as a chemical feedstock into a variety of industrial processes.


Pilot Facility

Ze-gen's demonstration facility is colocated with a processing facility owned by New Bedford Waste Services, LLC in
New Bedford, Massachusetts New Bedford (Massachusett language, Massachusett: ) is a city in Bristol County, Massachusetts, Bristol County, Massachusetts. It is located on the Acushnet River in what is known as the South Coast (Massachusetts), South Coast region. Up throug ...
. The facility was built to test the key parameters of the gasification process in order to more fully understand the chemistry of the system and the operating parameters. The plant became operational in November 2007, and Ze-gen achieved target synthesis gas quality in June 2008. The data and analysis collected during the Phase I testing helped to inform modifications and upgrades in the facility. Phase II testing began in September 2009. As of June 2011, the demonstration facility has logged over 4200 hours of operation, including 30 days of consecutive runtime.


Commercial Facility

Ze-gen plans to develop its first commercial facility in Attleboro, Massachusetts. The proposed facility is to be located within the Attleboro Corporate Campus, a former
Texas Instruments Texas Instruments Incorporated (TI) is an American technology company headquartered in Dallas, Texas, that designs and manufactures semiconductors and various integrated circuits, which it sells to electronics designers and manufacturers globall ...
manufacturing facility and now the home to a number of businesses. Through the conversion of 44,000 tons of specific waste streams annually, the syngas produced at the facility will be used to generate approximately 7MW of
alternative energy Renewable energy is energy that is collected from renewable resources that are naturally replenished on a Orders of magnitude (time), human timescale. It includes sources such as Solar power, sunlight, wind power, wind, the movement of Hydropo ...
. The thermal and electrical power will be sold to tenants within the corporate campus, allowing the campus to reduce its reliance on fossil fuels. In April 2011, Ze-gen announced its decision to suspend its project in Attleboro in order to focus on developing its commercial facility project at a site with stronger energy markets and one that's more receptive to alternative energy development.


Funding

As of 2009, Ze-gen has received $30 million in funding from sources including: Omar Zawawi Establishment, Flagship Ventures, VantagePoint Venture Partners, and Massachusetts Technology Development Corporation.http://www.newenergyworldnetwork.com/renewable-energy-news/by_technology/energy_efficiency/ze-gen-raises-20m-in-series-b-financing.html


See also

*
Gasification Gasification is a process that converts biomass- or fossil fuel-based carbonaceous materials into gases, including as the largest fractions: nitrogen (N2), carbon monoxide (CO), hydrogen (H2), and carbon dioxide (). This is achieved by reacting ...
* Fischer-Tropsch *
Syngas Syngas, or synthesis gas, is a mixture of hydrogen and carbon monoxide, in various ratios. The gas often contains some carbon dioxide and methane. It is principly used for producing ammonia or methanol. Syngas is combustible and can be used as ...
*
Landfills A landfill site, also known as a tip, dump, rubbish dump, garbage dump, or dumping ground, is a site for the disposal of waste materials. Landfill is the oldest and most common form of waste disposal, although the systematic burial of the waste ...


References

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External links


“Ze-gen Energized By Middle East Conglomerate”

“A Special Report on Waste: The Appliance of Science”

“Betting on a Hot Market For Syngas”

“Energy Firm May Buzz into Attleboro”


Energy companies of the United States