Walfordite is a very rare

tellurite The tellurite ion is . A tellurite (compound), for example sodium tellurite, is a compound that contains this ion. They are typically colorless or white salts, which in some ways are comparable to sulfite. A mineral with the formula TeO2 is ...

mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2 ...

that was discovered in

Chile Chile, officially the Republic of Chile, is a country in the western part of South America. It is the southernmost country in the world, and the closest to Antarctica, occupying a long and narrow strip of land between the Andes to the east a ...

in 1999. The mineral is described as orange with orange-yellow streak, and is determined to have a chemical formula of Fe³⁺,Te⁶⁺Te⁴⁺₃O₈ with minor

titanium Titanium is a chemical element with the Symbol (chemistry), symbol Ti and atomic number 22. Found in nature only as an oxide, it can be reduced to produce a lustrous transition metal with a silver color, low density, and high strength, resista ...

and

magnesium Magnesium is a chemical element with the symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 of the periodic ta ...

substitution resulting in an approximate empirical formula of (Fe³⁺,Te⁶⁺,Ti⁴⁺,Mg)(Te⁴⁺)₃O₈.

Occurrence

The only reported occurrence is in the Wendy

open pit Open-pit mining, also known as open-cast or open-cut mining and in larger contexts mega-mining, is a surface mining technique of extracting rock or minerals from the earth from an open-air pit, sometimes known as a borrow. This form of minin ...

, El Indio-Tambo mining district of the

Coquimbo Region The Coquimbo Region ( es, Región de Coquimbo, ) is one of Chile's 16 regions (first order administrative divisions). It is bordered by Atacama to the north, Valparaíso to the south, Argentina to the east, and the Pacific Ocean to the west. ...

, northern Chile where it occurs in

oxidized Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or a ...

breccia Breccia () is a rock composed of large angular broken fragments of minerals or rocks cemented together by a fine-grained matrix. The word has its origins in the Italian language, in which it means "rubble". A breccia may have a variety of ...

associated with a

tellurium Tellurium is a chemical element with the symbol Te and atomic number 52. It is a brittle, mildly toxic, rare, silver-white metalloid. Tellurium is chemically related to selenium and sulfur, all three of which are chalcogens. It is occasionall ...

-bearing gold deposit. Associated minerals include: alunite, rodalquilarite, native gold,

emmonsite Emmonsite, also known as durdenite, is an iron tellurite mineral with the formula: Fe2(TeO3)3·2(H2O). Emmonsite forms triclinic crystals. It is of a yellowish-green color, with a vitreous luster, and a hardness of 5 on the Moh scale. Emmonsite ...

jarosite Jarosite is a basic hydrous sulfate of potassium and ferric iron (Fe-III) with a chemical formula of KFe3(SO4)2(OH)6. This sulfate mineral is formed in ore deposits by the oxidation of iron sulfides. Jarosite is often produced as a byproduct du ...

and

pyrite The mineral pyrite (), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula Fe S2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral. Pyrite's metallic luster and pale brass-yellow hue giv ...

. The mineral was named for mine geologist Phillip Walford (1945— ) who first noted the mineral.

References

Tellurite and selenite minerals Oxide minerals Cubic minerals Minerals in space group 206 {{Mineral-stub

Occurrence

See also

References