Vladimirite is a rare calcium arsenate mineral with a chemical formula, formula of Ca₅(HAsO₄)₂(AsO₄)₂·5H₂O. It is named after the Vladimirovskoye Deposition (geology), deposit in Russia, where it was discovered in the 1950s. Vladimirite is monoclinic-prismatic, which means crystallographically, it contains three axes of unequal length and the angles between two of the axes are 90 degrees, and one is less than 90 degrees. It belongs to the space group P2₁/c. The mineral also has an orthorhombic Polymorphism (materials science), polytype. In terms of its optical properties, vladimirite is anisotropic which means the velocity of light varies depending on direction through the mineral. Relief is a diagnostic characteristic of a mineral in plane polarized light that refers to the various ways different minerals "stand out". Vladimirite's calculated relief is 1.65-1.661, which is moderate. It is colorless in plane polarized light, and it is weakly pleochroic. Pleochroism is the variety of colors under plane polarized light displayed by crystals at various angles.

Occurrence

Vladimirite was first described in 1953 at two deposits in Russia, the Khovu-Aksy nickel-cobalt deposit, Tuva Republic, and the Vladimirovskoye cobalt deposit, Altai Mountains, Altaiskii Krai, Siberia. It is a secondary mineral in the Redox, oxidized zone of arsenic-bearing ore deposits. It occurs with picropharmacolite, erythrite and aragonite. It has been reported from the Richelsdorf Mountains, Hesse, Germany; the Bou Azzer district, Morocco and the Mohawk mine, Keweenaw County, Michigan.

References

Calcium minerals Arsenate minerals Monoclinic minerals Minerals in space group 14 {{mineral-stub