Ultramafic rocks
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Ultramafic rocks (also referred to as ultrabasic rocks, although the terms are not wholly equivalent) are
igneous Igneous rock (derived from the Latin word ''ignis'' meaning fire), or magmatic rock, is one of the three main rock types, the others being sedimentary and metamorphic. Igneous rock is formed through the cooling and solidification of magma or ...
and meta-igneous rocks with a very low
silica Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is ...
content (less than 45%), generally >18% MgO, high FeO, low
potassium Potassium is the chemical element with the symbol K (from Neo-Latin ''kalium'') and atomic number19. Potassium is a silvery-white metal that is soft enough to be cut with a knife with little force. Potassium metal reacts rapidly with atmosph ...
, and are composed of usually greater than 90%
mafic A mafic mineral or rock is a silicate mineral or igneous rock rich in magnesium and iron. Most mafic minerals are dark in color, and common rock-forming mafic minerals include olivine, pyroxene, amphibole, and biotite. Common mafic rocks incl ...
mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2 ...
s (dark colored, high
magnesium Magnesium is a chemical element with the symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 of the periodic ta ...
and
iron Iron () is a chemical element with Symbol (chemistry), symbol Fe (from la, Wikt:ferrum, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 element, group 8 of the periodic table. It is, Abundanc ...
content). The
Earth's mantle Earth's mantle is a layer of silicate rock between the crust and the outer core. It has a mass of 4.01 × 1024 kg and thus makes up 67% of the mass of Earth. It has a thickness of making up about 84% of Earth's volume. It is predominantly so ...
is composed of ultramafic rocks. Ultrabasic is a more inclusive term that includes igneous rocks with low silica content that may not be extremely enriched in Fe and Mg, such as
carbonatites Carbonatite () is a type of intrusive or extrusive igneous rock defined by mineralogic composition consisting of greater than 50% carbonate minerals. Carbonatites may be confused with marble and may require geochemical verification. Carbonatit ...
and
ultrapotassic igneous rocks Ultrapotassic igneous rocks are a class of rare, volumetrically minor and generally ultramafic or mafic silica-depleted igneous rocks. Ultrapotassic rocks are defined by molar K2 O/ Na2O >3 in much of the scientific literature. In other papers wr ...
.


Intrusive ultramafic rocks

Intrusive ultramafic rocks are often found in large, layered ultramafic intrusions where differentiated rock types often occur in layers. Such cumulate rock types do not represent the chemistry of the magma from which they crystallized. The ultramafic intrusives include the
dunite Dunite (), also known as olivinite (not to be confused with the mineral olivenite), is an intrusive igneous rock of ultramafic composition and with phaneritic (coarse-grained) texture. The mineral assemblage is greater than 90% olivine, with ...
s, peridotites and
pyroxenite Pyroxenite is an ultramafic igneous rock consisting essentially of minerals of the pyroxene group, such as augite, diopside, hypersthene, bronzite or enstatite. Pyroxenites are classified into clinopyroxenites, orthopyroxenites, and the we ...
s. Other rare varieties include troctolite which has a greater percentage of calcic plagioclase. These grade into the
anorthosite Anorthosite () is a phaneritic, intrusive igneous rock characterized by its composition: mostly plagioclase feldspar (90–100%), with a minimal mafic component (0–10%). Pyroxene, ilmenite, magnetite, and olivine are the mafic minerals most ...
s.
Gabbro Gabbro () is a phaneritic (coarse-grained), mafic intrusive igneous rock formed from the slow cooling of magnesium-rich and iron-rich magma into a holocrystalline mass deep beneath the Earth's surface. Slow-cooling, coarse-grained gabbro is ch ...
and
norite Norite is a mafic intrusive igneous rock composed largely of the calcium-rich plagioclase labradorite, orthopyroxene, and olivine. The name ''norite'' is derived from ''Norge'', the Norwegian name for Norway. Norite also known as orthopyrox ...
often occur in the upper portions of the layered ultramafic sequences.
Hornblendite Hornblendite is a plutonic rock consisting mainly of the amphibole hornblende. Hornblende-rich ultramafic rocks are rare and when hornblende is the dominant mineral phase they are classified as hornblendites with qualifiers such as garnet hor ...
and, rarely
phlogopite Phlogopite is a yellow, greenish, or reddish-brown member of the mica family of phyllosilicates. It is also known as magnesium mica. Phlogopite is the magnesium endmember of the biotite solid solution series, with the chemical formula KMg3AlSi3O ...
, are also found.


Volcanic ultramafic rocks on Earth

Volcanic A volcano is a rupture in the crust of a planetary-mass object, such as Earth, that allows hot lava, volcanic ash, and gases to escape from a magma chamber below the surface. On Earth, volcanoes are most often found where tectonic plates a ...
ultramafic rocks are rare outside of the Archaean and are essentially restricted to the
Neoproterozoic The Neoproterozoic Era is the unit of geologic time from 1 billion to 538.8 million years ago. It is the last era of the Precambrian Supereon and the Proterozoic Eon; it is subdivided into the Tonian, Cryogenian, and Ediacaran periods. It is prec ...
or earlier. Subvolcanic ultramafic rocks and dykes persist longer, but are also rare. There is evidence of ultramafic rocks elsewhere in the solar system. Examples include komatiite and picritic basalt. Komatiites can be host to
ore Ore is natural rock or sediment that contains one or more valuable minerals, typically containing metals, that can be mined, treated and sold at a profit.Encyclopædia Britannica. "Ore". Encyclopædia Britannica Online. Retrieved 7 Apr ...
deposits of
nickel Nickel is a chemical element with symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel is a hard and ductile transition metal. Pure nickel is chemically reactive but large pieces are slow ...
.


Ultramafic tuff

Ultramafic
tuff Tuff is a type of rock made of volcanic ash ejected from a vent during a volcanic eruption. Following ejection and deposition, the ash is lithified into a solid rock. Rock that contains greater than 75% ash is considered tuff, while rock ...
is extremely rare. It has a characteristic abundance of
olivine The mineral olivine () is a magnesium iron silicate with the chemical formula . It is a type of nesosilicate or orthosilicate. The primary component of the Earth's upper mantle, it is a common mineral in Earth's subsurface, but weathers quickl ...
or serpentine and a scarcity or absence of
feldspar Feldspars are a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the ''plagioclase'' (sodium-calcium) felds ...
and
quartz Quartz is a hard, crystalline mineral composed of silica ( silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical ...
. Rare occurrences may include unusual surface deposits of maars of
kimberlite Kimberlite is an igneous rock and a rare variant of peridotite. It is most commonly known to be the main host matrix for diamonds. It is named after the town of Kimberley in South Africa, where the discovery of an diamond called the Star of S ...
s in the
diamond Diamond is a solid form of the element carbon with its atoms arranged in a crystal structure called diamond cubic. Another solid form of carbon known as graphite is the chemically stable form of carbon at room temperature and pressure, ...
fields of southern Africa and other regions.


Ultrapotassic ultramafic rocks

Technically ultrapotassic rocks and melilitic rocks are considered a separate group, based on melting model criteria, but there are ultrapotassic and highly silica-under-saturated rocks with >18% MgO which can be considered "ultramafic". Ultrapotassic, ultramafic igneous rocks such as
lamprophyre Lamprophyres () are uncommon, small-volume ultrapotassic igneous rocks primarily occurring as dikes, lopoliths, laccoliths, stocks, and small intrusions. They are alkaline silica- undersaturated mafic or ultramafic rocks with high magnesium ...
,
lamproite Lamproite is an ultrapotassic mantle-derived volcanic or subvolcanic rock. It has low CaO, Al2O3, Na2O, high K2O/Al2O3, a relatively high MgO content and extreme enrichment in incompatible elements. Lamproites are geographically widespread ...
and
kimberlite Kimberlite is an igneous rock and a rare variant of peridotite. It is most commonly known to be the main host matrix for diamonds. It is named after the town of Kimberley in South Africa, where the discovery of an diamond called the Star of S ...
are known to have reached the surface of the Earth. Although no modern eruptions have been observed, analogues are preserved. Most of these rocks occur as
dikes Dyke (UK) or dike (US) may refer to: General uses * Dyke (slang), a slang word meaning "lesbian" * Dike (geology), a subvertical sheet-like intrusion of magma or sediment * Dike (mythology), ''Dikē'', the Greek goddess of moral justice * Dikes ...
,
diatreme A diatreme, sometimes known as a maar-diatreme volcano, is a volcanic pipe formed by a gaseous explosion. When magma rises up through a crack in Earth's crust and makes contact with a shallow body of groundwater, rapid expansion of heated wate ...
s,
lopolith A lopolith is a large igneous intrusion which is lenticular in shape with a depressed central region. Lopoliths are generally concordant with the intruded strata with dike or funnel-shaped feeder bodies below the body. The term was first defin ...
s or
laccolith A laccolith is a body of intrusive rock with a dome-shaped upper surface and a level base, fed by a conduit from below. A laccolith forms when magma (molten rock) rising through the Earth's crust begins to spread out horizontally, prying apar ...
s, and very rarely, intrusions. Most kimberlite and lamproite occurrences occur as
volcanic A volcano is a rupture in the crust of a planetary-mass object, such as Earth, that allows hot lava, volcanic ash, and gases to escape from a magma chamber below the surface. On Earth, volcanoes are most often found where tectonic plates a ...
and subvolcanic diatremes and maars; lavas are virtually unknown. Vents of Proterozoic lamproite (
Argyle diamond mine The Argyle Diamond Mine was a diamond mine located in the East Kimberley region in the remote north of Western Australia. Argyle was at times the largest diamond producer in the world by volume (14 million carats in 2018), although the propor ...
), and Cenozoic lamproite (
Gaussberg Gaussberg (or Schwarzen Berg, Mount Gauss) is an extinct, high volcanic cone in East Antarctica fronting on Davis Sea immediately west of Posadowsky Glacier. It is ice-free and conical in nature, having formed subglacially about 55,000  ...
,
Antarctica Antarctica () is Earth's southernmost and least-populated continent. Situated almost entirely south of the Antarctic Circle and surrounded by the Southern Ocean, it contains the geographic South Pole. Antarctica is the fifth-largest cont ...
) are known, as are vents of Devonian lamprophyre (
Scotland Scotland (, ) is a Countries of the United Kingdom, country that is part of the United Kingdom. Covering the northern third of the island of Great Britain, mainland Scotland has a Anglo-Scottish border, border with England to the southeast ...
). Kimberlite pipes in Canada, Russia and South Africa have incompletely preserved
tephra Tephra is fragmental material produced by a volcanic eruption regardless of composition, fragment size, or emplacement mechanism. Volcanologists also refer to airborne fragments as pyroclasts. Once clasts have fallen to the ground, they re ...
and agglomerate facies. These are generally
diatreme A diatreme, sometimes known as a maar-diatreme volcano, is a volcanic pipe formed by a gaseous explosion. When magma rises up through a crack in Earth's crust and makes contact with a shallow body of groundwater, rapid expansion of heated wate ...
events and as such are not lava flows although tephra and ash deposits are partially preserved. These represent low-
volume Volume is a measure of occupied three-dimensional space. It is often quantified numerically using SI derived units (such as the cubic metre and litre) or by various imperial or US customary units (such as the gallon, quart, cubic inch). Th ...
volatile melts and attain their ultramafic chemistry via a different process than typical ultramafic rocks.


Metamorphic ultramafic rocks

Metamorphism Metamorphism is the transformation of existing rock (the protolith) to rock with a different mineral composition or texture. Metamorphism takes place at temperatures in excess of , and often also at elevated pressure or in the presence of ch ...
of ultramafic rocks in the presence of
water Water (chemical formula ) is an Inorganic compound, inorganic, transparent, tasteless, odorless, and Color of water, nearly colorless chemical substance, which is the main constituent of Earth's hydrosphere and the fluids of all known living ...
and/or
carbon dioxide Carbon dioxide ( chemical formula ) is a chemical compound made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature. In the air, carbon dioxide is trans ...
results in two main classes of metamorphic ultramafic rock;
talc carbonate Talc carbonates are a suite of rock and mineral compositions found in metamorphosed ultramafic rocks. The term refers to the two most common end-member minerals found within ultramafic rocks which have undergone talc-carbonation or carbonation rea ...
and
serpentinite Serpentinite is a rock composed predominantly of one or more serpentine group minerals, the name originating from the similarity of the texture of the rock to that of the skin of a snake. Serpentinite has been called ''serpentine'' or ''se ...
. Talc carbonation reactions occur in ultramafic rocks at lower
greenschist Greenschists are metamorphic rocks that formed under the lowest temperatures and pressures usually produced by regional metamorphism, typically and 2–10 kilobars (). Greenschists commonly have an abundance of green minerals such as chlorite ...
through to
granulite Granulites are a class of high-grade metamorphic rocks of the granulite facies that have experienced high-temperature and moderate-pressure metamorphism. They are medium to coarse–grained and mainly composed of feldspars sometimes associated ...
facies metamorphism when the rock in question is subjected to metamorphism and the metamorphic fluid has more than 10% molar proportion of CO2 (
carbon dioxide Carbon dioxide ( chemical formula ) is a chemical compound made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature. In the air, carbon dioxide is trans ...
). When such metamorphic fluids have less than 10% molar proportion of CO2, reactions favor serpentinisation, resulting in chlorite- serpentine- amphibole type assemblages.


Distribution in space and time

The majority of ultramafic rocks are exposed in
orogenic Orogeny is a mountain building process. An orogeny is an event that takes place at a convergent plate margin when plate motion compresses the margin. An ''orogenic belt'' or ''orogen'' develops as the compressed plate crumples and is uplifted t ...
belts, and predominate in Archaean and Proterozoic terranes. Ultramafic magmas in the Phanerozoic are rarer, and there are very few recognised true ultramafic lavas in the Phanerozoic. Many surface exposures of ultramafic rocks occur in
ophiolite An ophiolite is a section of Earth's oceanic crust and the underlying upper mantle that has been uplifted and exposed above sea level and often emplaced onto continental crustal rocks. The Greek word ὄφις, ''ophis'' (''snake'') is found ...
complexes where deep mantle-derived rocks have been obducted onto
continental crust Continental crust is the layer of igneous, sedimentary, and metamorphic rocks that forms the geological continents and the areas of shallow seabed close to their shores, known as continental shelves. This layer is sometimes called '' sial'' be ...
along and above subduction zones.


Soil and regolith on ultramafic rock

Serpentine soil is a magnesium rich, calcium, potassium and phosphorus poor soil that develops on the
regolith Regolith () is a blanket of unconsolidated, loose, heterogeneous superficial deposits covering solid rock. It includes dust, broken rocks, and other related materials and is present on Earth, the Moon, Mars, some asteroids, and other terrestr ...
derived from ultramafic rocks. Ultramafic rocks also contain elevated amounts of chromium and nickel which may be toxic to plants. As a result, a distinctive type of
vegetation Vegetation is an assemblage of plant species and the ground cover they provide. It is a general term, without specific reference to particular taxa, life forms, structure, spatial extent, or any other specific botanical or geographic characte ...
develops on these soils. Examples are the ultramafic
woodland A woodland () is, in the broad sense, land covered with trees, or in a narrow sense, synonymous with wood (or in the U.S., the ''plurale tantum'' woods), a low-density forest forming open habitats with plenty of sunlight and limited shade (se ...
s and barrens of the Appalachian
mountain A mountain is an elevated portion of the Earth's crust, generally with steep sides that show significant exposed bedrock. Although definitions vary, a mountain may differ from a plateau in having a limited summit area, and is usually highe ...
s and
piedmont it, Piemontese , population_note = , population_blank1_title = , population_blank1 = , demographics_type1 = , demographics1_footnotes = , demographics1_title1 = , demographics1_info1 = , demographics1_title2 ...
, the "wet maquis" of the
New Caledonia rain forests The New Caledonia rain forests are a terrestrial ecoregion, located in New Caledonia in the South Pacific. It is a tropical moist broadleaf forest ecoregion, part of the Australasian realm. Setting The ecoregion covers the windward eastern s ...
, and the ultramafic
forest A forest is an area of land dominated by trees. Hundreds of definitions of forest are used throughout the world, incorporating factors such as tree density, tree height, land use, legal standing, and ecological function. The United Nations' ...
s of
Mount Kinabalu Mount Kinabalu ( ms, Gunung Kinabalu, Dusun: ''Gayo Ngaran or Nulu Nabalu'') is the highest mountain in Borneo and Malaysia. With an elevation of , it is third-highest peak of an island on Earth, and 20th most prominent mountain in the worl ...
and other peaks in
Sabah Sabah () is a state of Malaysia located in northern Borneo, in the region of East Malaysia. Sabah borders the Malaysian state of Sarawak to the southwest and the North Kalimantan province of Indonesia to the south. The Federal Territory o ...
,
Malaysia Malaysia ( ; ) is a country in Southeast Asia. The federation, federal constitutional monarchy consists of States and federal territories of Malaysia, thirteen states and three federal territories, separated by the South China Sea into two r ...
. Vegetation is typically stunted, and sometimes includes
endemic Endemism is the state of a species being found in a single defined geographic location, such as an island, state, nation, country or other defined zone; organisms that are indigenous to a place are not endemic to it if they are also found else ...
species adapted to the soils. Often thick, magnesite- calcrete
caprock Caprock or cap rock is a more resistant rock type overlying a less resistant rock type,Kearey, Philip (2001). ''Dictionary of Geology'', 2nd ed., Penguin Reference, London, New York, etc., p. 41.. . analogous to an upper crust on a cake that is ha ...
, laterite and duricrust forms over ultramafic rocks in
tropical The tropics are the regions of Earth surrounding the Equator. They are defined in latitude by the Tropic of Cancer in the Northern Hemisphere at N and the Tropic of Capricorn in the Southern Hemisphere at S. The tropics are also referred to ...
and subtropical environments. Particular floral assemblages associated with highly nickeliferous ultramafic rocks are indicative tools for
mineral exploration Mining in the engineering discipline is the extraction of minerals from underneath, open pit, above or on the ground. Mining engineering is associated with many other disciplines, such as mineral processing, exploration, excavation, geology, and ...
. Weathered ultramafic rocks may form lateritic nickel ore deposits.


Other celestial bodies


Io

Ultramafic lava may have been detected on Io, a moon of
Jupiter Jupiter is the fifth planet from the Sun and the largest in the Solar System. It is a gas giant with a mass more than two and a half times that of all the other planets in the Solar System combined, but slightly less than one-thousandth t ...
, because heat-mapping of Io's surface found ultra-hot areas with temperatures in excess of . The
magma Magma () is the molten or semi-molten natural material from which all igneous rocks are formed. Magma is found beneath the surface of the Earth, and evidence of magmatism has also been discovered on other terrestrial planets and some natural sa ...
immediately below these hot spots is probably about hotter, based on surface-to-subsurface temperature differences observed for lava on Earth. A temperature of is thought to indicate the presence of ultramafic magma.


Mercury

Mercury appears to have ultramafic volcanic rock.


See also

* Chromitite *
Magnetite Magnetite is a mineral and one of the main iron ores, with the chemical formula Fe2+Fe3+2O4. It is one of the oxides of iron, and is ferrimagnetic; it is attracted to a magnet and can be magnetized to become a permanent magnet itself. With th ...
*
Kambalda type komatiitic nickel ore deposits Kambalda type komatiitic nickel ore deposits are a class of magmatic iron-nickel-copper-platinum-group element ore deposit in which the physical processes of komatiite volcanology serve to deposit, concentrate and enrich a Fe-Ni-Cu-(PGE) sulfide ...
* Fractional crystallization (geology) * Volcanism on Io, a moon of Jupiter


References

{{Authority control Metamorphic rocks