Thallium(I) bromide
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Thallium(I) bromide is a
chemical compound A chemical compound is a chemical substance composed of many identical molecules (or molecular entities) containing atoms from more than one chemical element held together by chemical bonds. A molecule consisting of atoms of only one element ...
of
thallium Thallium is a chemical element with the symbol Tl and atomic number 81. It is a gray post-transition metal that is not found free in nature. When isolated, thallium resembles tin, but discolors when exposed to air. Chemists William Crookes an ...
and
bromine Bromine is a chemical element with the symbol Br and atomic number 35. It is the third-lightest element in group 17 of the periodic table ( halogens) and is a volatile red-brown liquid at room temperature that evaporates readily to form a simi ...
with a
chemical formula In chemistry, a chemical formula is a way of presenting information about the chemical proportions of atoms that constitute a particular chemical compound or molecule, using chemical element symbols, numbers, and sometimes also other symbol ...
TlBr. This salt is used in room-temperature detectors of X-rays, gamma-rays and blue light, as well as in near-infrared optics. It is a
semiconductor A semiconductor is a material which has an electrical conductivity value falling between that of a conductor, such as copper, and an insulator, such as glass. Its resistivity falls as its temperature rises; metals behave in the opposite way. ...
with a
band gap In solid-state physics, a band gap, also called an energy gap, is an energy range in a solid where no electronic states can exist. In graphs of the electronic band structure of solids, the band gap generally refers to the energy difference ( ...
of 2.68 eV. The crystalline structure is of cubic
CsCl CSCL can refer to: * Caesium chloride (CsCl), a chemical compound. * Computer Supported Collaborative Learning, a research topic on supporting collaborative learning with the assistance of computer artifacts. * China Shipping Container Lines, a c ...
type at room temperature, but it lowers to the orthorombic thallium iodide type upon cooling, the transition temperature being likely affected by the impurities. Nanometer-thin TlBr films grown on LiF, NaCl or KBr substrates exhibit a rocksalt structure. Thallium is extremely toxic and a cumulative poison which can be absorbed through the skin. Acute and chronic effects of ingesting thallium compounds include fatigue, limb pain, peripheral neuritis, joint pain, loss of hair, diarrhea, vomiting, vision loss, and damage to central nervous system, liver and kidneys.Thallium Bromide Material safety data sheet
espimetals.com


References


Cited sources

* Bromides Thallium(I) compounds Metal halides Caesium chloride crystal structure {{inorganic-compound-stub