Storax balsam
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Storax ( la, storax; el, στύραξ, ''stúrax''), often commercially sold as styrax, is a natural
resin In polymer chemistry and materials science, resin is a solid or highly viscous substance of plant or synthetic origin that is typically convertible into polymers. Resins are usually mixtures of organic compounds. This article focuses on nat ...
isolated from the wounded bark of ''
Liquidambar orientalis ''Liquidambar Orientalis'', commonly known as oriental sweetgum or Turkish sweetgum, is a deciduous tree in the genus ''Liquidambar'', native to the eastern Mediterranean region, that occurs as pure stands mainly in the floodplains of southwe ...
'' Mill. (Asia Minor) and ''
Liquidambar styraciflua American sweetgum (''Liquidambar styraciflua''), also known as American storax, hazel pine, bilsted, redgum, satin-walnut, star-leaved gum, alligatorwood, or simply sweetgum, is a deciduous tree in the genus ''Liquidambar'' native to warm temper ...
'' L. (Central America) (
Hamamelidaceae Hamamelidaceae, commonly referred to as the witch-hazel family, is a family of flowering plants in the order Saxifragales. The clade consists of shrubs and small trees positioned within the woody clade of the core Saxifragales. An earlier sy ...
). It is distinct from benzoin (also called "storax"), a similar resin obtained from the Styracaceae plant family.


Composition

Purified storax contains circa 33 to 50% storesin, an alcoholic resin, both free and as cinnamic esters. Contains 5 to 15%
cinnamic acid Cinnamic acid is an organic compound with the formula C6H5-CH=CH- COOH. It is a white crystalline compound that is slightly soluble in water, and freely soluble in many organic solvents. Classified as an unsaturated carboxylic acid, it occurs na ...
, 5 to 15% cinnamyl cinnamate, circa 10% phenylpropyl cinnamate; small amounts of
ethyl cinnamate Ethyl cinnamate is the ester of cinnamic acid and ethanol. It is present in the essential oil of cinnamon. Pure ethyl cinnamate has a "fruity and balsamic odor, reminiscent of cinnamon with an amber note". The ''p''-methoxy derivative is report ...
,
benzyl cinnamate Benzyl cinnamate is the chemical compound which is the ester derived from cinnamic acid and benzyl alcohol. Natural occurrence Benzyl cinnamate occurs in Balsam of Peru and Tolu balsam, in Sumatra and Penang benzoin, and as the main constituen ...
, and
styrene Styrene () is an organic compound with the chemical formula C6H5CH=CH2. This derivative of benzene is a colorless oily liquid, although aged samples can appear yellowish. The compound evaporates easily and has a sweet smell, although high concen ...
, Some may contain traces of
vanillin Vanillin is an organic compound with the molecular formula . It is a phenolic aldehyde. Its functional groups include aldehyde, hydroxyl, and ether. It is the primary component of the extract of the vanilla bean. Synthetic vanillin is now u ...
. Some sources report a resin containing triterpenic acids ( oleanolic and 3-epioleanolic acids).


Uses

Storax has a pleasant, floral/lilac, leathery, balsamic smell. Storax and its derivatives (
resinoid Resinoids are extracts of resinous plant exudates (balsams, oleo gum resins, and natural oleoresins). Production Resinous plant exudates (balsams, oleo gum resins, and natural oleoresins) and animal secretions (ambergris, castoreum, musk, and ...
,
essential oil An essential oil is a concentrated hydrophobic liquid containing volatile (easily evaporated at normal temperatures) chemical compounds from plants. Essential oils are also known as volatile oils, ethereal oils, aetheroleum, or simply as the o ...
,
absolute Absolute may refer to: Companies * Absolute Entertainment, a video game publisher * Absolute Radio, (formerly Virgin Radio), independent national radio station in the UK * Absolute Software Corporation, specializes in security and data risk manag ...
) are used as flavors, fragrances, and in pharmaceuticals (
Friar's Balsam Tincture of benzoin is a pungent solution of benzoin resin in ethanol. A similar preparation called Friar's Balsam or Compound Benzoin Tincture contains, in addition, Cape aloes or Barbados aloes and storax resin. Friar's balsam was invented by Jo ...
). American storax resin (''Liquidambar styraciflua'') is chewed like gum to freshen breath and clean teeth.


History

Mnesimachus,
Aristotle Aristotle (; grc-gre, Ἀριστοτέλης ''Aristotélēs'', ; 384–322 BC) was a Greek philosopher and polymath during the Classical period in Ancient Greece. Taught by Plato, he was the founder of the Peripatetic school of ...
,
Theophrastus Theophrastus (; grc-gre, Θεόφραστος ; c. 371c. 287 BC), a Greek philosopher and the successor to Aristotle in the Peripatetic school. He was a native of Eresos in Lesbos.Gavin Hardy and Laurence Totelin, ''Ancient Botany'', Routle ...
('' Historia Plantarum''),
Herodotus Herodotus ( ; grc, , }; BC) was an ancient Greek historian and geographer from the Greek city of Halicarnassus, part of the Persian Empire (now Bodrum, Turkey) and a later citizen of Thurii in modern Calabria (Italy). He is known fo ...
, and
Strabo Strabo''Strabo'' (meaning "squinty", as in strabismus) was a term employed by the Romans for anyone whose eyes were distorted or deformed. The father of Pompey was called " Pompeius Strabo". A native of Sicily so clear-sighted that he could s ...
are the first ones to mention the storax tree and its balsam. In
ancient Greece Ancient Greece ( el, Ἑλλάς, Hellás) was a northeastern Mediterranean civilization, existing from the Greek Dark Ages of the 12th–9th centuries BC to the end of classical antiquity ( AD 600), that comprised a loose collection of cu ...
, storax also denoted the spike at the lower end of a spearshaft. Pliny ('' Historia Naturalis'' 12.98, 15.26; 24.24) notes the use of storax as a perfume, while Scribonius Largus drank wine flavored with storax.
Ciris The ''Appendix Vergiliana'' is a collection of poems traditionally ascribed as being the juvenilia (work written as a juvenile) of Virgil.Régine ChambertVergil's Epicureanism in his early poems in "Vergil, Philodemus, and the Augustans" 2003: ...
mentions storax as a fragrant hair dye.
Dioscorides Pedanius Dioscorides ( grc-gre, Πεδάνιος Διοσκουρίδης, ; 40–90 AD), “the father of pharmacognosy”, was a Greek physician, pharmacologist, botanist, and author of '' De materia medica'' (, On Medical Material) —a 5-vo ...
(''
De materia medica (Latin name for the Greek work , , both meaning "On Medical Material") is a pharmacopoeia of medicinal plants and the medicines that can be obtained from them. The five-volume work was written between 50 and 70 CE by Pedanius Dioscorides, ...
'' 1.79) reports its use as incense, similar to
frankincense Frankincense (also known as olibanum) is an aromatic resin used in incense and perfumes, obtained from trees of the genus '' Boswellia'' in the family Burseraceae. The word is from Old French ('high-quality incense'). There are several species ...
, having expectorant and soothing properties. The 10th century Arab historian
al-Masudi Al-Mas'udi ( ar, أَبُو ٱلْحَسَن عَلِيّ ٱبْن ٱلْحُسَيْن ٱبْن عَلِيّ ٱلْمَسْعُودِيّ, '; –956) was an Arab historian, geographer and traveler. He is sometimes referred to as the " Herodotu ...
listed storax gum (''mayʿa'') as a spice in his book ''Murūdj al-dhahab'' (''Meadows of Gold''). Chao Ju-Kuan, a 13th century trade commissioner in Fukien province, described liquid storax gum as a product of ''Ta-shï'' (the Arabian Empire).
Linnaeus Carl Linnaeus (; 23 May 1707 – 10 January 1778), also known after his ennoblement in 1761 as Carl von Linné Blunt (2004), p. 171. (), was a Swedish botanist, zoologist, taxonomist, and physician who formalised binomial nomenclature, the ...
, who determined the scientific names of plants, thought that storax was extracted from the tree called in modern Hebrew ''livneh refu'i'' which he termed ''
Styrax officinalis ''Styrax officinalis'' is a species of shrub in the family Styracaceae. Description ''Styrax officinalis'' is a deciduous shrub reaching a height of . It has a simple, relaxed form, with very thin elliptical leaves long and wide, alternate and ...
''. However in the light of tests made in Israel it is very doubtful if a sap with medicinal or aromatic qualities can be extracted from this tree. The storax of the ancients was probably extracted from a different tree, seemingly from the ''
Liquidambar orientalis ''Liquidambar Orientalis'', commonly known as oriental sweetgum or Turkish sweetgum, is a deciduous tree in the genus ''Liquidambar'', native to the eastern Mediterranean region, that occurs as pure stands mainly in the floodplains of southwe ...
'' which grows wild in northern Syria, and may even have been grown in Israel; from it is extracted an aromatic sap with healing qualities called ''storax liquidis''. This may possibly be the biblical balm, though other sources conclude that the biblical balm is
Balsam Balsam is the resinous exudate (or sap) which forms on certain kinds of trees and shrubs. Balsam (from Latin balsamum "gum of the balsam tree", ultimately from Semitic, Aramaic ''busma'', Arabic ''balsam'' and Hebrew ''basam'', "spice", "perfume ...
( opobalsamum). ''
Styrax benzoin ''Styrax benzoin'' is a species of tree native to Sumatra in Indonesia. Common names for the tree include gum benjamin tree, loban (in Arabic), kemenyan (in Indonesia and Malaysia), onycha, and Sumatra benzoin tree. Distribution It is a common ...
'' is a more humid Asian species, reported from India, Cambodia, Laos, Myanmar, Thailand, Vietnam, Java, Sumatra, and Malaysia. Thus, this species historically would have needed to be imported from outside Israel. In the nineteenth century, styrene was isolated by distillation of storax balsam. In North Africa, for mystical purposes, women burn benzoin and storax in potsherds.


Safety

Storax resin is "generally regarded as safe" ( GRAS), but at low levels, for example, circa 15 ppm in candy and 25 ppm in baked goods.


References

{{Reflist Resins Essential oils Liquidambar Incense material Perfume ingredients