Roy Plunkett
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Roy J. Plunkett (June 26, 1910 – May 12, 1994) was an American
chemist A chemist (from Greek ''chēm(ía)'' alchemy; replacing ''chymist'' from Medieval Latin ''alchemist'') is a scientist trained in the study of chemistry. Chemists study the composition of matter and its properties. Chemists carefully describe t ...
. He discovered polytetrafluoroethylene (PTFE), better known as Teflon, in 1938.


Personal life and education

Plunkett was born in
New Carlisle, Ohio New Carlisle is a city in Clark County, Ohio, Clark County, Ohio, United States. The population was 5,785 at the United States Census 2010, 2010 census. It is part of the Springfield, Ohio Springfield, Ohio metropolitan area, Metropolitan Statistic ...
and attended Newton High School in
Pleasant Hill, Ohio Pleasant Hill is a village in Miami County, Ohio, United States. The population was 1,200 at the 2010 census. It is part of the Dayton Metropolitan Statistical Area. History Pleasant Hill was originally called Newton, and under the latter name ...
. He graduated from
Manchester University , mottoeng = Knowledge, Wisdom, Humanity , established = 2004 – University of Manchester Predecessor institutions: 1956 – UMIST (as university college; university 1994) 1904 – Victoria University of Manchester 1880 – Victoria Univer ...
with a B.A. in chemistry in 1932. He received his Ph.D. in chemistry in 1936 from
Ohio State University The Ohio State University, commonly called Ohio State or OSU, is a public land-grant research university in Columbus, Ohio. A member of the University System of Ohio, it has been ranked by major institutional rankings among the best publ ...
for his work on ''The Mechanism of Carbohydrate Oxidation.'' He married Dorothy Enola Detrick, b. 1907, d 1984 on 16 Aug. 1935 in
Franklin, Ohio Franklin is a city in Warren County, Ohio, United States. The population was 11,771 at the 2010 census. The Great Miami River flows through Franklin. Ohio State Routes 73, 123 and 741 pass through Franklin, while Interstate 75 passes on the ...
. Next, he married Lois Mary Koch, b. 1925, d. 1996 on 24 May 1965 in Arlington, Virginia. Plunkett died of cancer on May 12, 1994, at his Texas home at the age of 83.


Career

In 1936 he was hired as a research chemist by E.I. du Pont de Nemours and Company at their Jackson Laboratory in
Deepwater, New Jersey Deepwater is an unincorporated community located within Pennsville Township, in Salem County, New Jersey, United States.L ...
. While attempting to make a new
chlorofluorocarbon Chlorofluorocarbons (CFCs) and hydrochlorofluorocarbons (HCFCs) are fully or partly halogenated hydrocarbons that contain carbon (C), hydrogen (H), chlorine (Cl), and fluorine (F), produced as volatile derivatives of methane, ethane, and pro ...
refrigerant in 1938, Plunkett discovered polytetrafluoroethylene (PTFE), better known as Teflon. Plunkett shared the story of his accidental discovery at the spring meeting of the American Chemical Society national meeting in the History of Chemistry section, April 1986 in New York City which was published in the Symposium Proceedings:Plunkett, RJ ''The History of Polytetrafluoroethylene: Discovery and Development'', pages 261-266 in "High Performance Polymers: Their Origin and Development. Proceedings of the Symposium on the History of High Performance Polymers at the American Chemical Society Meeting held in New York, April 15–18, 1986." Seymour RB and Kirshenbaum GS, Editors, Elsevier, New York, 1986.
On the morning of April 6, 1938, Jack Rebok, my assistant, selected one of the TFE cylinders that we had been using the previous day and set up the apparatus ready to go. When he opened the valve — to let the TFE gas flow under its own pressure from the cylinder — nothing happened...We were in a quandary. I couldn't think of anything else to do under the circumstances, so we unscrewed the valve from the cylinder. By this time it was pretty clear that there wasn't any gas left. I carefully tipped the cylinder upside down, and out came a whitish powder down onto the lab bench. We scraped around some with the wire inside the cylinder...to get some more of the powder. What I got out that way certainly didn't add up, so I knew there must be more, inside. Finally...we decided to cut open the cylinder. When we did, we found more of the powder packed onto the bottom and lower sides of the cylinder.
The
tetrafluoroethylene Tetrafluoroethylene (TFE) is a fluorocarbon with the chemical formula C2 F4. It is the simplest perfluorinated alkene. This gaseous species is used primarily in the industrial preparation of fluoropolymers. Properties Tetrafluoroethylene is a ...
in the container had
polymerized In polymer chemistry, polymerization (American English), or polymerisation (British English), is a process of reacting monomer molecules together in a chemical reaction to form polymer chains or three-dimensional networks. There are many for ...
into polytetrafluoroethylene, a waxy solid with that was found to have had properties such as resistance to
corrosion Corrosion is a natural process that converts a refined metal into a more chemically stable oxide. It is the gradual deterioration of materials (usually a metal) by chemical or electrochemical reaction with their environment. Corrosion engi ...
, low surface
friction Friction is the force resisting the relative motion of solid surfaces, fluid layers, and material elements sliding against each other. There are several types of friction: *Dry friction is a force that opposes the relative lateral motion of ...
, and high
heat In thermodynamics, heat is defined as the form of energy crossing the boundary of a thermodynamic system by virtue of a temperature difference across the boundary. A thermodynamic system does not ''contain'' heat. Nevertheless, the term is ...
resistance. Later in his career, Plunkett was the chief chemist involved in the production of
tetraethyllead Tetraethyllead (commonly styled tetraethyl lead), abbreviated TEL, is an organolead compound with the formula Pb( C2H5)4. It is a fuel additive, first being mixed with gasoline beginning in the 1920s as a patented octane rating booster that ...
, an antiknock agent that made gasoline "leaded," later discontinued over concerns about the toxic effects of
lead Lead is a chemical element with the symbol Pb (from the Latin ) and atomic number 82. It is a heavy metal that is denser than most common materials. Lead is soft and malleable, and also has a relatively low melting point. When freshly cu ...
. After that, he directed the production of
Freon Freon ( ) is a registered trademark of the Chemours Company and generic descriptor for a number of halocarbon products. They are stable, nonflammable, low toxicity gases or liquids which have generally been used as refrigerants and as aerosol prope ...
, DuPont's brand name for chlorofluorocarbon refrigerant, before retiring in 1975.


Awards

Plunkett received the
John Scott Medal John Scott Award, created in 1816 as the John Scott Legacy Medal and Premium, is presented to men and women whose inventions improved the "comfort, welfare, and happiness of human kind" in a significant way. "...the John Scott Medal Fund, establish ...
from the city of
Philadelphia Philadelphia, often called Philly, is the List of municipalities in Pennsylvania#Municipalities, largest city in the Commonwealth (U.S. state), Commonwealth of Pennsylvania, the List of United States cities by population, sixth-largest city i ...
in 1951, for an invention promoting the "comfort, welfare, and happiness of humankind". Attendees were given a Teflon-coated muffin tin to take home. Other awards and honors followed. Plunkett was inducted into the Plastics Hall of Fame in 1973 and the
National Inventors Hall of Fame The National Inventors Hall of Fame (NIHF) is an American not-for-profit organization, founded in 1973, which recognizes individual engineers and inventors who hold a U.S. patent of significant technology. Besides the Hall of Fame, it also oper ...
in 1985.


References


Further reading

* George B. Kauffman. "Plunkett, Roy Joseph" in ''American National Biography'' (1999) ww.anb.org/viewbydoi/10.1093/anb/9780198606697.article.1302553 online* Raymond B. Seymour and Charles H. Fisher. "Roy J. Plunkett," in ''Profiles of Eminent American Chemists,'' ed. Sylvia Tascher (1988), pp. 381–84. * Findagrave lin


External links

* * {{DEFAULTSORT:Plunkett, Roy J. 1910 births 1994 deaths Manchester University (Indiana) alumni DuPont people Ohio State University Graduate School alumni Polymer scientists and engineers People from New Carlisle, Ohio 20th-century American inventors