Reinforced carbon–carbon
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Carbon fibre reinforced carbon (CFRC), carbon–carbon (C/C), or reinforced carbon–carbon (RCC) is a
composite material A composite material (also called a composition material or shortened to composite, which is the common name) is a material which is produced from two or more constituent materials. These constituent materials have notably dissimilar chemical or ...
consisting of
carbon fiber Carbon fiber-reinforced polymers (American English), carbon-fibre-reinforced polymers (Commonwealth English), carbon-fiber-reinforced plastics, carbon-fiber reinforced-thermoplastic (CFRP, CRP, CFRTP), also known as carbon fiber, carbon compo ...
reinforcement in a matrix of
graphite Graphite () is a crystalline form of the element carbon. It consists of stacked layers of graphene. Graphite occurs naturally and is the most stable form of carbon under standard conditions. Synthetic and natural graphite are consumed on la ...
. It was developed for the reentry vehicles of
intercontinental ballistic missiles An intercontinental ballistic missile (ICBM) is a ballistic missile with a range greater than , primarily designed for nuclear weapons delivery (delivering one or more thermonuclear warheads). Conventional, chemical, and biological weapons c ...
, and is most widely known as the material for the nose cone and wing leading edges of the
Space Shuttle orbiter The Space Shuttle orbiter is the spaceplane component of the Space Shuttle, a partially reusable orbital spacecraft system that was part of the discontinued Space Shuttle program. Operated from 1977 to 2011 by NASA, the U.S. space agency, thi ...
. Carbon-carbon
brake disc A disc brake is a type of brake that uses the calipers to squeeze pairs of pads against a disc or a "rotor" to create friction. This action slows the rotation of a shaft, such as a vehicle axle, either to reduce its rotational speed or to hold ...
s and
brake pad Brake pads are a component of disc brakes used in automotive and other applications. Brake pads are composed of steel backing plates with friction material bound to the surface that faces the disc brake rotors. Function Brake pads convert the kin ...
s have been the standard component of the brake systems of
Formula One Formula One (also known as Formula 1 or F1) is the highest class of international racing for open-wheel single-seater formula racing cars sanctioned by the Fédération Internationale de l'Automobile (FIA). The World Drivers' Championship, ...
racing cars since the late 1970’s; the first year carbon brakes were seen on a Formula One car was 1976. Carbon–carbon is well-suited to structural applications at high temperatures, or where
thermal shock Thermal shock is a type of rapidly transient mechanical load. By definition, it is a mechanical load caused by a rapid change of temperature of a certain point. It can be also extended to the case of a thermal gradient, which makes different pa ...
resistance and/or a low coefficient of thermal expansion is needed. While it is less brittle than many other ceramics, it lacks impact resistance; Space Shuttle ''Columbia'' was destroyed during atmospheric re-entry after one of its RCC panels was broken by the impact of a piece of
polyurethane foam Polyurethane products have many uses. Over three quarters of the global consumption of polyurethane products is in the form of foams, with flexible and rigid types being roughly equal in market size. In both cases, the foam is usually behind othe ...
insulation that broke off from the
Space Shuttle External Tank The Space Shuttle external tank (ET) was the component of the Space Shuttle launch vehicle that contained the liquid hydrogen fuel and liquid oxygen oxidizer. During lift-off and ascent it supplied the fuel and oxidizer under pressure to the ...
.


Production

The material is made in three stages: First, material is laid up in its intended final shape, with carbon filament and/or cloth surrounded by an
organic Organic may refer to: * Organic, of or relating to an organism, a living entity * Organic, of or relating to an anatomical organ Chemistry * Organic matter, matter that has come from a once-living organism, is capable of decay or is the product ...
binder such as plastic or pitch. Often, coke or some other fine carbon
aggregate Aggregate or aggregates may refer to: Computing and mathematics * collection of objects that are bound together by a root entity, otherwise known as an aggregate root. The aggregate root guarantees the consistency of changes being made within the ...
is added to the binder mixture. Second, the lay-up is heated, so that
pyrolysis The pyrolysis (or devolatilization) process is the thermal decomposition of materials at elevated temperatures, often in an inert atmosphere. It involves a change of chemical composition. The word is coined from the Greek-derived elements '' ...
transforms the binder to relatively pure carbon. The binder loses volume in the process, causing voids to form; the addition of aggregate reduces this problem, but does not eliminate it. Third, the voids are gradually filled by forcing a carbon-forming gas such as
acetylene Acetylene ( systematic name: ethyne) is the chemical compound with the formula and structure . It is a hydrocarbon and the simplest alkyne. This colorless gas is widely used as a fuel and a chemical building block. It is unstable in its pure ...
through the material at a high temperature, over the course of several days. This long
heat treatment Heat treating (or heat treatment) is a group of industrial process, industrial, thermal and metalworking, metalworking processes used to alter the physical property, physical, and sometimes chemical property, chemical, properties of a material. ...
process also allows the carbon to form into larger
graphite Graphite () is a crystalline form of the element carbon. It consists of stacked layers of graphene. Graphite occurs naturally and is the most stable form of carbon under standard conditions. Synthetic and natural graphite are consumed on la ...
crystals, and is the major reason for the material's high cost. The gray "Reinforced Carbon–Carbon (RCC)" panels on the space shuttle's wing leading edges and nose cone cost NASA $100,000/sq ft to produce, although much of this cost was a result of the advanced geometry and research costs associated with the panels. This stage can also include manufacturing of the finished product. C/C is a hard material that can be made highly resistant to thermal expansion, temperature gradients, and thermal cycling, depending on how the fibre scaffold is laid up and the quality/density of the matrix filler. Carbon–carbon materials retain their properties above 2000 °C. This temperature may be exceeded with the help of protective coatings to prevent oxidation. The material has a density between 1.6–1.98 g/cm3.


Similar products

Carbon fibre-reinforced silicon carbide (C/SiC) is a development of pure carbon–carbon that uses
silicon carbide Silicon carbide (SiC), also known as carborundum (), is a hard chemical compound containing silicon and carbon. A semiconductor, it occurs in nature as the extremely rare mineral moissanite, but has been mass-produced as a powder and crystal s ...
with
carbon fibre Carbon fiber-reinforced polymers (American English), carbon-fibre-reinforced polymers (Commonwealth English), carbon-fiber-reinforced plastics, carbon-fiber reinforced-thermoplastic (CFRP, CRP, CFRTP), also known as carbon fiber, carbon compo ...
. It is slightly denser than pure carbon-carbon and thought to be more durable. It can be used in the brake disc and brake pads of high-performance road cars. The first car to use it was the
Mercedes-Benz C215 The second generation of the Mercedes-Benz CL-Class is the C215-chassis coupé of 1998–2006. It is based on the 1998–2005 Mercedes-Benz S-Class (W220), though it rides on an shorter wheelbase. Sales in Germany started in August 1999 for t ...
Coupe F1 edition. It is standard on the
Bugatti Veyron The Bugatti Veyron EB 16.4 is a mid-engine sports car, designed and developed in Germany by the Volkswagen Group and Bugatti and manufactured in Molsheim, France, by French automobile manufacturer Bugatti. It was named after the racing driver P ...
and certain current
Bentley Bentley Motors Limited is a British designer, manufacturer and marketer of luxury cars and SUVs. Headquartered in Crewe, England, the company was founded as Bentley Motors Limited by W. O. Bentley (1888–1971) in 1919 in Cricklewood, Nort ...
s,
Ferrari Ferrari S.p.A. (; ) is an Italian luxury sports car manufacturer based in Maranello, Italy. Founded by Enzo Ferrari (1898–1988) in 1939 from the Alfa Romeo racing division as ''Auto Avio Costruzioni'', the company built its first car in ...
s,
Porsche Dr. Ing. h.c. F. Porsche AG, usually shortened to Porsche (; see below), is a German automobile manufacturer specializing in high-performance sports cars, SUVs and sedans, headquartered in Stuttgart, Baden-Württemberg, Germany. The company ...
s, Corvette ZR1 , Z06 and
Lamborghini Automobili Lamborghini S.p.A. () is an Italian brand and manufacturer of luxury sports cars and SUVs based in Sant'Agata Bolognese. The company is owned by the Volkswagen Group through its subsidiary Audi. Ferruccio Lamborghini (1916–19 ...
s. They are also offered as an "optional upgrade" on certain high performance
Audi Audi AG () is a German automotive manufacturer of luxury vehicles headquartered in Ingolstadt, Bavaria, Germany. As a subsidiary of its parent company, the Volkswagen Group, Audi produces vehicles in nine production facilities worldwide. ...
cars, including the D3 S8, B7 RS4, C6 S6 and RS6, and the R8. The material is not used in Formula 1 because of its weight. Carbon brakes became widely available for commercial airplanes in the 1980s,Boeing: Operational Advantages of Carbon Brakes
/ref> having been first used on the
Concorde The Aérospatiale/BAC Concorde () is a retired Franco-British supersonic airliner jointly developed and manufactured by Sud Aviation (later Aérospatiale) and the British Aircraft Corporation (BAC). Studies started in 1954, and France an ...
supersonic transport A supersonic transport (SST) or a supersonic airliner is a civilian supersonic aircraft designed to transport passengers at speeds greater than the speed of sound. To date, the only SSTs to see regular service have been Concorde and the Tupol ...
. A related non-ceramic carbon composite with uses in high-tech racing automotives is the carbotanium carbon–titanium composite used in the Zonda R and Huayra supercars made by the Italian motorcar company Pagani.


Footnotes


References


External links


''Carbon brakes for Concorde''
{{DEFAULTSORT:Reinforced Carbon-Carbon Composite materials Refractory materials Fibre-reinforced polymers