Realgar wine
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Realgar wine or Xionghuang wine (Chinese: , ''Xiónghuáng Jiǔ'') is a
Chinese alcoholic drink There is a long history of alcoholic drinks in China. They include rice and grape wine, beer, whisky and various liquors including ''baijiu'', the most-consumed distilled spirit in the world. Name (''jiǔ'') is the Chinese character referring ...
that consists of
huangjiu ''Huangjiu'' (), meaning yellow wine, is a Chinese alcoholic beverage, and is most popular in the Jiangnan area. ''Huangjiu'' is brewed by mixing boiled grains including rice, glutinous rice or millet with qū as starter culture, followed by ...
("yellow wine") dosed with powdered
realgar Realgar ( ), also known as "ruby sulphur" or "ruby of arsenic", is an arsenic sulfide mineral with the chemical formula α-. It is a soft, sectile mineral occurring in monoclinic crystals, or in granular, compact, or powdery form, often in asso ...
, a yellow-orange
arsenic Arsenic is a chemical element with the symbol As and atomic number 33. Arsenic occurs in many minerals, usually in combination with sulfur and metals, but also as a pure elemental crystal. Arsenic is a metalloid. It has various allotropes, but ...
sulfide mineral (As4S4). It is traditionally consumed as part of the
Dragon Boat Festival The Dragon Boat Festival ( zh, s=端午节, t=端午節) is a traditional Chinese holiday which occurs on the fifth day of the fifth month of the Chinese calendar, which corresponds to late May or June in the Gregorian calendar. Names The Engl ...
at the height of summer.


Tradition

Realgar solution has been sprinkled around the house as an repellent against snakes and insects since ancient times. In this sense, realgar was considered to be a
universal antidote A panacea , named after the Greek goddess of universal remedy Panacea, is any supposed remedy that is claimed (for example) to cure all diseases and Immortality, prolong life indefinitely. It was in the past sought by alchemy, alchemists in connec ...
against
poison Poison is a chemical substance that has a detrimental effect to life. The term is used in a wide range of scientific fields and industries, where it is often specifically defined. It may also be applied colloquially or figuratively, with a broa ...
by
traditional Chinese medicine Traditional Chinese medicine (TCM) is an alternative medical practice drawn from traditional medicine in China. It has been described as "fraught with pseudoscience", with the majority of its treatments having no logical mechanism of action ...
, which therefore advocated its use for protection against disease, snakes, and evil spirits. The
Dragon Boat Festival The Dragon Boat Festival ( zh, s=端午节, t=端午節) is a traditional Chinese holiday which occurs on the fifth day of the fifth month of the Chinese calendar, which corresponds to late May or June in the Gregorian calendar. Names The Engl ...
coincides with what
Chinese astronomy Astronomy in China has a long history stretching from the Shang dynasty, being refined over a period of more than 3,000 years. The ancient Chinese people have identified stars from 1300 BCE, as Chinese star names later categorized in the twe ...
considers the height of summer and ''
yang Yang may refer to: * Yang, in yin and yang, one half of the two symbolic polarities in Chinese philosophy * Korean yang, former unit of currency of Korea from 1892 to 1902 * YANG, a data modeling language for the NETCONF network configuration ...
'''s force for the year. Adults were advised to consume ''huangjiu'' (as alcohol is considered ''
yin Yin may refer to: *the dark force in the yin and yang from traditional Chinese philosophy and medicine *Yīn (surname) (), a Chinese surname *Yǐn (surname) (), a Chinese surname *Shang dynasty, also known as the Yin dynasty **Yinxu or Yin, the S ...
'') dosed with realgar powder; children too young to consume alcohol would wear an amulet containing realgar or have a ("king") drawn on their forehead or chest with realgar slurry left over from the production of the wine to protect them. These practices were later connected with the festivities honoring poet and statesman
Qu Yuan Qu Yuan ( – 278 BCE) was a Chinese poet and politician in the Chu (state), State of Chu during the Warring States period. He is known for his patriotism and contributions to Classical Chinese poetry, classical poetry and verses, ...
(340–278 BC), who killed himself in protest by drowning in a river. According to legend, locals rushed in boats to save him or preserve his body from being eaten by the fish. A doctor among them is said to have cast realgar into the river, drawing out an aquatic dragon which the boatmen promptly killed.


Preparation

Realgar wine can be bought ready-made, but it is often prepared from homemade yellow wine and realgar mineral powder bought from drugstores, markets, or street vendors. A typical recipe calls for 50 to 100 grams of realgar powder to be added to one litre of homemade wine and left to stand at room temperature for several hours.


Health risks

Although practiced for many centuries, the drinking of realgar wine and the painting of children with realgar have come under scrutiny in modern times. Pure realgar by itself has low toxicity when ingested since its poor solubility hampers its absorption in the gastrointestinal tract, but the minerals used in realgar wine may contain substantial amounts of other inorganic arsenic compounds, such as
arsenate The arsenate ion is . An arsenate (compound) is any compound that contains this ion. Arsenates are salts or esters of arsenic acid. The arsenic atom in arsenate has a valency of 5 and is also known as pentavalent arsenic or As(V). Arsenate res ...
and
arsenite In chemistry, an arsenite is a chemical compound containing an arsenic oxyanion where arsenic has oxidation state +3. Note that in fields that commonly deal with groundwater chemistry, arsenite is used generically to identify soluble AsIII anions. ...
, which can be absorbed by the body. Arsenic is a potent poison and a causal factor in urinary bladder, skin, liver, and lung cancers. There have been a number of poisonings associated with realgar ingestion. Samples of realgar wine have been found to contain 70 to 400 mg of dissolved arsenic compounds per litre (compared to less than 0.003 mg/L in the homemade wine itself), mostly as
arsenite In chemistry, an arsenite is a chemical compound containing an arsenic oxyanion where arsenic has oxidation state +3. Note that in fields that commonly deal with groundwater chemistry, arsenite is used generically to identify soluble AsIII anions. ...
and
arsenate The arsenate ion is . An arsenate (compound) is any compound that contains this ion. Arsenates are salts or esters of arsenic acid. The arsenic atom in arsenate has a valency of 5 and is also known as pentavalent arsenic or As(V). Arsenate res ...
: more than a thousand times the maximum concentration of arsenic legally allowed in commercial liquor. The concentration of dissolved arsenic decreases as
ethanol Ethanol (abbr. EtOH; also called ethyl alcohol, grain alcohol, drinking alcohol, or simply alcohol) is an organic compound. It is an Alcohol (chemistry), alcohol with the chemical formula . Its formula can be also written as or (an ethyl ...
content increases. Consumption of 200 mL of the realgar wine containing 70 mg arsenic compounds per liter resulted in a substantial increase of arsenic levels in urine, to 200 μg/L. Levels of ≥80 μg/L were observed in the urine of children who had their faces painted with realgar slurry, indicating absorption through the skin.


See also

*
Cold-Food Powder Cold-Food Powder () or Five Minerals Powder () was a poisonous psychoactive drug popular during the Six Dynasties (220–589) and Tang dynasty (618–907) periods of China. Terminology Both Chinese names ''hanshisan'' and ''wushisan'' have the ...
, an ancient Chinese drug containing realgar


References

{{chinese booze Chinese wine Adulteration