Raw water
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Raw water is water found in the environment that has not been treated and does not have any of its minerals, ions, particles, bacteria, or parasites removed. Raw water includes
rain Rain is water droplets that have condensed from atmospheric water vapor and then fall under gravity. Rain is a major component of the water cycle and is responsible for depositing most of the fresh water on the Earth. It provides water f ...
water, ground water, water from infiltration wells, and water from bodies like
lake A lake is an area filled with water, localized in a basin, surrounded by land, and distinct from any river or other outlet that serves to feed or drain the lake. Lakes lie on land and are not part of the ocean, although, like the much large ...
s and
river A river is a natural flowing watercourse, usually freshwater, flowing towards an ocean, sea, lake or another river. In some cases, a river flows into the ground and becomes dry at the end of its course without reaching another body of ...
s. Raw water is generally unsafe for human consumption due to the presence of contaminants. A major health problem in some
developing countries A developing country is a sovereign state with a lesser developed industrial base and a lower Human Development Index (HDI) relative to other countries. However, this definition is not universally agreed upon. There is also no clear agreem ...
is use of raw water for drinking and cooking. Without treatment, raw water can be used for
irrigation Irrigation (also referred to as watering) is the practice of applying controlled amounts of water to land to help grow crops, landscape plants, and lawns. Irrigation has been a key aspect of agriculture for over 5,000 years and has been devel ...
,
construction Construction is a general term meaning the art and science to form objects, systems, or organizations,"Construction" def. 1.a. 1.b. and 1.c. ''Oxford English Dictionary'' Second Edition on CD-ROM (v. 4.0) Oxford University Press 2009 and ...
, or cleaning purposes.Perth W.A. (2016) What is Raw Water?. Vintage Road Haulage. http://www.vintageroadhaulage.com.au/faq/what-is-raw-water/ Farmers use it for watering their
crop A crop is a plant that can be grown and harvested extensively for profit or subsistence. When the plants of the same kind are cultivated at one place on a large scale, it is called a crop. Most crops are cultivated in agriculture or hydropon ...
s and give it to
livestock Livestock are the domesticated animals raised in an agricultural setting to provide labor and produce diversified products for consumption such as meat, eggs, milk, fur, leather, and wool. The term is sometimes used to refer solely to ani ...
to drink, storing it in man-made lakes or reservoirs for long periods of time. Construction industries can use raw water for making
cement A cement is a binder, a chemical substance used for construction that sets, hardens, and adheres to other materials to bind them together. Cement is seldom used on its own, but rather to bind sand and gravel (aggregate) together. Cement mixe ...
or for damping down unsealed roads to prevent dust rising. Raw water can also be used for flushing toilets and washing cars, as well as any other purposes that do not require it to be consumed by humans. Water in this form is considered raw, as opposed to water which has been treated before consumption, such as
drinking water Drinking water is water that is used in drink or food preparation; potable water is water that is safe to be used as drinking water. The amount of drinking water required to maintain good health varies, and depends on physical activity level, ...
or water which has been used in an industrial process, such as waste water. Raw water flushing is a method of
water conservation Water conservation includes all the policies, strategies and activities to sustainably manage the natural resource of fresh water, to protect the hydrosphere, and to meet the current and future human demand (thus avoiding water scarcity). Popula ...
where raw water is used for flush toilets.


Composition

The composition of raw water is naturally variable, but commonly contains one or more of the following significant contaminants, in the form of dissolved ions, particles and living organisms: * Humic acid and other complex acids, produced by plant decay. These occur in peat and soil and may cause discoloration and metallic taste of water. * Minerals which make water hard. Most common are
carbonate A carbonate is a salt of carbonic acid (H2CO3), characterized by the presence of the carbonate ion, a polyatomic ion with the formula . The word ''carbonate'' may also refer to a carbonate ester, an organic compound containing the carbonate ...
s of calcium and magnesium. * Particles of
clay Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2 Si2 O5( OH)4). Clays develop plasticity when wet, due to a molecular film of water surrounding the clay pa ...
and
silt Silt is granular material of a size between sand and clay and composed mostly of broken grains of quartz. Silt may occur as a soil (often mixed with sand or clay) or as sediment mixed in suspension with water. Silt usually has a floury feel ...
. * Pathogenic
bacteria Bacteria (; singular: bacterium) are ubiquitous, mostly free-living organisms often consisting of one biological cell. They constitute a large domain of prokaryotic microorganisms. Typically a few micrometres in length, bacteria were am ...
,
viruses A virus is a submicroscopic infectious agent that replicates only inside the living cells of an organism. Viruses infect all life forms, from animals and plants to microorganisms, including bacteria and archaea. Since Dmitri Ivanovsky's ...
,
protozoa Protozoa (singular: protozoan or protozoon; alternative plural: protozoans) are a group of single-celled eukaryotes, either free-living or parasitic, that feed on organic matter such as other microorganisms or organic tissues and debris. Histo ...
and their cysts. ( waterborne diseases) *
Salt Salt is a mineral composed primarily of sodium chloride (NaCl), a chemical compound belonging to the larger class of salts; salt in the form of a natural crystalline mineral is known as rock salt or halite. Salt is present in vast quant ...
, which makes water
brackish Brackish water, sometimes termed brack water, is water occurring in a natural environment that has more salinity than freshwater, but not as much as seawater. It may result from mixing seawater (salt water) and fresh water together, as in estua ...
, having more
salinity Salinity () is the saltiness or amount of salt (chemistry), salt dissolved in a body of water, called saline water (see also soil salinity). It is usually measured in g/L or g/kg (grams of salt per liter/kilogram of water; the latter is dimensio ...
than fresh water, but not as much as seawater. Other, less common, contaminants of raw water include: * Natural
radioactive Radioactive decay (also known as nuclear decay, radioactivity, radioactive disintegration, or nuclear disintegration) is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is consi ...
particles.Manu, A., Santhanakrishnan, V., Rajaram, S., & Ravi, P. M. (2014). Concentration of natural radionuclides in raw water and packaged drinking water and the effect of water treatment. Journal of Environmental Radioactivity, 138, 456-459 * Perfluorinated alkyl acids, such as perfluorooctanoic acid, which are group of pollutants that have been found in wastewater throughout
Europe Europe is a large peninsula conventionally considered a continent in its own right because of its great physical size and the weight of its history and traditions. Europe is also considered a Continent#Subcontinents, subcontinent of Eurasia ...
. There are concerns these chemicals could contaminate raw water sources that are commonly used for drinking water. *
Endocrine disruptor Endocrine disruptors, sometimes also referred to as hormonally active agents, endocrine disrupting chemicals, or endocrine disrupting compounds are chemicals that can interfere with endocrine (or hormonal) systems. These disruptions can cause ...
compounds; chemicals that can interfere with the endocrine system causing cancerous tumors, birth defects, and other developmental disorders. These contaminants can be harmful to humans if they drink raw water containing them, or if the water is not treated properly before consumption. The contaminants can also have an effect on the local ecosystem. For example, endocrine disrupting chemicals can have harmful effects on fish populations living in natural
lake A lake is an area filled with water, localized in a basin, surrounded by land, and distinct from any river or other outlet that serves to feed or drain the lake. Lakes lie on land and are not part of the ocean, although, like the much large ...
s and
river A river is a natural flowing watercourse, usually freshwater, flowing towards an ocean, sea, lake or another river. In some cases, a river flows into the ground and becomes dry at the end of its course without reaching another body of ...
s. These growing health concerns have led to the development of guidelines, such HACCP ( Hazard Analysis and Critical Control Points), for the production of safe drinking water from wastewater and raw water, and research into
sustainable Specific definitions of sustainability are difficult to agree on and have varied in the literature and over time. The concept of sustainability can be used to guide decisions at the global, national, and individual levels (e.g. sustainable livi ...
water supply alternatives Rodriguez, C., Van Buynder, P., Lugg, R., Blair, P., Devine, B., Cook, A., & Weinstein, P. (2009). Indirect Potable Reuse: A Sustainable Water Supply Alternative. International Journal of Environmental Research and Public Health, 6(3), 1174–1209


Treatment

Raw water can be used for many purposes, such as
cooling water Cooling tower and water discharge of a nuclear power plant Water cooling is a method of heat removal from components and industrial equipment. Evaporative cooling using water is often more efficient than air cooling. Water is inexpensive and ...
, water for rinsing and chemical production,
purified water Purified water is water that has been mechanically filtered or processed to remove impurities and make it suitable for use. Distilled water was, formerly, the most common form of purified water, but, in recent years, water is more frequently pur ...
, and
drinking water Drinking water is water that is used in drink or food preparation; potable water is water that is safe to be used as drinking water. The amount of drinking water required to maintain good health varies, and depends on physical activity level, ...
.Clever, M., Jordt, F., Knauf, R., Räbiger, N., Rüdebusch, M., & Hilker-Scheibel, R. (2000). Process water production from river water by ultrafiltration and reverse osmosis. Desalination, 131(1–3), 325-336 However, due to the possible contaminants, raw water must be treated before it is allowed for human consumption or industrial use.Bertone, E., Stewart, R. A., Zhang, H., & O'Halloran, K. (2016). Hybrid water treatment cost prediction model for raw water intake optimization. Environmental Modelling & Software, 75, 230-242 There are several steps involved in the treatment of raw water, and different methods in which it can take place.


Reverse osmosis

Reverse osmosis Reverse osmosis (RO) is a water purification process that uses a partially permeable membrane to separate ions, unwanted molecules and larger particles from drinking water. In reverse osmosis, an applied pressure is used to overcome osmotic ...
has been used for the production of demineralised water for over 30 years. In reverse osmosis, water is transported across a membrane under high pressure, leaving a product that consists mainly of water and a
concentrate A concentrate is a form of substance that has had the majority of its base component (in the case of a liquid: the solvent) removed. Typically, this will be the removal of water from a solution or suspension, such as the removal of water from ...
containing most other components such as
mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2 ...
s and unwanted residues.Vingerhoeds, M. H., Nijenhuis-de Vries, M. A., Ruepert, N., van der Laan, H., Bredie, W. L. P., & Kremer, S. (2016). Sensory quality of drinking water produced by reverse osmosis membrane filtration followed by remineralisation. Water Research, 94, 42-51 Many contaminants, including
iron Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in ...
,
manganese Manganese is a chemical element with the Symbol (chemistry), symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese is a transition metal with a multifaceted array of ...
,
ammonium The ammonium cation is a positively-charged polyatomic ion with the chemical formula or . It is formed by the protonation of ammonia (). Ammonium is also a general name for positively charged or protonated substituted amines and quaterna ...
, traces of
pesticide Pesticides are substances that are meant to control pests. This includes herbicide, insecticide, nematicide, molluscicide, piscicide, avicide, rodenticide, bactericide, insect repellent, animal repellent, microbicide, fungicide, and ...
s and
medicine Medicine is the science and practice of caring for a patient, managing the diagnosis, prognosis, prevention, treatment, palliation of their injury or disease, and promoting their health. Medicine encompasses a variety of health care pr ...
s, organic micro pollutants, and
radioactive Radioactive decay (also known as nuclear decay, radioactivity, radioactive disintegration, or nuclear disintegration) is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is consi ...
particles can be removed with reverse osmosis alone. This efficiency has made reverse osmosis the primary method of water purification, often being used in combination with other methods, as a final treatment. A downside to reverse osmosis is that the removing of most minerals from water can have negative effects on its taste. Minerals are sometimes added to drinking water that was already filtered to improve its taste.


Conventional pre-treatment

The conventional treatment method for water purification is a complex, multistage process that was used for many years. It generally consists of five primary steps. First, raw water is adjusted for alkalinity and pH with the addition of hydrated lime and
carbon dioxide Carbon dioxide ( chemical formula ) is a chemical compound made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature. In the air, carbon dioxide is t ...
. Second, particulate matter is congregated with aluminum sulphate and other coagulants, such as
polymer A polymer (; Greek '' poly-'', "many" + '' -mer'', "part") is a substance or material consisting of very large molecules called macromolecules, composed of many repeating subunits. Due to their broad spectrum of properties, both synthetic a ...
s, which the water flows in a cascade that mixes the chemicals and raw water with the coagulants. Third, the water is slowly mixed in
clarifier Clarifiers are settling tanks built with mechanical means for continuous removal of solids being deposited by sedimentation. A clarifier is generally used to remove solid particulates or suspended solids from liquid for clarification and/or thi ...
s where larger particles settle down to the bottom and are periodically removed ( sedimentation). Fourth, water is directed from the clarifiers to the filters (e.g.
anthracite Anthracite, also known as hard coal, and black coal, is a hard, compact variety of coal that has a submetallic luster. It has the highest carbon content, the fewest impurities, and the highest energy density of all types of coal and is the hig ...
and
sand filter Sand filters are used as a step in the water treatment process of water purification. There are three main types; rapid (gravity) sand filters, upward flow sand filters and slow sand filters. All three methods are used extensively in the water i ...
) to entrap any smaller particles that survived the clarification process. Finally,
sodium hydroxide Sodium hydroxide, also known as lye and caustic soda, is an inorganic compound with the formula NaOH. It is a white solid ionic compound consisting of sodium cations and hydroxide anions . Sodium hydroxide is a highly caustic base and al ...
is added to adjust the final pH/alkalinity, sodium hypochlorite for disinfection and
fluoride Fluoride (). According to this source, is a possible pronunciation in British English. is an inorganic, monatomic anion of fluorine, with the chemical formula (also written ), whose salts are typically white or colorless. Fluoride salts ty ...
for fluoridation. This process is often used as a pre-treatment method while another processes, such as reverse osmosis, is used for the final treatment. A disadvantage of this method is its use of chemicals, such as
ozone Ozone (), or trioxygen, is an inorganic molecule with the chemical formula . It is a pale blue gas with a distinctively pungent smell. It is an allotrope of oxygen that is much less stable than the diatomic allotrope , breaking down in the l ...
, flocculents,
hydrogen peroxide Hydrogen peroxide is a chemical compound with the formula . In its pure form, it is a very pale blue liquid that is slightly more viscous than water. It is used as an oxidizer, bleaching agent, and antiseptic, usually as a dilute solution (3 ...
, lime, and
chlorine Chlorine is a chemical element with the symbol Cl and atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate between them. Chlorine i ...
for the filtration process. These chemicals could be dangerous if used incorrectly or if they remained in the water after complete treatment. This requires special precautions, and each step of the process has to be controlled to achieve an overall optimal performance. The need for a complex control system for conventional treatment can result in it being financially costly. This has led to the development of alternative pre-treatment and treatment methods for raw water.


Ultrafiltration

Ultrafiltration is a membrane filtration process and provides an alternative to conventional pre-treatment. In this method water is only pre-filtered with a common screen filter before being filtered at high pressure through a membrane, separating the water from contaminants within it. Ultrafiltration can be used on its own for water purification or as a pre-treatment for reverse osmosis. Its advantages over conventional pre-treatment include: very high
water quality Water quality refers to the chemical, physical, and biological characteristics of water based on the standards of its usage. It is most frequently used by reference to a set of standards against which compliance, generally achieved through tr ...
independent of the contaminants in the initial raw water, a plant that is simpler in design and more flexible, which makes it easier to automate, lower use of chemicals, and final product free of
virus A virus is a submicroscopic infectious agent that replicates only inside the living cells of an organism. Viruses infect all life forms, from animals and plants to microorganisms, including bacteria and archaea. Since Dmitri Ivanovsk ...
es and
microorganism A microorganism, or microbe,, ''mikros'', "small") and ''organism'' from the el, ὀργανισμός, ''organismós'', "organism"). It is usually written as a single word but is sometimes hyphenated (''micro-organism''), especially in old ...
s.


Biofilm pre-treatment and Bio-diatomite Dynamic Membrane Reactor

The
biofilm A biofilm comprises any syntrophic consortium of microorganisms in which cells stick to each other and often also to a surface. These adherent cells become embedded within a slimy extracellular matrix that is composed of extracellular po ...
membrane filtration method is used to remove harmful chemical by-products, such as NH4+-N, total
nitrogen Nitrogen is the chemical element with the symbol N and atomic number 7. Nitrogen is a nonmetal and the lightest member of group 15 of the periodic table, often called the pnictogens. It is a common element in the universe, estimated at se ...
, and
dissolved organic matter Dissolved organic carbon (DOC) is the fraction of organic carbon operationally defined as that which can pass through a filter with a pore size typically between 0.22 and 0.7 micrometers. The fraction remaining on the filter is called parti ...
, that could form from disinfection processes.Yang, G., Feng, L., Wang, S., Zhou, J., Guo, C., Xia, T., Sun, W., Jiang, Y., Sun, X., Cao, Lian., Xu, X., Zhu, L. (2015). Potential risk and control strategy of biofilm pretreatment process treating raw water. Bioresource Technology, 198, 456-463 Biofilm Pre-treatment is a necessary step for water treatment in many parts of world due to its low operation cost and effectiveness at pollutant removal. In this process microorganisms remove contaminants in raw and wastewater that are harmful to humans, but nutrients to them. Bio-diatomite dynamic membrane reactor filtration combines dynamic membrane technology for wastewater treatment, and microbial colonies that form diatomite particles to purify water. These methods are under development in
China China, officially the People's Republic of China (PRC), is a country in East Asia. It is the world's List of countries and dependencies by population, most populous country, with a Population of China, population exceeding 1.4 billion, slig ...
as part of addressing the country's
pollution Pollution is the introduction of contaminants into the natural environment that cause adverse change. Pollution can take the form of any substance (solid, liquid, or gas) or energy (such as radioactivity, heat, sound, or light). Pollutants, th ...
problems.


Turbidity

Turbidity Turbidity is the cloudiness or haziness of a fluid caused by large numbers of individual particles that are generally invisible to the naked eye, similar to smoke in air. The measurement of turbidity is a key test of water quality. Fluids ...
is how murky or
hazy Haze is traditionally an atmospheric phenomenon in which dust, smoke, and other dry particulates suspended in air obscure visibility and the clarity of the sky. The World Meteorological Organization manual of codes includes a classificatio ...
water seems due to suspended
particle In the physical sciences, a particle (or corpuscule in older texts) is a small localized object which can be described by several physical or chemical properties, such as volume, density, or mass. They vary greatly in size or quantity, from ...
s. The more suspended particles, the higher the turbidity. Turbidity is used to visually measure water quality. In raw water, turbidity is very common.Gauthier, V., Barbeau, B., Tremblay, G., Millette, R., & Bernier, A. (2003). Impact of raw water turbidity fluctuations on drinking water quality in a distribution system. Journal of Environmental Engineering and Science, 2(4), 281-291 High amounts of turbidity in raw water is due to: * Increased flow due to heavy rain fall * Spring turnover of water masses * Bank
erosion Erosion is the action of surface processes (such as water flow or wind) that removes soil, rock, or dissolved material from one location on the Earth's crust, and then transports it to another location where it is deposited. Erosion is d ...
*
Sediment Sediment is a naturally occurring material that is broken down by processes of weathering and erosion, and is subsequently transported by the action of wind, water, or ice or by the force of gravity acting on the particles. For example, sand ...
resuspension in shallow areas * Temporary increase from the more turbid areas


Turbidity and health concerns

During high turbidity peaks,
pathogen In biology, a pathogen ( el, πάθος, "suffering", "passion" and , "producer of") in the oldest and broadest sense, is any organism or agent that can produce disease. A pathogen may also be referred to as an infectious agent, or simply a g ...
s are more commonly found in raw water. This can contribute to the spread of illnesses. When turbidity increases, reported hospital visits for the elderly (65+) with gastrointestinal illnesses also increase. Even places with water filtration systems that meet standards can have an
endemic Endemism is the state of a species being found in a single defined geographic location, such as an island, state, nation, country or other defined zone; organisms that are indigenous to a place are not endemic to it if they are also found else ...
of
gastrointestinal illness Gastrointestinal diseases (abbrev. GI diseases or GI illnesses) refer to diseases involving the gastrointestinal tract, namely the oesophagus, stomach, small intestine, large intestine and rectum, and the accessory organs of digestion, the liver, ...
, or waterborne
infectious disease An infection is the invasion of tissues by pathogens, their multiplication, and the reaction of host tissues to the infectious agent and the toxins they produce. An infectious disease, also known as a transmissible disease or communicable di ...
s. Those hospitalized represent a small percentage of total morbidity caused by these illnesses.


Controlling turbidity

Controlling the land surrounding raw water sources is key to reducing turbidity. Areas of high sediment resuspension and erosion need attending regularly, and screens and other devices are needed to catch suspended particles. Screens that trap particles and debris must be cleaned consistently. Flushing out water pumps should be done when demand is lowest. This gives time for the water to settle, and decrease turbidity before is it needed in high amounts. "Turbidity reduction is best achieved when the water is run through a series of chemical and physical treatment methods before reaching the filter".


Bottled products

Around 2017, untreated spring water, described as "naturally probiotic" raw water, became a commercial product distributed through health food shops, but experts have raised public health concerns about the possible occurrence of harmful bacteria, viruses, and parasites such as '' Giardia''. One raw water business in the United States has even claimed that methods used by bottled and spring water producers could change the molecular structure of water. The fad was mocked on ''
The Daily Show ''The Daily Show'' is an American late-night talk and satirical news television program. It airs each Monday through Thursday on Comedy Central with release shortly after on Paramount+. ''The Daily Show'' draws its comedy and satire form fr ...
'' in April 2018 in a segment that included an interview with Marion Nestle.


See also

* *
Groundwater Groundwater is the water present beneath Earth's surface in rock and Pore space in soil, soil pore spaces and in the fractures of stratum, rock formations. About 30 percent of all readily available freshwater in the world is groundwater. A unit ...
* Wastewater *
Rain Rain is water droplets that have condensed from atmospheric water vapor and then fall under gravity. Rain is a major component of the water cycle and is responsible for depositing most of the fresh water on the Earth. It provides water f ...
water *
Water conservation Water conservation includes all the policies, strategies and activities to sustainably manage the natural resource of fresh water, to protect the hydrosphere, and to meet the current and future human demand (thus avoiding water scarcity). Popula ...


References


Additional sources

* * {{Authority control Liquid water