Quark matter
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Quark matter or QCD matter (
quantum chromodynamic In theoretical physics, quantum chromodynamics (QCD) is the theory of the strong interaction between quarks mediated by gluons. Quarks are fundamental particles that make up composite hadrons such as the proton, neutron and pion. QCD is a ty ...
) refers to any of a number of hypothetical phases of matter whose
degrees of freedom Degrees of freedom (often abbreviated df or DOF) refers to the number of independent variables or parameters of a thermodynamic system. In various scientific fields, the word "freedom" is used to describe the limits to which physical movement or ...
include
quark A quark () is a type of elementary particle and a fundamental constituent of matter. Quarks combine to form composite particles called hadrons, the most stable of which are protons and neutrons, the components of atomic nuclei. All commonly ...
s and
gluon A gluon ( ) is an elementary particle that acts as the exchange particle (or gauge boson) for the strong force between quarks. It is analogous to the exchange of photons in the electromagnetic force between two charged particles. Gluons bind ...
s, of which the prominent example is quark-gluon plasma. Several series of conferences in 2019, 2020, and 2021 were devoted to this topic. Quarks are liberated into quark matter at extremely high temperatures and/or densities, and some of them are still only theoretical as they require conditions so extreme that they cannot be produced in any laboratory, especially not at equilibrium conditions. Under these extreme conditions, the familiar structure of
matter In classical physics and general chemistry, matter is any substance that has mass and takes up space by having volume. All everyday objects that can be touched are ultimately composed of atoms, which are made up of interacting subatomic part ...
, where the basic constituents are nuclei (consisting of
nucleon In physics and chemistry, a nucleon is either a proton or a neutron, considered in its role as a component of an atomic nucleus. The number of nucleons in a nucleus defines the atom's mass number (nucleon number). Until the 1960s, nucleons were ...
s which are bound states of quarks) and electrons, is disrupted. In quark matter it is more appropriate to treat the quarks themselves as the basic degrees of freedom. In the
standard model The Standard Model of particle physics is the theory describing three of the four known fundamental forces ( electromagnetic, weak and strong interactions - excluding gravity) in the universe and classifying all known elementary particles. It ...
of particle physics, the
strong force The strong interaction or strong force is a fundamental interaction that confines quarks into proton, neutron, and other hadron particles. The strong interaction also binds neutrons and protons to create atomic nuclei, where it is called the ...
is described by the theory of
QCD In theoretical physics, quantum chromodynamics (QCD) is the theory of the strong interaction between quarks mediated by gluons. Quarks are fundamental particles that make up composite hadrons such as the proton, neutron and pion. QCD is a type o ...
. At ordinary temperatures or densities this force just confines the quarks into composite particles (
hadrons In particle physics, a hadron (; grc, ἁδρός, hadrós; "stout, thick") is a composite subatomic particle made of two or more quarks held together by the strong interaction. They are analogous to molecules that are held together by the ele ...
) of size around 10−15 m = 1 
femtometer The magnitudes_.html" ;"title="Magnitude_(mathematics).html" ;"title="atom.html" ;"title="helium helium_atom_and_perspective_Magnitude_(mathematics)">magnitudes_">Magnitude_(mathematics).html"_;"title="atom.html"_;"title="helium_atom">helium_a ...
= 1 fm (corresponding to the QCD energy scale ΛQCD ≈ 200  MeV) and its effects are not noticeable at longer distances. However, when the temperature reaches the QCD energy scale ( T of order 1012 
kelvin The kelvin, symbol K, is the primary unit of temperature in the International System of Units (SI), used alongside its prefixed forms and the degree Celsius. It is named after the Belfast-born and University of Glasgow-based engineer and ...
s) or the density rises to the point where the average inter-quark separation is less than 1 fm (quark
chemical potential In thermodynamics, the chemical potential of a species is the energy that can be absorbed or released due to a change of the particle number of the given species, e.g. in a chemical reaction or phase transition. The chemical potential of a speci ...
μ around 400 MeV), the hadrons are melted into their constituent quarks, and the strong interaction becomes the dominant feature of the physics. Such phases are called quark matter or QCD matter. The strength of the color force makes the properties of quark matter unlike gas or plasma, instead leading to a state of matter more reminiscent of a liquid. At high densities, quark matter is a Fermi liquid, but is predicted to exhibit color superconductivity at high densities and temperatures below 1012 K.


Occurrence


Natural occurrence

* According to the
Big Bang The Big Bang event is a physical theory that describes how the universe expanded from an initial state of high density and temperature. Various cosmological models of the Big Bang explain the evolution of the observable universe from the ...
theory, in the early universe at high temperatures when the universe was only a few tens of microseconds old, the phase of matter took the form of a hot phase of quark matter called the
quark–gluon plasma Quark–gluon plasma (QGP) or quark soup is an interacting localized assembly of quarks and gluons at thermal (local kinetic) and (close to) chemical (abundance) equilibrium. The word ''plasma'' signals that free color charges are allowed. In a ...
(QGP). *
Compact star In astronomy, the term compact star (or compact object) refers collectively to white dwarfs, neutron stars, and black holes. It would grow to include exotic stars if such hypothetical, dense bodies are confirmed to exist. All compact objects ha ...
s (
neutron star A neutron star is the collapsed core of a massive supergiant star, which had a total mass of between 10 and 25 solar masses, possibly more if the star was especially metal-rich. Except for black holes and some hypothetical objects (e.g. w ...
s). A neutron star is much cooler than 1012 K, but gravitational collapse has compressed it to such high densities, that it is reasonable to surmise that quark matter may exist in the core. Compact stars composed mostly or entirely of quark matter are called
quark star A quark star is a hypothetical type of compact, exotic star, where extremely high core temperature and pressure has forced nuclear particles to form quark matter, a continuous state of matter consisting of free quarks. Background Some massive ...
s or strange stars. * QCD matter may exist within the
collapsar A collapsar is a star which has undergone gravitational collapse. When a star no longer has enough fuel for significant fusion reactions, there are three possible outcomes, depending on the star's mass: If it is less than the Chandrasekhar limit ...
of a
gamma-ray burst In gamma-ray astronomy, gamma-ray bursts (GRBs) are immensely energetic explosions that have been observed in distant galaxies. They are the most energetic and luminous electromagnetic events since the Big Bang. Bursts can last from ten millise ...
, where temperatures as high as 6.7 x 1013 K may be generated. At this time no star with properties expected of these objects has been observed, although some evidence has been provided for quark matter in the cores of large neutron stars. *
Strangelet A strangelet (pronounced ) is a hypothetical particle consisting of a bound state of roughly equal numbers of up, down, and strange quarks. An equivalent description is that a strangelet is a small fragment of strange matter, small enough to be ...
s. These are theoretically postulated (but as yet unobserved) lumps of
strange matter Strange matter (or strange quark matter) is quark matter containing strange quarks. In nature, strange matter is hypothesized to occur in the core of neutron stars, or, more speculatively, as isolated droplets that may vary in size from femtome ...
comprising nearly equal amounts of up, down and strange quarks. Strangelets are supposed to be present in the galactic flux of high energy particles and should therefore theoretically be detectable in
cosmic rays Cosmic rays are high-energy particles or clusters of particles (primarily represented by protons or atomic nuclei) that move through space at nearly the speed of light. They originate from the Sun, from outside of the Solar System in our ...
here on Earth, but no strangelet has been detected with certainty. *
Cosmic ray Cosmic rays are high-energy particles or clusters of particles (primarily represented by protons or atomic nuclei) that move through space at nearly the speed of light. They originate from the Sun, from outside of the Solar System in our own ...
impacts. Cosmic rays comprise a lot of different particles, including highly accelerated atomic nuclei, particularly that of
iron Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in ...
. Laboratory experiments suggests that the inevitable interaction with heavy
noble gas The noble gases (historically also the inert gases; sometimes referred to as aerogens) make up a class of chemical elements with similar properties; under standard conditions, they are all odorless, colorless, monatomic gases with very low ch ...
nuclei in the
upper atmosphere Upper atmosphere is a collective term that refers to various layers of the atmosphere of the Earth above the troposphere and corresponding regions of the atmospheres of other planets, and includes: * The mesosphere, which on Earth lies between th ...
would lead to quark–gluon plasma formation. * Quark matter with
baryon number In particle physics, the baryon number is a strictly conserved additive quantum number of a system. It is defined as ::B = \frac\left(n_\text - n_\bar\right), where ''n''q is the number of quarks, and ''n'' is the number of antiquarks. Baryo ...
over about 300 may be more stable than nuclear matter. This form of baryonic matter could possibly form a
continent of stability The continent of stability is a hypothesised large group of nuclides with masses greater than 300 daltons that is stable against radioactive decay, consisting of freely flowing up quarks and down quarks rather than up and down quarks bound into pro ...
.


Laboratory experiments

Even though quark-gluon plasma can only occur under quite extreme conditions of temperature and/or pressure, it is being actively studied at particle colliders, such as the Large Hadron Collider LHC at
CERN The European Organization for Nuclear Research, known as CERN (; ; ), is an intergovernmental organization that operates the largest particle physics laboratory in the world. Established in 1954, it is based in a northwestern suburb of Gen ...
and the Relativistic Heavy Ion Collider
RHIC The Relativistic Heavy Ion Collider (RHIC ) is the first and one of only two operating heavy-ion colliders, and the only spin-polarized proton collider ever built. Located at Brookhaven National Laboratory (BNL) in Upton, New York, and used by an ...
at
Brookhaven National Laboratory Brookhaven National Laboratory (BNL) is a United States Department of Energy national laboratory located in Upton, Long Island, and was formally established in 1947 at the site of Camp Upton, a former U.S. Army base and Japanese internment c ...
. In these collisions, the plasma only occurs for a very short time before it spontaneously disintegrates. The plasma's physical characteristics are studied by detecting the debris emanating from the collision region with large particle detectors Heavy-ion collisions at very high energies can produce small short-lived regions of space whose energy density is comparable to that of the 20-micro-second-old universe. This has been achieved by colliding heavy nuclei such as
lead Lead is a chemical element with the symbol Pb (from the Latin ) and atomic number 82. It is a heavy metal that is denser than most common materials. Lead is soft and malleable, and also has a relatively low melting point. When freshly cut, ...
nuclei at high speeds, and a first time claim of formation of
quark–gluon plasma Quark–gluon plasma (QGP) or quark soup is an interacting localized assembly of quarks and gluons at thermal (local kinetic) and (close to) chemical (abundance) equilibrium. The word ''plasma'' signals that free color charges are allowed. In a ...
came from the
SPS SPS may refer to: Law and government * Agreement on the Application of Sanitary and Phytosanitary Measures of the WTO * NATO Science for Peace and Security * Single Payment Scheme, an EU agricultural subsidy * The Standard Procurement System, ...
accelerator at
CERN The European Organization for Nuclear Research, known as CERN (; ; ), is an intergovernmental organization that operates the largest particle physics laboratory in the world. Established in 1954, it is based in a northwestern suburb of Gen ...
in February 2000. This work has been continued at more powerful accelerators, such as RHIC in the US, and as of 2010 at the European LHC at CERN located in the border area of Switzerland and France. There is good evidence that the quark–gluon plasma has also been produced at RHIC.


Thermodynamics

The context for understanding the thermodynamics of quark matter is the
standard model The Standard Model of particle physics is the theory describing three of the four known fundamental forces ( electromagnetic, weak and strong interactions - excluding gravity) in the universe and classifying all known elementary particles. It ...
of particle physics, which contains six different
flavors Flavor or flavour is either the sensory perception of taste or smell, or a flavoring in food that produces such perception. Flavor or flavour may also refer to: Science *Flavors (programming language), an early object-oriented extension to Li ...
of quarks, as well as
lepton In particle physics, a lepton is an elementary particle of half-integer spin (spin ) that does not undergo strong interactions. Two main classes of leptons exist: charged leptons (also known as the electron-like leptons or muons), and neutr ...
s like
electron The electron ( or ) is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family, and are generally thought to be elementary particles because they have n ...
s and
neutrino A neutrino ( ; denoted by the Greek letter ) is a fermion (an elementary particle with spin of ) that interacts only via the weak interaction and gravity. The neutrino is so named because it is electrically neutral and because its rest mass ...
s. These interact via the
strong interaction The strong interaction or strong force is a fundamental interaction that confines quarks into proton, neutron, and other hadron particles. The strong interaction also binds neutrons and protons to create atomic nuclei, where it is called th ...
,
electromagnetism In physics, electromagnetism is an interaction that occurs between particles with electric charge. It is the second-strongest of the four fundamental interactions, after the strong force, and it is the dominant force in the interactions o ...
, and also the
weak interaction In nuclear physics and particle physics, the weak interaction, which is also often called the weak force or weak nuclear force, is one of the four known fundamental interactions, with the others being electromagnetism, the strong interaction ...
which allows one flavor of quark to turn into another. Electromagnetic interactions occur between particles that carry electrical charge; strong interactions occur between particles that carry
color charge Color charge is a property of quarks and gluons that is related to the particles' strong interactions in the theory of quantum chromodynamics (QCD). The "color charge" of quarks and gluons is completely unrelated to the everyday meanings of colo ...
. The correct thermodynamic treatment of quark matter depends on the physical context. For large quantities that exist for long periods of time (the "thermodynamic limit"), we must take into account the fact that the only conserved charges in the standard model are quark number (equivalent to
baryon In particle physics, a baryon is a type of composite subatomic particle which contains an odd number of valence quarks (at least 3). Baryons belong to the hadron family of particles; hadrons are composed of quarks. Baryons are also classifie ...
number), electric charge, the eight color charges, and lepton number. Each of these can have an associated chemical potential. However, large volumes of matter must be electrically and color-neutral, which determines the electric and color charge chemical potentials. This leaves a three-dimensional
phase space In dynamical system theory, a phase space is a space in which all possible states of a system are represented, with each possible state corresponding to one unique point in the phase space. For mechanical systems, the phase space usuall ...
, parameterized by quark chemical potential, lepton chemical potential, and temperature. In compact stars quark matter would occupy cubic kilometers and exist for millions of years, so the thermodynamic limit is appropriate. However, the neutrinos escape, violating lepton number, so the phase space for quark matter in compact stars only has two dimensions, temperature (''T'') and quark number chemical potential μ. A
strangelet A strangelet (pronounced ) is a hypothetical particle consisting of a bound state of roughly equal numbers of up, down, and strange quarks. An equivalent description is that a strangelet is a small fragment of strange matter, small enough to be ...
is not in the thermodynamic limit of large volume, so it is like an exotic nucleus: it may carry electric charge. A heavy-ion collision is in neither the thermodynamic limit of large volumes nor long times. Putting aside questions of whether it is sufficiently equilibrated for thermodynamics to be applicable, there is certainly not enough time for weak interactions to occur, so flavor is conserved, and there are independent chemical potentials for all six quark flavors. The initial conditions (the
impact parameter In physics, the impact parameter is defined as the perpendicular distance between the path of a projectile and the center of a potential field created by an object that the projectile is approaching (see diagram). It is often referred to in ...
of the collision, the number of up and down quarks in the colliding nuclei, and the fact that they contain no quarks of other flavors) determine the chemical potentials. (Reference for this section:).


Phase diagram

The
phase diagram A phase diagram in physical chemistry, engineering, mineralogy, and materials science is a type of chart used to show conditions (pressure, temperature, volume, etc.) at which thermodynamically distinct phases (such as solid, liquid or gaseous ...
of quark matter is not well known, either experimentally or theoretically. A commonly conjectured form of the phase diagram is shown in the figure to the right. It is applicable to matter in a compact star, where the only relevant thermodynamic potentials are quark
chemical potential In thermodynamics, the chemical potential of a species is the energy that can be absorbed or released due to a change of the particle number of the given species, e.g. in a chemical reaction or phase transition. The chemical potential of a speci ...
μ and
temperature Temperature is a physical quantity that expresses quantitatively the perceptions of hotness and coldness. Temperature is measured with a thermometer. Thermometers are calibrated in various temperature scales that historically have relied o ...
T. For guidance it also shows the typical values of μ and ''T'' in heavy-ion collisions and in the early universe. For readers who are not familiar with the concept of a chemical potential, it is helpful to think of μ as a measure of the imbalance between quarks and antiquarks in the system. Higher μ means a stronger bias favoring quarks over antiquarks. At low temperatures there are no antiquarks, and then higher μ generally means a higher density of quarks. Ordinary atomic matter as we know it is really a mixed phase, droplets of nuclear matter (nuclei) surrounded by vacuum, which exists at the low-temperature phase boundary between vacuum and nuclear matter, at μ = 310 MeV and ''T'' close to zero. If we increase the quark density (i.e. increase μ) keeping the temperature low, we move into a phase of more and more compressed nuclear matter. Following this path corresponds to burrowing more and more deeply into a
neutron star A neutron star is the collapsed core of a massive supergiant star, which had a total mass of between 10 and 25 solar masses, possibly more if the star was especially metal-rich. Except for black holes and some hypothetical objects (e.g. w ...
. Eventually, at an unknown critical value of μ, there is a transition to quark matter. At ultra-high densities we expect to find the color-flavor-locked (CFL) phase of color-superconducting quark matter. At intermediate densities we expect some other phases (labelled "non-CFL quark liquid" in the figure) whose nature is presently unknown,. They might be other forms of color-superconducting quark matter, or something different. Now, imagine starting at the bottom left corner of the phase diagram, in the vacuum where μ = ''T'' = 0. If we heat up the system without introducing any preference for quarks over antiquarks, this corresponds to moving vertically upwards along the ''T'' axis. At first, quarks are still confined and we create a gas of hadrons (
pion In particle physics, a pion (or a pi meson, denoted with the Greek letter pi: ) is any of three subatomic particles: , , and . Each pion consists of a quark and an antiquark and is therefore a meson. Pions are the lightest mesons and, more gene ...
s, mostly). Then around ''T'' = 150 MeV there is a crossover to the quark gluon plasma: thermal fluctuations break up the pions, and we find a gas of quarks, antiquarks, and gluons, as well as lighter particles such as photons, electrons, positrons, etc. Following this path corresponds to travelling far back in time (so to say), to the state of the universe shortly after the big bang (where there was a very tiny preference for quarks over antiquarks). The line that rises up from the nuclear/quark matter transition and then bends back towards the ''T'' axis, with its end marked by a star, is the conjectured boundary between confined and unconfined phases. Until recently it was also believed to be a boundary between phases where chiral symmetry is broken (low temperature and density) and phases where it is unbroken (high temperature and density). It is now known that the CFL phase exhibits chiral symmetry breaking, and other quark matter phases may also break chiral symmetry, so it is not clear whether this is really a chiral transition line. The line ends at the "chiral critical point", marked by a star in this figure, which is a special temperature and density at which striking physical phenomena, analogous to critical opalescence, are expected. (Reference for this section:,). For a complete description of phase diagram it is required that one must have complete understanding of dense, strongly interacting hadronic matter and strongly interacting quark matter from some underlying theory e.g. quantum chromodynamics (QCD). However, because such a description requires the proper understanding of QCD in its non-perturbative regime, which is still far from being completely understood, any theoretical advance remains very challenging.


Theoretical challenges: calculation techniques

The phase structure of quark matter remains mostly conjectural because it is difficult to perform calculations predicting the properties of quark matter. The reason is that QCD, the theory describing the dominant interaction between quarks, is strongly coupled at the densities and temperatures of greatest physical interest, and hence it is very hard to obtain any predictions from it. Here are brief descriptions of some of the standard approaches.


Lattice gauge theory

The only first-principles calculational tool currently available is lattice QCD, i.e. brute-force computer calculations. Because of a technical obstacle known as the fermion sign problem, this method can only be used at low density and high temperature (μ < ''T''), and it predicts that the crossover to the quark–gluon plasma will occur around ''T'' = 150 MeV However, it cannot be used to investigate the interesting color-superconducting phase structure at high density and low temperature.


Weak coupling theory

Because QCD is asymptotically free it becomes weakly coupled at unrealistically high densities, and diagrammatic methods can be used. Such methods show that the CFL phase occurs at very high density. At high temperatures, however, diagrammatic methods are still not under full control.


Models

To obtain a rough idea of what phases might occur, one can use a model that has some of the same properties as QCD, but is easier to manipulate. Many physicists use Nambu–Jona-Lasinio models, which contain no gluons, and replace the strong interaction with a four-fermion interaction. Mean-field methods are commonly used to analyse the phases. Another approach is the bag model, in which the effects of confinement are simulated by an additive energy density that penalizes unconfined quark matter.


Effective theories

Many physicists simply give up on a microscopic approach, and make informed guesses of the expected phases (perhaps based on NJL model results). For each phase, they then write down an effective theory for the low-energy excitations, in terms of a small number of parameters, and use it to make predictions that could allow those parameters to be fixed by experimental observations.


Other approaches

There are other methods that are sometimes used to shed light on QCD, but for various reasons have not yet yielded useful results in studying quark matter.


1/N expansion

Treat the number of colors ''N'', which is actually 3, as a large number, and expand in powers of 1/''N''. It turns out that at high density the higher-order corrections are large, and the expansion gives misleading results.


Supersymmetry

Adding scalar quarks (squarks) and fermionic gluons (gluinos) to the theory makes it more tractable, but the thermodynamics of quark matter depends crucially on the fact that only fermions can carry quark number, and on the number of degrees of freedom in general.


Experimental challenges

Experimentally, it is hard to map the phase diagram of quark matter because it has been rather difficult to learn how to tune to high enough temperatures and density in the laboratory experiment using collisions of relativistic heavy ions as experimental tools. However, these collisions ultimately will provide information about the crossover from hadronic matter to QGP. It has been suggested that the observations of compact stars may also constrain the information about the high-density low-temperature region. Models of the cooling, spin-down, and precession of these stars offer information about the relevant properties of their interior. As observations become more precise, physicists hope to learn more. One of the natural subjects for future research is the search for the exact location of the chiral critical point. Some ambitious lattice QCD calculations may have found evidence for it, and future calculations will clarify the situation. Heavy-ion collisions might be able to measure its position experimentally, but this will require scanning across a range of values of μ and T.


Evidence

In 2020, evidence was provided that the cores of neutron stars with mass ~2 M were likely composed of quark matter. Their result was based on neutron-star tidal deformability during a
neutron star merger A neutron star merger is a type of stellar collision. It occurs in a fashion similar to the rare brand of type Ia supernovae resulting from merging white dwarf stars. When two neutron stars orbit each other closely, they gradually spiral i ...
as measured by gravitational-wave observatories, leading to an estimate of star radius, combined with calculations of the equation of state relating the pressure and energy density of the star's core. The evidence was strongly suggestive but did not conclusively prove the existence of quark matter.


See also

* * * * * * * * *


Sources and further reading

* Aronson, S. and Ludlam, T.
''"Hunting the quark gluon plasma"''
U.S. Dept. of Energy (2005) * Letessier, Jean:
Hadrons and quark-gluon plasma
', Cambridge monographs on particle physics, nuclear physics, and cosmology (Vol. 18), Cambridge University Press (2002) * *


References


External links


Virtual Journal on QCD MatterRHIC finds Exotic Antimatter
{{DEFAULTSORT:Qcd Matter Quantum chromodynamics Phases of matter Plasma physics Unsolved problems in physics