Pyroceram
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Pyroceram is the original
glass-ceramic Glass-ceramics are polycrystalline materials produced through controlled crystallization of base glass, producing a fine uniform dispersion of crystals throughout the bulk material. Crystallization is accomplished by subjecting suitable glasses to ...
material developed and
trademarked A trademark (also written trade mark or trade-mark) is a type of intellectual property consisting of a recognizable sign, design, or expression that identifies products or services from a particular source and distinguishes them from others. ...
by
Corning Glass Corning Incorporated is an American multinational technology company that specializes in specialty glass, ceramics, and related materials and technologies including advanced optics, primarily for industrial and scientific applications. The co ...
in the 1950s. Pyroceram is an opaque, white, glass material, commonly used in kitchenware, glass stove tops, wood stove doors, etc.. It has high heat tolerance and low thermal expansion.


Development

Its development has been traced to Corning's work in developing
photosensitive glass Photosensitive glass, also known as photostructurable glass (PSG) or photomachinable glass, is a crystal-clear glass that belongs to the lithium-silicate family of glasses, in which an image of a mask can be captured by microscopic metallic par ...
. Corning credits S. Donald Stookey with the discovery of Pyroceram. While conducting research in 1953 on a photosensitive lithium silicate glass called Fotoform containing a dispersion of
silver nanoparticle Silver nanoparticles are nanoparticles of silver of between 1 nm and 100 nm in size. While frequently described as being 'silver' some are composed of a large percentage of silver oxide due to their large ratio of surface to bulk silve ...
s, Stookey noted that an accidentally overheated fragment of the glass resisted breakage when dropped. This discovery evolved into Pyroceram, with β-
spodumene Spodumene is a pyroxene mineral consisting of lithium aluminium inosilicate, Li Al( Si O3)2, and is a source of lithium. It occurs as colorless to yellowish, purplish, or lilac kunzite (see below), yellowish-green or emerald-green hiddenite, pri ...
as the crystalline phase, and was used in 1958 for the production of
CorningWare Corning Ware, also written CorningWare, was originally a brand name for a unique glass-ceramic ( Pyroceram) cookware resistant to thermal shock. It was first introduced in 1958 by Corning Glass Works (later Corning Inc.) in the United States. The ...
cookware. Pyroceram's thermal stability also results in its being used for mirrors in astronomical telescopes. A transparent version of Pyroceram, with β-
quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical form ...
as the crystalline phase, was also described in 1950s patents. By 1963 this variant was also being seriously studied for use in making cookware. It would be extensively explored over the next two decades and result in the creation of
Visions Vision, Visions, or The Vision may refer to: Perception Optical perception * Visual perception, the sense of sight * Visual system, the physical mechanism of eyesight * Computer vision, a field dealing with how computers can be made to gain un ...
cookware, by Corning France, in the late 1970s. The manufacture of the material involves controlled
crystallization Crystallization is the process by which solid forms, where the atoms or molecules are highly organized into a structure known as a crystal. Some ways by which crystals form are precipitating from a solution, freezing, or more rarely deposi ...
.
NASA The National Aeronautics and Space Administration (NASA ) is an independent agency of the US federal government responsible for the civil space program, aeronautics research, and space research. NASA was established in 1958, succeeding t ...
classifies it as a
glass-ceramic Glass-ceramics are polycrystalline materials produced through controlled crystallization of base glass, producing a fine uniform dispersion of crystals throughout the bulk material. Crystallization is accomplished by subjecting suitable glasses to ...
product. After about 30 years of informal use as a standard in high-heat (≥1000 °C) applications, Pyroceram 9606 was approved by
NIST The National Institute of Standards and Technology (NIST) is an agency of the United States Department of Commerce whose mission is to promote American innovation and industrial competitiveness. NIST's activities are organized into physical sci ...
as a
certified reference material Certified reference materials (CRMs) are 'controls' or standards used to check the quality and metrological traceability of products, to validate analytical measurement methods, or for the calibration of instruments. A certified reference materi ...
for
thermal conductivity The thermal conductivity of a material is a measure of its ability to conduct heat. It is commonly denoted by k, \lambda, or \kappa. Heat transfer occurs at a lower rate in materials of low thermal conductivity than in materials of high thermal ...
measurements.


Trademark

Pyroceram was originally a proprietary brand name. Corning registered Pyroceram as a trademark for glass-ceramic vessels and utensils in 1958, and in 1966 added polished glass-ceramic tabletops and countertops to the registered uses of the brand name. Both of those registrations have since ended. In 1998, Corning registered Pyroceram as a trademark for clear glass-ceramic window glass for wood-burning stoves.


See also

*
National Institute of Standards and Technology The National Institute of Standards and Technology (NIST) is an agency of the United States Department of Commerce whose mission is to promote American innovation and industrial competitiveness. NIST's activities are organized into physical sci ...
.


References


External links


The NPL Measurements Contribution to the Certification of Pyroceram 9606 as a Reference Material for Thermal Properties

Corning Visions
-
X-ray fluorescence X-ray fluorescence (XRF) is the emission of characteristic "secondary" (or fluorescent) X-rays from a material that has been excited by being bombarded with high-energy X-rays or gamma rays. The phenomenon is widely used for elemental analysis ...
test results Glass-ceramics Corning Inc. {{material-stub