Perlite is an

amorphous In condensed matter physics and materials science, an amorphous solid (or non-crystalline solid, glassy solid) is a solid that lacks the long-range order that is characteristic of a crystal. Etymology The term comes from the Greek language, Gr ...

volcanic glass Volcanic glass is the amorphous (uncrystallized) product of rapidly cooling magma. Like all types of glass, it is a state of matter intermediate between the closely packed, highly ordered array of a crystal and the highly disordered array of ...

that has a relatively high

water Water (chemical formula ) is an inorganic, transparent, tasteless, odorless, and nearly colorless chemical substance, which is the main constituent of Earth's hydrosphere and the fluids of all known living organisms (in which it acts as ...

content, typically formed by the hydration of

obsidian Obsidian () is a naturally occurring volcanic glass formed when lava extruded from a volcano cools rapidly with minimal crystal growth. It is an igneous rock. Obsidian is produced from felsic lava, rich in the lighter elements such as silicon ...

. It occurs naturally and has the unusual property of greatly expanding when heated sufficiently. It is an industrial mineral, suitable "as ceramic flux to lower the

sintering Clinker nodules produced by sintering Sintering or frittage is the process of compacting and forming a solid mass of material by pressure or heat without melting it to the point of liquefaction. Sintering happens as part of a manufacturing ...

temperature", and a commercial product useful for its low density after processing.

Properties

Perlite softens when it reaches temperatures of . Water trapped in the structure of the material vaporises and escapes, and this causes the expansion of the material to 7–16 times its original volume. The expanded material is a brilliant white, due to the reflectivity of the trapped bubbles. Unexpanded ("raw") perlite has a

bulk density Bulk density, also called apparent density or volumetric density, is a property of powders, granules, and other "divided" solids, especially used in reference to mineral components ( soil, gravel), chemical substances, ( pharmaceutical) ingredi ...

around 1100 kg/m³ (1.1 g/cm³), while typical expanded perlite has a bulk density of about 30–150 kg/m³ (0.03–0.150 g/cm³).

Typical analysis

*70–75%

silicon dioxide Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is one ...

: SiO₂ *12–15% aluminium oxide: Al₂O₃ *3–4%

sodium oxide Sodium oxide is a chemical compound with the formula Na2 O. It is used in ceramics and glasses. It is a white solid but the compound is rarely encountered. Instead "sodium oxide" is used to describe components of various materials such as gla ...

: Na₂O *3–5%

potassium oxide Potassium oxide ( K O) is an ionic compound of potassium and oxygen. It is a base. This pale yellow solid is the simplest oxide of potassium. It is a highly reactive compound that is rarely encountered. Some industrial materials, such as fertili ...

: K₂O *0.5-2%

iron oxide Iron oxides are chemical compounds composed of iron and oxygen. Several iron oxides are recognized. All are black magnetic solids. Often they are non-stoichiometric. Oxyhydroxides are a related class of compounds, perhaps the best known of wh ...

: Fe₂O₃ *0.2–0.7%

magnesium oxide Magnesium oxide ( Mg O), or magnesia, is a white hygroscopic solid mineral that occurs naturally as periclase and is a source of magnesium (see also oxide). It has an empirical formula of MgO and consists of a lattice of Mg2+ ions and O2� ...

: MgO *0.5–1.5%

calcium oxide Calcium oxide (CaO), commonly known as quicklime or burnt lime, is a widely used chemical compound. It is a white, caustic, alkaline, crystalline solid at room temperature. The broadly used term "'' lime''" connotes calcium-containing inorganic ...

: CaO *3–5% loss on ignition (chemical / combined water)

Sources and production

Perlite is a non-renewable resource. The world reserves of perlite are estimated at 700 million

tonne The tonne ( or ; symbol: t) is a unit of mass equal to 1000 kilograms. It is a non-SI unit accepted for use with SI. It is also referred to as a metric ton to distinguish it from the non-metric units of the short ton ( United State ...

s. The confirmed resources of perlite existing in

Armenia Armenia (), , group=pron officially the Republic of Armenia,, is a landlocked country in the Armenian Highlands of Western Asia.The UNbr>classification of world regions places Armenia in Western Asia; the CIA World Factbook , , and ''O ...

amount to 150 million m³, whereas the total amount of projected resources reaches up to 3 billion m³. Considering specific density of 1.1 ton/m³ confirmed reserves in Armenia amount to 136 million tons. Other reported reserves are: Greece - 120 million tonnes, Turkey, USA and Hungary - about 49-57 million tonnes. Perlite world production, led by China, Turkey, Greece, USA, Armenia and Hungary, summed up to 4.6 million tonnes in 2018.

Uses

Because of its low density and relatively low price (about US$150 per tonne of unexpanded perlite), many commercial applications for perlite have developed.

Construction and manufacturing

In the

construction Construction is a general term meaning the art and science to form objects, systems, or organizations,"Construction" def. 1.a. 1.b. and 1.c. ''Oxford English Dictionary'' Second Edition on CD-ROM (v. 4.0) Oxford University Press 2009 and ...

and manufacturing fields, it is used in lightweight

plaster Plaster is a building material used for the protective or decorative coating of walls and ceilings and for moulding and casting decorative elements. In English, "plaster" usually means a material used for the interiors of buildings, while "re ...

s, concrete and mortar, insulation and ceiling tiles.Wallace P. Bole
Perlite
USGS 2009 Minerals Yearbook It may also be used to build

composite materials A composite material (also called a composition material or shortened to composite, which is the common name) is a material which is produced from two or more constituent materials. These constituent materials have notably dissimilar chemical or ...

that are sandwich-structured or to create syntactic foam. Perlite filters are fairly commonplace in filtering

beer Beer is one of the oldest and the most widely consumed type of alcoholic drink in the world, and the third most popular drink overall after water and tea. It is produced by the brewing and fermentation of starches, mainly derived from ce ...

before it is bottled. Small quantities of perlite are also used in foundries,

cryogenic In physics, cryogenics is the production and behaviour of materials at very low temperatures. The 13th IIR International Congress of Refrigeration (held in Washington DC in 1971) endorsed a universal definition of “cryogenics” and “cr ...

insulation, and

ceramics A ceramic is any of the various hard, brittle, heat-resistant and corrosion-resistant materials made by shaping and then firing an inorganic, nonmetallic material, such as clay, at a high temperature. Common examples are earthenware, porcelain ...

(as a clay additive). It is also used by the explosives industry.

Aquatic filtration

Perlite is currently used in commercial pool filtration technology, as a replacement to diatomaceous earth filters. Perlite is an excellent filtration aid and is used extensively as an alternative to

diatomaceous earth Diatomaceous earth (), diatomite (), or kieselgur/kieselguhr is a naturally occurring, soft, siliceous sedimentary rock that can be crumbled into a fine white to off-white powder. It has a particle size ranging from more than 3 μm to l ...

. The popularity of perlite usage as a filter medium is growing considerably worldwide. Several products exist in the market to provide perlite based filtration. Several perlite filters and perlite media have met NSF-50 approval (Aquify PMF Series and AquaPerl), which standardizes water quality and technology safety and performance. Perlite can be safely disposed of through existing sewage systems, although some pool operators choose to separate the perlite using settling tanks or screening systems to be disposed of separately.

Biotechnology

Due to thermal and mechanical stability, non-toxicity, and high resistance against microbial attacks and organic solvents, perlite is widely used in biotechnological applications. Perlite was found to be an excellent support for immobilization of biocatalysts such as enzymes for

bioremediation Bioremediation broadly refers to any process wherein a biological system (typically bacteria, microalgae, fungi, and plants), living or dead, is employed for removing environmental pollutants from air, water, soil, flue gasses, industrial effluent ...

and sensing applications.

Agriculture

horticulture Horticulture is the branch of agriculture that deals with the art, science, technology, and business of plant cultivation. It includes the cultivation of fruits, vegetables, nuts, seeds, herbs, sprouts, mushrooms, algae, flowers, seaweeds and no ...

, perlite can be used as a

soil amendment A soil conditioner is a product which is added to soil to improve the soil’s physical qualities, usually its fertility (ability to provide nutrition for plants) and sometimes its mechanics. In general usage, the term "soil conditioner" is often ...

or alone as a medium for

hydroponics Hydroponics is a type of horticulture and a subset of hydroculture which involves growing plants, usually crops or medicinal plants, without soil, by using water-based mineral nutrient solutions in aqueous solvents. Terrestrial or aquatic plant ...

or for starting cuttings. When used as an amendment, it has high permeability and low water retention and helps prevent

soil compaction In geotechnical engineering, soil compaction is the process in which stress applied to a soil causes densification as air is displaced from the pores between the soil grains. When stress is applied that causes densification due to water (or othe ...

Cosmetics

Perlite is used in cosmetics as an absorbent and mechanical exfoliant.

Substitutes

Perlite can be replaced for all of its uses. Substitutes include: * Diatomite, used for filter-aids * Expanded clay, an alternative lightweight filler for building materials *

Shale Shale is a fine-grained, clastic sedimentary rock formed from mud that is a mix of flakes of clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2 Si2 O5( OH)4) and tiny fragments (silt-sized particles) of other minerals, especiall ...

Pumice Pumice (), called pumicite in its powdered or dust form, is a volcanic rock that consists of highly vesicular rough-textured volcanic glass, which may or may not contain crystals. It is typically light-colored. Scoria is another vesicular v ...

Slag Slag is a by-product of smelting ( pyrometallurgical) ores and used metals. Broadly, it can be classified as ferrous (by-products of processing iron and steel), ferroalloy (by-product of ferroalloy production) or non-ferrous/base metals (by-p ...

Vermiculite Vermiculite is a hydrous phyllosilicate mineral which undergoes significant expansion when heated. Exfoliation occurs when the mineral is heated sufficiently, and commercial furnaces can routinely produce this effect. Vermiculite forms by the we ...

- many expanders of perlite are also exfoliating vermiculite and belong to both trade associations

Occupational safety

As perlite contains silicon dioxide, goggles and silica filtering masks are recommended when handling large quantities.

United States

The

Occupational Safety and Health Administration The Occupational Safety and Health Administration'' (OSHA ) is a large regulatory agency of the United States Department of Labor that originally had federal visitorial powers to inspect and examine workplaces. Congress established the agen ...

(OSHA) has set the legal limit (

permissible exposure limit The permissible exposure limit (PEL or OSHA PEL) is a legal limit in the United States for exposure of an employee to a chemical substance or physical agent such as high level noise. Permissible exposure limits are established by the Occupationa ...

) for perlite exposure in the workplace as 15 mg/m³ total exposure and 5 mg/m³ respiratory exposure over an 8-hour workday. The

National Institute for Occupational Safety and Health The National Institute for Occupational Safety and Health (NIOSH, ) is the United States federal agency responsible for conducting research and making recommendations for the prevention of work-related injury and illness. NIOSH is part of the C ...

(NIOSH) has set a recommended exposure limit (REL) of 10 mg/m³ total exposure and 5 mg/m³ respiratory exposure over an 8-hour workday.

References

External links

{{commons category
The Perlite Institute"That Wonderful Volcanic Popcorn."
''Popular Mechanics'', December 1954, p. 136.

Felsic rocks Vitreous rocks Building stone Soil improvers Industrial minerals