Orders of magnitude (specific energy)
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Specific energy or massic energy is
energy In physics, energy (from Ancient Greek: ἐνέργεια, ''enérgeia'', “activity”) is the quantitative property that is transferred to a body or to a physical system, recognizable in the performance of work and in the form of hea ...
per unit
mass Mass is an intrinsic property of a body. It was traditionally believed to be related to the quantity of matter in a physical body, until the discovery of the atom and particle physics. It was found that different atoms and different eleme ...
. It is also sometimes called gravimetric energy density, which is not to be confused with energy density, which is defined as energy per unit volume. It is used to quantify, for example, stored
heat In thermodynamics, heat is defined as the form of energy crossing the boundary of a thermodynamic system by virtue of a temperature difference across the boundary. A thermodynamic system does not ''contain'' heat. Nevertheless, the term is ...
and other
thermodynamic properties In thermodynamics, a physical property is any property that is measurable, and whose value describes a state of a physical system. Thermodynamic properties are defined as characteristic features of a system, capable of specifying the system's stat ...
of substances such as specific internal energy,
specific enthalpy Enthalpy , a property of a thermodynamic system, is the sum of the system's internal energy and the product of its pressure and volume. It is a state function used in many measurements in chemical, biological, and physical systems at a constant p ...
, specific
Gibbs free energy In thermodynamics, the Gibbs free energy (or Gibbs energy; symbol G) is a thermodynamic potential that can be used to calculate the maximum amount of work that may be performed by a thermodynamically closed system at constant temperature and ...
, and specific
Helmholtz free energy In thermodynamics, the Helmholtz free energy (or Helmholtz energy) is a thermodynamic potential that measures the useful work obtainable from a closed thermodynamic system at a constant temperature (isothermal). The change in the Helmholtz ener ...
. It may also be used for the
kinetic energy In physics, the kinetic energy of an object is the energy that it possesses due to its motion. It is defined as the work needed to accelerate a body of a given mass from rest to its stated velocity. Having gained this energy during its acc ...
or potential energy of a body. Specific energy is an intensive property, whereas energy and mass are
extensive properties Physical properties of materials and systems can often be categorized as being either intensive or extensive, according to how the property changes when the size (or extent) of the system changes. According to IUPAC, an intensive quantity is one ...
. The SI unit for specific energy is the
joule The joule ( , ; symbol: J) is the unit of energy in the International System of Units (SI). It is equal to the amount of work done when a force of 1 newton displaces a mass through a distance of 1 metre in the direction of the force applie ...
per kilogram (J/kg). Other units still in use in some contexts are the
kilocalorie The calorie is a unit of energy. For historical reasons, two main definitions of "calorie" are in wide use. The large calorie, food calorie, or kilogram calorie was originally defined as the amount of heat needed to raise the temperature of on ...
per gram (Cal/g or kcal/g), mostly in food-related topics,
watt hour A kilowatt-hour ( unit symbol: kW⋅h or kW h; commonly written as kWh) is a unit of energy: one kilowatt of power for one hour. In terms of SI derived units with special names, it equals 3.6 megajoules (MJ). Kilowatt-hours are a common bi ...
s per kilogram in the field of batteries, and the
Imperial unit The imperial system of units, imperial system or imperial units (also known as British Imperial or Exchequer Standards of 1826) is the system of units first defined in the British Weights and Measures Act 1824 and continued to be developed thr ...
BTU The British thermal unit (BTU or Btu) is a unit of heat; it is defined as the amount of heat required to raise the temperature of one pound of water by one degree Fahrenheit. It is also part of the United States customary units. The modern SI u ...
per pound (Btu/lb), in some
engineering Engineering is the use of scientific principles to design and build machines, structures, and other items, including bridges, tunnels, roads, vehicles, and buildings. The discipline of engineering encompasses a broad range of more speciali ...
and applied technical fields. Kenneth E. Heselton (2004)
"Boiler Operator's Handbook"
Fairmont Press, 405 pages.
The concept of specific energy is related to but distinct from the notion of molar energy in chemistry, that is energy per
mole Mole (or Molé) may refer to: Animals * Mole (animal) or "true mole", mammals in the family Talpidae, found in Eurasia and North America * Golden moles, southern African mammals in the family Chrysochloridae, similar to but unrelated to Talpida ...
of a substance, which uses units such as joules per mole, or the older but still widely used calories per mole. Jerzy Leszczynski (2011)
"Handbook of Computational Chemistry"
Springer, 1430 pages.


Table of some non-SI conversions

The following table shows the factors for conversion to J/kg of some non-SI units: For a table giving the specific energy of many different fuels as well as batteries, see the article Energy density.


Ionising radiation

For
ionising radiation Ionizing radiation (or ionising radiation), including nuclear radiation, consists of subatomic particles or electromagnetic waves that have sufficient energy to ionize atoms or molecules by detaching electrons from them. Some particles can travel ...
, the
gray Grey (more common in British English) or gray (more common in American English) is an intermediate color between black and white. It is a neutral or achromatic color, meaning literally that it is "without color", because it can be composed o ...
is the SI unit of specific energy absorbed by matter known as absorbed dose, from which the SI unit the
sievert The sievert (symbol: SvNot be confused with the sverdrup or the svedberg, two non-SI units that sometimes use the same symbol.) is a unit in the International System of Units (SI) intended to represent the stochastic health risk of ionizing rad ...
is calculated for the stochastic health effect on tissues, known as
dose equivalent Equivalent dose is a dose quantity '' H '' representing the stochastic health effects of low levels of ionizing radiation on the human body which represents the probability of radiation-induced cancer and genetic damage. It is derived from the ...
. The
International Committee for Weights and Measures The General Conference on Weights and Measures (GCWM; french: Conférence générale des poids et mesures, CGPM) is the supreme authority of the International Bureau of Weights and Measures (BIPM), the intergovernmental organization established i ...
states: "In order to avoid any risk of confusion between the absorbed dose ''D'' and the
dose equivalent Equivalent dose is a dose quantity '' H '' representing the stochastic health effects of low levels of ionizing radiation on the human body which represents the probability of radiation-induced cancer and genetic damage. It is derived from the ...
''H'', the special names for the respective units should be used, that is, the name gray should be used instead of joules per kilogram for the unit of absorbed dose ''D'' and the name
sievert The sievert (symbol: SvNot be confused with the sverdrup or the svedberg, two non-SI units that sometimes use the same symbol.) is a unit in the International System of Units (SI) intended to represent the stochastic health risk of ionizing rad ...
instead of joules per kilogram for the unit of dose equivalent ''H''."


Energy density of food

Energy density is the amount of energy per mass or volume of food. The energy density of a food can be determined from the label by dividing the energy per serving (usually in
kilojoule The joule ( , ; symbol: J) is the unit of energy in the International System of Units (SI). It is equal to the amount of work done when a force of 1 newton displaces a mass through a distance of 1 metre in the direction of the force applied ...
s or food calories) by the serving size (usually in grams, milliliters or fluid ounces). Energy density is thus expressed in cal/g, kcal/g, J/g, kJ/g, cal/mL, kcal/mL, J/mL, or kJ/mL. The "calorie" commonly used in nutritional contexts is the kilocalorie (abbreviated "Cal" and sometimes called the "dietary calorie", "food calorie" or "Calorie" with a capital "C"). This is equivalent to a thousand calories (abbreviated "cal") or one kilocalorie (kcal). Because food energy is commonly measured in Calories, the energy density of food is commonly called "caloric density". Energy density measures the energy released when the food is
metabolized Metabolism (, from el, μεταβολή ''metabolē'', "change") is the set of life-sustaining chemical reactions in organisms. The three main functions of metabolism are: the conversion of the energy in food to energy available to run cell ...
by a healthy organism when it ingests the food (see
food energy Food energy is chemical energy that animals (including humans) derive from their food to sustain their metabolism, including their muscular activity. Most animals derive most of their energy from aerobic respiration, namely combining the carbohy ...
for calculation) and the food is metabolized with oxygen, into waste products such as
carbon dioxide Carbon dioxide ( chemical formula ) is a chemical compound made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature. In the air, carbon dioxide is trans ...
and water. Besides alcohol the only sources of food energy are
carbohydrate In organic chemistry, a carbohydrate () is a biomolecule consisting of carbon (C), hydrogen (H) and oxygen (O) atoms, usually with a hydrogen–oxygen atom ratio of 2:1 (as in water) and thus with the empirical formula (where ''m'' may or m ...
s,
fat In nutrition, biology, and chemistry, fat usually means any ester of fatty acids, or a mixture of such compounds, most commonly those that occur in living beings or in food. The term often refers specifically to triglycerides (triple est ...
s and
protein Proteins are large biomolecules and macromolecules that comprise one or more long chains of amino acid residues. Proteins perform a vast array of functions within organisms, including catalysing metabolic reactions, DNA replication, res ...
s, which make up ninety percent of the dry weight of food. Therefore,
water Water (chemical formula ) is an Inorganic compound, inorganic, transparent, tasteless, odorless, and Color of water, nearly colorless chemical substance, which is the main constituent of Earth's hydrosphere and the fluids of all known living ...
content is the most important factor in energy density. Carbohydrates provide four calories per gram (17 kJ/g), and proteins offer slightly less at 16kJ/g whereas fat provides nine calories per gram (38 kJ/g), times as much energy. Fats contain more carbon-carbon and carbon-hydrogen bonds than carbohydrates or proteins and are therefore richer in energy. Foods that derive most of their energy from fat have a much higher energy density than those that derive most of their energy from carbohydrates or proteins, even if the water content is the same. Nutrients with a lower absorption, such as
fiber Fiber or fibre (from la, fibra, links=no) is a natural or artificial substance that is significantly longer than it is wide. Fibers are often used in the manufacture of other materials. The strongest engineering materials often incorpora ...
or
sugar alcohol Sugar alcohols (also called polyhydric alcohols, polyalcohols, alditols or glycitols) are organic compounds, typically derived from sugars, containing one hydroxyl group (–OH) attached to each carbon atom. They are white, water-soluble solids ...
s, lower the energy density of foods as well. A moderate energy density would be 1.6 to 3 calories per gram (7–13 kJ/g); salmon, lean meat, and bread would fall in this category. High-energy foods would have more than three calories per gram and include crackers, cheese, dark chocolate, and peanuts.


Fuel

Energy density is sometimes useful for comparing fuels. For example,
liquid hydrogen Liquid hydrogen (LH2 or LH2) is the liquid state of the element hydrogen. Hydrogen is found naturally in the molecular H2 form. To exist as a liquid, H2 must be cooled below its critical point of 33  K. However, for it to be in a fully l ...
fuel has a higher specific energy (energy per unit mass) than
gasoline Gasoline (; ) or petrol (; ) (see ) is a transparent, petroleum-derived flammable liquid that is used primarily as a fuel in most spark-ignited internal combustion engines (also known as petrol engines). It consists mostly of organi ...
does, but a much lower volumetric energy density.


Astrodynamics

Specific mechanical energy, rather than simply energy, is often used in
astrodynamics Orbital mechanics or astrodynamics is the application of ballistics and celestial mechanics to the practical problems concerning the motion of rockets and other spacecraft. The motion of these objects is usually calculated from Newton's laws of ...
, because gravity changes the kinetic and potential specific energies of a vehicle in ways that are independent of the mass of the vehicle, consistent with the conservation of energy in a Newtonian gravitational system. The specific energy of an object such as a
meteoroid A meteoroid () is a small rocky or metallic body in outer space. Meteoroids are defined as objects significantly smaller than asteroids, ranging in size from grains to objects up to a meter wide. Objects smaller than this are classified as mi ...
falling on the earth from outside the earth's gravitational well is at least one half the square of the
escape velocity In celestial mechanics, escape velocity or escape speed is the minimum speed needed for a free, non- propelled object to escape from the gravitational influence of a primary body, thus reaching an infinite distance from it. It is typically ...
of 11.2 km/s. This comes to 63 MJ/kg (15 kcal/g, or 15 tonnes
TNT equivalent TNT equivalent is a convention for expressing energy, typically used to describe the energy released in an explosion. The is a unit of energy defined by that convention to be , which is the approximate energy released in the detonation of a ...
per tonne).
Comet A comet is an icy, small Solar System body that, when passing close to the Sun, warms and begins to release gases, a process that is called outgassing. This produces a visible atmosphere or coma, and sometimes also a tail. These phenomena ...
s have even more energy, typically moving with respect to the sun, when in our vicinity, at about the square root of two times the speed of the earth. This comes to 42 km/s, or a specific energy of 882 MJ/kg. The speed relative to the earth may be more or less, depending on direction. Since the speed of the earth around the sun is about 30 km/s, a comet's speed relative to the earth can range from 12 to 72 km/s, the latter corresponding to 2592 MJ/kg. If a comet with this speed fell to the earth it would gain another 63 MJ/kg, yielding a total of 2655 MJ/kg with a speed of 72.9 km/s. Since the equator is moving at about 0.5 km/s, the impact speed has an upper limit of 73.4 km/s, giving an upper limit for the specific energy of a comet hitting the earth of about 2690 MJ/kg. If the Hale-Bopp comet (50 km in diameter) had hit Earth, it would have vaporized the oceans and sterilized the surface of Earth.


Miscellaneous

*
Kinetic energy In physics, the kinetic energy of an object is the energy that it possesses due to its motion. It is defined as the work needed to accelerate a body of a given mass from rest to its stated velocity. Having gained this energy during its acc ...
per unit mass: ''v''2, where ''v'' is the speed (giving J/kg when ''v'' is in m/s). See also kinetic energy per unit mass of projectiles. * Potential energy with respect to gravity, close to earth, per unit mass: ''gh'', where ''g'' is the acceleration due to gravity (
standardized Standardization or standardisation is the process of implementing and developing technical standards based on the consensus of different parties that include firms, users, interest groups, standards organizations and governments. Standardization ...
as ≈9.8 m/s2) and ''h'' is the height above the reference level (giving J/kg when ''g'' is in m/s2 and ''h'' is in m). *
Heat In thermodynamics, heat is defined as the form of energy crossing the boundary of a thermodynamic system by virtue of a temperature difference across the boundary. A thermodynamic system does not ''contain'' heat. Nevertheless, the term is ...
: energies per unit mass are
specific heat capacity In thermodynamics, the specific heat capacity (symbol ) of a substance is the heat capacity of a sample of the substance divided by the mass of the sample, also sometimes referred to as massic heat capacity. Informally, it is the amount of heat t ...
times
temperature Temperature is a physical quantity that expresses quantitatively the perceptions of hotness and coldness. Temperature is measurement, measured with a thermometer. Thermometers are calibrated in various Conversion of units of temperature, temp ...
difference, and specific melting heat, and specific heat of vaporization


See also

* Energy density, which has tables of specific energies of devices and materials * Specific power * Heat of combustion *
Specific orbital energy In the gravitational two-body problem, the specific orbital energy \varepsilon (or vis-viva energy) of two orbiting bodies is the constant sum of their mutual potential energy (\varepsilon_p) and their total kinetic energy (\varepsilon_k), divide ...


References

* {{DEFAULTSORT:Specific Energy Energy (physics) Thermodynamic properties