Ooid
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Ooids are small (commonly ≤2 mm in diameter), spheroidal, "coated" (layered)
sedimentary Sedimentary rocks are types of rock that are formed by the accumulation or deposition of mineral or organic particles at Earth's surface, followed by cementation. Sedimentation is the collective name for processes that cause these particles ...
grains, usually composed of calcium carbonate, but sometimes made up of
iron Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in ...
- or
phosphate In chemistry, a phosphate is an anion, salt, functional group or ester derived from a phosphoric acid. It most commonly means orthophosphate, a derivative of orthophosphoric acid . The phosphate or orthophosphate ion is derived from phosph ...
-based minerals. Ooids usually form on the
sea floor The seabed (also known as the seafloor, sea floor, ocean floor, and ocean bottom) is the bottom of the ocean. All floors of the ocean are known as 'seabeds'. The structure of the seabed of the global ocean is governed by plate tectonics. Most of ...
, most commonly in shallow tropical seas (around the
Bahamas The Bahamas (), officially the Commonwealth of The Bahamas, is an island country within the Lucayan Archipelago of the West Indies in the North Atlantic. It takes up 97% of the Lucayan Archipelago's land area and is home to 88% of the a ...
, for example, or in the
Persian Gulf The Persian Gulf ( fa, خلیج فارس, translit=xalij-e fârs, lit=Gulf of Fars, ), sometimes called the ( ar, اَلْخَلِيْجُ ٱلْعَرَبِيُّ, Al-Khalīj al-ˁArabī), is a mediterranean sea in Western Asia. The bo ...
). After being buried under additional
sediment Sediment is a naturally occurring material that is broken down by processes of weathering and erosion, and is subsequently transported by the action of wind, water, or ice or by the force of gravity acting on the particles. For example, sand ...
, these ooid grains can be cemented together to form a
sedimentary rock Sedimentary rocks are types of rock that are formed by the accumulation or deposition of mineral or organic particles at Earth's surface, followed by cementation. Sedimentation is the collective name for processes that cause these particles ...
called an ''
oolite Oolite or oölite (''egg stone'') is a sedimentary rock formed from ooids, spherical grains composed of concentric layers. The name derives from the Ancient Greek word for egg (ᾠόν). Strictly, oolites consist of ooids of diameter 0.25 ...
''. Oolites usually consist of calcium carbonate; these belong to the
limestone Limestone ( calcium carbonate ) is a type of carbonate sedimentary rock which is the main source of the material lime. It is composed mostly of the minerals calcite and aragonite, which are different crystal forms of . Limestone forms w ...
rock family. Pisoids are similar to ooids, but are larger than 2 mm in diameter, often considerably larger, as with the pisoids in the hot springs at Carlsbad (
Karlovy Vary Karlovy Vary (; german: Karlsbad, formerly also spelled ''Carlsbad'' in English) is a spa city in the Karlovy Vary Region of the Czech Republic. It has about 46,000 inhabitants. It lies on the confluence of the rivers Ohře and Teplá. It is n ...
) in the
Czech Republic The Czech Republic, or simply Czechia, is a landlocked country in Central Europe. Historically known as Bohemia, it is bordered by Austria to the south, Germany to the west, Poland to the northeast, and Slovakia to the southeast. The ...
.


Formation

An ooid forms as a series of concentric layers around a nucleus. The layers contain crystals arranged radially, tangentially or randomly. The nucleus can be a shell fragment, quartz grain or any other small fragment. Most modern ooids are
aragonite Aragonite is a carbonate mineral, one of the three most common naturally occurring crystal forms of calcium carbonate, (the other forms being the minerals calcite and vaterite). It is formed by biological and physical processes, including pre ...
, a polymorph of calcium carbonate; some are composed of high-magnesium
calcite Calcite is a carbonate mineral and the most stable polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on the Mohs scale of mineral hardness, based on scratc ...
, and some are bimineralic (layers of calcite and aragonite). Ancient ooids can be calcitic, either originally precipitated as calcite (as in
calcite seas A calcite sea is a sea in which low-magnesium calcite is the primary inorganic marine calcium carbonate precipitate. An aragonite sea is the alternate seawater chemistry in which aragonite and high-magnesium calcite are the primary inorganic ca ...
), or formed by alteration (neomorphic replacement) of aragonitic ooids (or the aragonite layers in originally bimineralic ooids). Moldic ooids (or molds later filled in by calcite cement) occur in both young and ancient rocks, indicating the removal of a soluble polymorph (usually aragonite).


Variation

Whether ooids become calcitic or aragonitic can be linked to
strontium Strontium is the chemical element with the symbol Sr and atomic number 38. An alkaline earth metal, strontium is a soft silver-white yellowish metallic element that is highly chemically reactive. The metal forms a dark oxide layer when it is e ...
/
calcium Calcium is a chemical element with the symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar ...
substitution within the
crystalline structure In crystallography, crystal structure is a description of the ordered arrangement of atoms, ions or molecules in a crystalline material. Ordered structures occur from the intrinsic nature of the constituent particles to form symmetric patterns ...
. This has been shown in some examples to be due to temperature fluctuations in marine environments, which affects
salinity Salinity () is the saltiness or amount of salt (chemistry), salt dissolved in a body of water, called saline water (see also soil salinity). It is usually measured in g/L or g/kg (grams of salt per liter/kilogram of water; the latter is dimensio ...
levels, which in turn facilitate the substitution. Marine calcitic ooids were typically formed during
calcite sea A calcite sea is a sea in which low-magnesium calcite is the primary inorganic marine calcium carbonate precipitate. An aragonite sea is the alternate seawater chemistry in which aragonite and high-magnesium calcite are the primary inorganic ca ...
intervals, especially during the
Ordovician The Ordovician ( ) is a geologic period and system, the second of six periods of the Paleozoic Era. The Ordovician spans 41.6 million years from the end of the Cambrian Period million years ago (Mya) to the start of the Silurian Period Mya. T ...
and the
Jurassic The Jurassic ( ) is a geologic period and stratigraphic system that spanned from the end of the Triassic Period million years ago (Mya) to the beginning of the Cretaceous Period, approximately Mya. The Jurassic constitutes the middle period of ...
Periods. The geochemistry of these seas was a function of
seafloor spreading Seafloor spreading or Seafloor spread is a process that occurs at mid-ocean ridges, where new oceanic crust is formed through volcanic activity and then gradually moves away from the ridge. History of study Earlier theories by Alfred Wegener a ...
and fluctuating Mg/Ca ratios. Low Mg/Ca ratios favor the precipitation of low-magnesium calcite.


Growth mode

Ooids with radial crystals (such as the aragonitic ooids in the
Great Salt Lake The Great Salt Lake is the largest saltwater lake in the Western Hemisphere and the eighth-largest terminal lake in the world. It lies in the northern part of the U.S. state of Utah and has a substantial impact upon the local climate, particu ...
, Utah, US) grow by ions extending the lattices of the radial crystals. The mode of growth of ooids with tangential (usually minute needle-like) crystals is less clear. They may be accumulated in a "snowball" fashion from tiny crystals in the sediment or water, or they may crystallize in place on the ooid surface. A hypothesis of growth by accretion (like a snowball) from the polymineralic sediment of fine aragonite, high-magnesium calcite (HMC) and low-magnesium calcite (LMC), must explain how only aragonite needles are added to the ooid cortex. Both in tangential and in radial ooids, the cortex is composed of many very fine increments of growth. Some modern (and ancient) ooids partially or totally lack clear layering and have a micritic (very fine grained) texture. Examination of such micritic ooids by scanning electron microscopy often shows evidence of microbial borings later filled by fine cement.


Growth factors

There are several factors that affect ooid growth:
supersaturation In physical chemistry, supersaturation occurs with a solution (chemistry), solution when the concentration of a solute exceeds the concentration specified by the value of solubility at Solubility equilibrium, equilibrium. Most commonly the term ...
of the water with respect to calcium carbonate, the availability of nuclei, agitation of the ooids, water depth, and the role of microbes.


Ooimmuration

Sometimes
fossils A fossil (from Classical Latin , ) is any preserved remains, impression, or trace of any once-living thing from a past geological age. Examples include bones, shells, exoskeletons, stone imprints of animals or microbes, objects preserved ...
are included in ooids, often forming the nuclei. This
taphonomic Taphonomy is the study of how organisms decay and become fossilized or preserved in the paleontological record. The term ''taphonomy'' (from Greek , 'burial' and , 'law') was introduced to paleontology in 1940 by Soviet scientist Ivan Efremov t ...
process is termed ''ooimmuration'' (Wilson et al., 2021). The formation of the ooid cortex around the test or shell protects it from abrasion, fragmentation and bioerosion. Ooimmuration also retains fine organic remains that would ordinarily be winnowed away by currents.


References

Flügel, Erik (2010),
Microfacies of Carbonate Rocks: Analysis, Interpretation and Application
', 2nd ed.
Springer
pp. 242–244. . Accessed 2014-06-23. Wilson, M.A., Cooke, A.M., Judge, S.A. and Palmer, T.J. 2021. Ooimmuration: Enhanced fossil preservation by ooids, with examples from the Middle Jurassic of southwestern Utah, USA. ''Palaios'' 36: 326-329. https://doi.org/10.2110/palo.2021.036


External links

*{{webarchive , url=https://web.archive.org/web/20130620192517/http://www.geologyrocks.co.uk/tutorials/ooid_formation , date=20 June 2013 , title= Ooid Formation Sedimentary rocks Limestone Petrology