Oil shale in China
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Oil shale in China is an important source of unconventional oil. A total Chinese oil shale resource amounts of 720 billion tonnes, located in 80 deposits of 47 
oil shale Oil shale is an organic-rich fine-grained sedimentary rock containing kerogen (a solid mixture of organic chemical compounds) from which liquid hydrocarbons can be produced. In addition to kerogen, general composition of oil shales constitut ...
basins. This is equal to 48 billion tonnes of
shale oil Shale oil is an unconventional oil produced from oil shale rock fragments by pyrolysis, hydrogenation, or thermal dissolution. These processes convert the organic matter within the rock (kerogen) into synthetic oil and gas. The resulting oil c ...
. At the same time there are speculations that the actual resource may even exceed the oil shale resource of the United States. The
oil shale industry The oil shale industry is an industry of mining and processing of oil shale—a fine-grained sedimentary rock, containing significant amounts of kerogen (a solid mixture of organic chemical compounds), from which liquid hydrocarbons can be manu ...
was established in China already in the 1920s. After decrease in the production, the industry started to increase and as of 2008; several companies are engage in the shale oil production or the oil shale-based power generation. After 2005, China became the largest shale oil producer in the world. In 2011, the country produced about 650,000 tonnes of shale oil. Most of production facilities are Fushun-type retorts. At the end of 2006, the Fushun Shale Oil Plant was the largest oil shale plant in the world. In 2005, the China National Oil Shale Association was established in
Fushun Fushun (, formerly romanised as ''Fouchouen'', using French spelling, also as Fuxi ()) is a prefecture level city in Liaoning province, China, about east of Shenyang, with a total area of , of which is the city proper. Situated on the Hun Rive ...
. The main oil shale research institution in China is the
China University of Petroleum The China University of Petroleum () is a state Double First Class University in China. It consists of China University of Petroleum (Beijing), and China University of Petroleum (Huadong). Both are regarded as the best universities in China a ...
.


Reserves

From 2004 to 2006 China undertook the national oil shale evaluation. According to the evaluation, it has been estimated that a total Chinese oil shale resource amounts of 720 billion tonnes, located in 80 deposits of 47 oil shale basins. This is equal to 48 billion tonnes of shale oil. The proven oil shale reserves comprise about 36 billion tonnes. The principle Chinese reserves with commercial importance lie in Fushun (Liaoning), Maoming (Guangdong), Huadian and Nong'an (Jilin), and Longkou (Shandong). The Longkou deposit has the highest oil content (about 14%). The Fushun oil-shale and
coal Coal is a combustible black or brownish-black sedimentary rock, formed as rock strata called coal seams. Coal is mostly carbon with variable amounts of other elements, chiefly hydrogen, sulfur, oxygen, and nitrogen. Coal is formed when ...
deposit of
Eocene The Eocene ( ) Epoch is a geological epoch that lasted from about 56 to 33.9 million years ago (mya). It is the second epoch of the Paleogene Period in the modern Cenozoic Era. The name ''Eocene'' comes from the Ancient Greek (''ēṓs'', " ...
age is located in north-eastern China, south of Fushun, Liaoning. Coal and oil shale are in a small outlier of
Mesozoic The Mesozoic Era ( ), also called the Age of Reptiles, the Age of Conifers, and colloquially as the Age of the Dinosaurs is the second-to-last era of Earth's geological history, lasting from about , comprising the Triassic, Jurassic and Cretace ...
and
Tertiary Tertiary ( ) is a widely used but obsolete term for the geologic period from 66 million to 2.6 million years ago. The period began with the demise of the non-avian dinosaurs in the Cretaceous–Paleogene extinction event, at the start ...
sedimentary Sedimentary rocks are types of rock that are formed by the accumulation or deposition of mineral or organic particles at Earth's surface, followed by cementation. Sedimentation is the collective name for processes that cause these particles ...
and
volcanic rock Volcanic rock (often shortened to volcanics in scientific contexts) is a rock formed from lava erupted from a volcano. In other words, it differs from other igneous rock by being of volcanic origin. Like all rock types, the concept of volcanic ...
s underlain by Precambrian granitic
gneiss Gneiss ( ) is a common and widely distributed type of metamorphic rock. It is formed by high-temperature and high-pressure metamorphic processes acting on formations composed of igneous or sedimentary rocks. Gneiss forms at higher temperatures a ...
. The thickness of the layer of oil shale varies from to with the average of . The
lacustrine A lake is an area filled with water, localized in a basin, surrounded by land, and distinct from any river or other outlet that serves to feed or drain the lake. Lakes lie on land and are not part of the ocean, although, like the much larger ...
origin oil shale is presented in the Jijuntun Formation, overlying the Guchengzi Formation consisting coal and underlying of green mudstone of the Xilutian Formation. The Tertiary age Maoming oil-shale deposit is long, wide, and to thick. The ore is yellow brown and the bulk density is about 1.85. The oil shale contains 72.1% ash, 10.8%
moisture Moisture is the presence of a liquid, especially water, often in trace amounts. Small amounts of water may be found, for example, in the air (humidity), in foods, and in some commercial products. Moisture also refers to the amount of water vapo ...
, 1.2% sulfur, with a heating value of 1,745 kcal/kg (
dry basis Dry basis is an expression of the calculation in chemistry, chemical engineering and related subjects, in which the presence of water (and/or other solvents) is neglected for the purposes of the calculation. Water (and/or other solvents) is neglect ...
). It is not suitable for above-ground retorting, but it could be used for a power generation by a
fluidized bed combustion Fluidized bed combustion (FBC) is a combustion technology used to burn solid fuels. In its most basic form, fuel particles are suspended in a hot, bubbling fluidity bed of ash and other particulate materials (sand, limestone etc.) through which ...
. Professor Alan R. Carroll of
University of Wisconsin–Madison A university () is an institution of higher (or tertiary) education and research which awards academic degrees in several academic disciplines. Universities typically offer both undergraduate and postgraduate programs. In the United Stat ...
estimates that Upper
Permian The Permian ( ) is a geologic period and System (stratigraphy), stratigraphic system which spans 47 million years from the end of the Carboniferous Period million years ago (Mya), to the beginning of the Triassic Period 251.9 Mya. It is the last ...
lacustrine oil shale deposits of the Junggar-
Turpan Turpan (also known as Turfan or Tulufan, , ug, تۇرپان) is a prefecture-level city located in the east of the autonomous region of Xinjiang, China. It has an area of and a population of 632,000 (2015). Geonyms The original name of the cit ...
-
Hami Hami (Kumul) is a prefecture-level city in Eastern Xinjiang, China. It is well known as the home of sweet Hami melons. In early 2016, the former Hami county-level city was merged with Hami Prefecture to form the Hami prefecture-level city with t ...
basins in northwest China, absent from previous global oil shale assessments, are comparable to the
Green River Formation The Green River Formation is an Eocene geologic formation that records the sedimentation in a group of intermountain lakes in three basins along the present-day Green River in Colorado, Wyoming, and Utah. The sediments are deposited in very fine ...
.


History

The extraction of oil shale in China began in 1926 under the Japanese rule. The commercial-scale production of shale oil began in 1930 in Fushun,
Manchuria Manchuria is an exonym (derived from the endo demonym " Manchu") for a historical and geographic region in Northeast Asia encompassing the entirety of present-day Northeast China (Inner Manchuria) and parts of the Russian Far East (Outer M ...
, with the construction of the "Refinery No. 1" operating Fushun-type retorts. After World War II, the shale oil production was ceased, but 100 Fushun-type oil shale retorts and the related shale oil processing units were restored in 1949 after the founding of the People’s Republic of China. In 1950, total 266 retorts were in operation, each with the capacity of 100–200 tonnes shale oil per day. In 1954, the "Refinery No. 2" began its production and in 1959, the maximum annual shale oil production increased to 780,000 tonnes. The produced shale oil was acid and alkaline washed and hydrotreated for producing light liquid fuels. In 1961, China was producing one third of its total oil production from oil shale. In Maoming, Guangdong Province, a new oil shale retorting plant with 64 retorts was put into operation in 1963. Since 1965, oil shale usage in Fushun started to decline. With the discovery of
Daqing oilfield The Daqing Oil Field (), formerly romanized as "Taching", is the largest oil field in the People's Republic of China, located between the Songhua river and Nen River in Heilongjiang province. When the Chinese government began to use to pinyin for ...
in the 1960s, the shale oil production declined and
Sinopec China Petroleum & Chemical Corporation (中国石油化工股份有限公司) or Sinopec (), is a Chinese oil and gas enterprise based in Beijing. It is listed in Hong Kong and also trades in Shanghai. Sinopec Limited's parent, Sinopec ...
, an operator of shale oil production these times, shut down its oil shale operations in the beginning of the 1990s. At the same time, the Fushun Oil Shale Retorting Plant was established as a part of the
Fushun Mining Group Fushun Mining Group (, FMG) is a large state-owned coal and oil shale company located in Fushun, Liaoning Province, China. The corporation consists of about 30 companies with about 28,000 employees. The main business includes coal mi ...
. It started production in 1992. In 2005, China became the largest shale oil producer in the world. At the same year, China National Oil Shale Association was established in Fushun.


Industry

The major oil shale industry in China is the Fushun Mining Group. Several other coal and oil companies have expanded their activities into oil shale extraction. , there were seven shale retorting plants with a total production of 650,000 tonnes of shale oil. These plants located in Fushun, Huadian,
Wangqing Wangqing County (; 현) is a county of southeastern Jilin province, China. It is under the administration of the Yanbian Korean Autonomous Prefecture. The county's name Wangqing comes from the Manchu language meaning ''fortress''. Administrative ...
, Beipiao, Longkou, Yaojie, and Dongning. Most of them use Fushun retorts or modified Fushun retorts.


Fushun Mining Group

Fushun Mining Group owns geological reserve for high grade oil shale about 3.6 billion tonnes, of which exploitable reserve is 920 million tonnes, divided between East Open Pit (760 million tonnes) and West Open Pit (160 million tonnes). The oil shale production uses reserves from the West Open Pit, while the East Open Pit oil shale reserves are not mined yet. Oil shale is produced as a byproduct of the coal mining. In 2006, Fushun Mining Group produced 240,000 tonnes of shale oil, and was expected to produce 300,000 tonnes in 2007. The company operates the largest oil shale retorting plant in the world. In 2011, it had two oil shale retorting plants with 120 and 100 retorts, producing annually about 350,000 tonnes of shale oil. In addition, the company has constructed the Alberta Taciuk processor to treat small size oil shale (particulate oil shale) which can't be processed in Fushun retort. The 250 tonnes per hour ATP processor was engineered and provided by Canadian company UMATAC Industrial Processes, a subsidiary of UMA Engineering Ltd. The processor is in the cold testing phase. The cost of shale oil production in Fushun is US$18.46 per barrel (1,500 yuan per tonne), of which the mining costs 0.184, transportation 4.25, and retorting 13.84. Fushun shale oil is sold as fuel oil, while part of the surplus retort gas with low heating value is used in an internal combustion engine for producing steam and power.
Spent shale Spent shale or spent oil shale (also known as retorted shale) is a solid residue from the shale oil extraction process of producing synthetic shale oil from oil shale. It consists of inorganic compounds (minerals) and remaining organic matter kno ...
and shale ash is used for the cement production; the annual production of cement is 300,000 tonnes and the annual production of bricks is 240 million.


PetroChina

In 2006, PetroChina, the largest Chinese oil company, set up a department of New Sources of Energy, which is responsible for the oil shale development. In August 2008, its subsidiary Daqing Oil Company started to build a shale oil plant in
Mudanjiang Mudanjiang (; Manchu: ''Mudan bira''), alternately romanized as Mutankiang, is a prefecture-level city in the southeast part of Heilongjiang province, People's Republic of China. It was called ''Botankou'' under Japanese occupation. It serves as ...
,
Heilongjiang Heilongjiang () formerly romanized as Heilungkiang, is a province in northeast China. The standard one-character abbreviation for the province is (). It was formerly romanized as "Heilungkiang". It is the northernmost and easternmost province ...
. The plant is designed to process 1.2 million tonnes of oil shale per year and produce 100,000 tonnes of shale oil. It will use solid heat carrier technology.


Maoming

Maoming oil shale industry was developed from the 1960s to the 1990s by Maoming Petrochemical Company, a subsidiary of Sinopec, which built 64 Fushun-type retorts and 48 gas combustion retorts for producing shale oil. The production peaked with 180,000 tonnes of shale oil per annum. This industry was shut down in the 1990s. The Guandong Province authorities have a plan to use the Maoming oil shale for the power production using fluidized bed combustion. In 2008, one circulating fluidized-bed boiler was constructed. Guangdong Electricity Company has plans to build a power station with capacity of 1,200 MW.


Longkou Mining Group

Longkou Mining Group, subsidiary of Shandong Energy, produces oil shale as a coal mining byproduct. It operates shale oil plant which is equipped with 40 Fushun retorts. The shale oil production is about 120,000 tonnes per year and the planned full capacity is 200,000 tonnes of shale oil per year. The company also plans to utilize Enefit-280 technology. In addition, the company plans to burn shale char mixed with particulate oil shale in fluidized bed combustion for power generation, and the shale ash would be utilized for production of building material.


Jilin Energy & Communication Corporation

In 1996, Jilin Energy & Communication Corporation, a subsidiary of the
China Power Investment Corporation China Power Investment Corporation also known as CPI Group was one of the five largest state-owned electricity producers in mainland China. It was administrated by the State-owned Assets Supervision and Administration Commission (SASAC) of the ...
, put into operation the first oil-shale-fired power plant in China, consisting of three circulating fluidized-bed units with capacity of 12 megawatts (MW). In 2005, the company in cooperation with the
Jilin Jilin (; alternately romanized as Kirin or Chilin) is one of the three provinces of Northeast China. Its capital and largest city is Changchun. Jilin borders North Korea ( Rasŏn, North Hamgyong, Ryanggang and Chagang) and Russia (Prim ...
Municipal Government put forward the Huadian oil shale comprehensive utilization project. The project includes construction of the shale oil plant with capacity of 200,000 tonnes of shale oil per year, two circulated fluidized bed combustion units with capacity of 50 MW each and production of 1.2 million tonnes of
cement A cement is a binder, a chemical substance used for construction that sets, hardens, and adheres to other materials to bind them together. Cement is seldom used on its own, but rather to bind sand and gravel ( aggregate) together. Cement mi ...
and other building materials utilizing spent shale and shale ash. The shale oil plant will utilize the Petrosix technology.


Royal Dutch Shell

Shell China has established a joint venture with the Jilin Guangzheng Mineral Development Company Limited to explore and develop oil shale resources in Jilin Province. 61% of shares of the joint venture, Jilin Shell Oil Shale Development Company Limited (Jilin Shell), belongs to Shell China, while 39% is owned by Jilin Guangzheng. The company is planning to use the Shell's '' in-situ'' conversion process.


Wangqing County Longteng Energy Development Co.

Privately owned Wangqing County Longteng Energy Development Co. operates a shale oil plant in Wangqing, Jilin. The plant is equipped with 40 Fushun-type retorts, and it produces about 50,000 tonnes of shale oil per year. In 2009, the company also commissioned an oil shale power plant which is equipped with two
circulating fluidized bed The circulating fluidized bed (CFB) is a type of Fluidized bed combustion that utilizes a recirculating loop for even greater efficiency of combustion. while achieving lower emission of pollutants. Reports suggest that up to 95% of pollutants Ci ...
. The plant has capacity of 6 MW of electricity.


Other industries

In Beipiao, Liaoning, the Beipiao Coal Mining Company operates 60 Fushun-type retort with plans to open additional 24 retorts in 2012. Yaojie Coal Electricity Group in cooperating with Sanjiang Coal Chemical Company opened shale oil plant in July 2010 in Lanzhou, Gansu. The plant consist of eight square-shaped gas combustion retorts. Longhua Harbin Coal Chemical Industry Company, a subsidiary of China National Coal Corporation, is preparing to build a shale oil plant with the capacity of 1,000 tonnes of shale oil per day in
Yilan Yilan may refer to: China * Yilan County, Heilongjiang (依兰县), county of central Heilongjiang province, People's Republic of China * Yilan Town, Heilongjiang (依兰镇), seat of Yilan County * Yilan, Jilin (依兰镇), town in Yanji Taiwan ...
, Heilongjiang. The plant will use hot recycled solids technology combined with fluidized bed retort. Similar plant is planned by the Songyasan Coal Mining Company. The Mingxin Mining Company is planning to co-produce coal and oil shale in Mingxin, Gansu Province. The planned shale oil plant would have a capacity of 400,000 tonnes of shale oil per year. In addition, five private companies produce about 30,000 tonnes of shale oil by utilizing the Fushun-type retorts in Jilin. Liaoning Chengda is operating 12 modified Fushun retorts in Huadian, Jilin, and is building 24modified Fushun retorts in
Jimsar County Jimsar County is a county in Changji Hui Autonomous Prefecture, Xinjiang, China. It contains an area of . According to the 2002 census, it has a population of 130,000. Near the town of Jimsar are the ruins of the ancient city of Beiting () or Tin ...
,
Xinjiang Xinjiang, SASM/GNC: ''Xinjang''; zh, c=, p=Xīnjiāng; formerly romanized as Sinkiang (, ), officially the Xinjiang Uygur Autonomous Region (XUAR), is an autonomous region of the People's Republic of China (PRC), located in the northwest ...
. Other potential industries could be start in Uromqi (Xinjiang), Yongden (Gansu), and Chanpo (
Hainan Hainan (, ; ) is the smallest and southernmost province of the People's Republic of China (PRC), consisting of various islands in the South China Sea. , the largest and most populous island in China,The island of Taiwan, which is slightly l ...
).


Research

The main oil shale research institution in China is the China University of Petroleum. Its Applied Chemistry Department is the main institution dealing with oil shale. The university's oil shale experts undertake oil shale evaluation, consulting, and reviewing work for pre-feasibility and feasibility studies and development projects for domestic and foreign countries. e.g. Mongolia.


References

{{Energy in the People's Republic of China Geology of China Mining in China Petroleum in China