Nitrogen monofluoride (fluoroimidogen) is a metastable species that has been observed in laser studies. It is isoelectronic with O₂. Like

boron monofluoride Boron monofluoride or fluoroborylene is a chemical compound with formula BF, one atom of boron and one of fluorine. It was discovered as an unstable gas and only in 2009 found to be a stable ligand combining with transition metals, in the same w ...

, it is an instance of the rare multiply-bonded fluorine atom. It is unstable with respect to its formal dimer,

dinitrogen difluoride Dinitrogen difluoride is a chemical compound with the formula N2F2. It is a gas at room temperature, and was first identified in 1952 as the thermal decomposition product of the azide N3F. It has the structure F−N=N−F and exists in both a ' ...

, as well as to its elements,

nitrogen Nitrogen is the chemical element with the symbol N and atomic number 7. Nitrogen is a nonmetal and the lightest member of group 15 of the periodic table, often called the pnictogens. It is a common element in the universe, estimated at se ...

and

fluorine Fluorine is a chemical element with the symbol F and atomic number 9. It is the lightest halogen and exists at standard conditions as a highly toxic, pale yellow diatomic gas. As the most electronegative reactive element, it is extremely reacti ...

. Nitrogen monofluoride is produced when

radical Radical may refer to: Politics and ideology Politics *Radical politics, the political intent of fundamental societal change *Radicalism (historical), the Radical Movement that began in late 18th century Britain and spread to continental Europe and ...

species (H, O, N, CH₃) abstract a fluorine atom from nitrogen difluoride (NF₂). Stoichiometrically, the reaction is extremely efficient, regenerating a radical for long-lasting

chain propagation Chain propagation (sometimes referred to as propagation) is a process in which a reactive intermediate is continuously regenerated during the course of a chemical chain reaction. For example, in the chlorination of methane, there is a two-step p ...

. However, radical impurities in the end product also catalyze that product's decomposition.

Azide In chemistry, azide is a linear, polyatomic anion with the formula and structure . It is the conjugate base of hydrazoic acid . Organic azides are organic compounds with the formula , containing the azide functional group. The dominant applic ...

decomposition offers a less-efficient but more pure technique:

fluorine azide Fluorine azide or triazadienyl fluoride is a yellow green gas composed of nitrogen and fluorine with formula . It is counted as an interhalogen compound, as the azide functional group is termed a pseudohalogen. It resembles , , and in this resp ...

(which can be formed ''in situ'' via reaction of atomic fluorine with hydrazoic acid) decomposes upon shock into NF and N₂. Many NF-producing reactions give the product in an

excited state In quantum mechanics, an excited state of a system (such as an atom, molecule or nucleus) is any quantum state of the system that has a higher energy than the ground state (that is, more energy than the absolute minimum). Excitation refers to a ...

with characteristic

chemiluminescence Chemiluminescence (also chemoluminescence) is the emission of light (luminescence) as the result of a chemical reaction. There may also be limited emission of heat. Given reactants A and B, with an excited intermediate ◊, : + -> lozenge -> ...

. They have thus been investigated for development as a

chemical laser A chemical laser is a laser that obtains its energy from a chemical reaction. Chemical lasers can reach continuous wave output with power reaching to megawatt levels. They are used in industry for cutting and drilling. Common examples of chemical ...

References

{{Fluorides Nitrogen fluorides Nitrogen compounds