Nils Johan Berlin
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Nils Johan Berlin (Nils Johannes Berlin) (18 February 1812 – 27 December 1891) was a
Swedish Swedish or ' may refer to: Anything from or related to Sweden, a country in Northern Europe. Or, specifically: * Swedish language, a North Germanic language spoken primarily in Sweden and Finland ** Swedish alphabet, the official alphabet used by ...
chemist A chemist (from Greek ''chēm(ía)'' alchemy; replacing ''chymist'' from Medieval Latin ''alchemist'') is a scientist trained in the study of chemistry. Chemists study the composition of matter and its properties. Chemists carefully describe th ...
and physician, who held various professorships at the
University of Lund , motto = Ad utrumque , mottoeng = Prepared for both , established = , type = Public research university , budget = SEK 9 billion general public In public relations and communication science, publics are groups of individual people, and the public (a.k.a. the general public) is the totality of such groupings. This is a different concept to the sociological concept of the ''Öffentlic ...
. His chemistry research emphasized the study of
minerals In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed ...
, especially the newly-discovered
rare earths The rare-earth elements (REE), also called the rare-earth metals or (in context) rare-earth oxides or sometimes the lanthanides (yttrium and scandium are usually included as rare earths), are a set of 17 nearly-indistinguishable lustrous silve ...
, having devised means of separating
yttrium Yttrium is a chemical element with the symbol Y and atomic number 39. It is a silvery-metallic transition metal chemically similar to the lanthanides and has often been classified as a " rare-earth element". Yttrium is almost always found in co ...
and
erbium Erbium is a chemical element with the symbol Er and atomic number 68. A silvery-white solid metal when artificially isolated, natural erbium is always found in chemical combination with other elements. It is a lanthanide, a rare-earth element, ...
. The mineral
berlinite Berlinite ( aluminium phosphate, chemical formula AlPO4 or Al(PO4)) is a rare high-temperature hydrothermal or metasomatic phosphate mineral. It has the same crystal structure as quartz with a low temperature polytype isostructural with α–quar ...
(a type of
aluminium phosphate Aluminium phosphate is a chemical compound. In nature it occurs as the mineral berlinite. Many synthetic forms of aluminium phosphate are known. They have framework structures similar to zeolites and some are used as catalysts, ion-exchangers or ...
) is named after him. Berlin became a member of the
Royal Swedish Academy of Sciences The Royal Swedish Academy of Sciences ( sv, Kungliga Vetenskapsakademien) is one of the royal academies of Sweden. Founded on 2 June 1739, it is an independent, non-governmental scientific organization that takes special responsibility for prom ...
in 1844.


Education

Berlin graduated from the
University of Uppsala Uppsala University ( sv, Uppsala universitet) is a public research university in Uppsala, Sweden. Founded in 1477, it is the oldest university in Sweden and the Nordic countries still in operation. The university rose to significance during ...
with a
doctor of philosophy A Doctor of Philosophy (PhD, Ph.D., or DPhil; Latin: or ') is the most common degree at the highest academic level awarded following a course of study. PhDs are awarded for programs across the whole breadth of academic fields. Because it is ...
in 1833, having studied under the tutelage of
Jöns Jacob Berzelius Baron Jöns Jacob Berzelius (; by himself and his contemporaries named only Jacob Berzelius, 20 August 1779 – 7 August 1848) was a Swedish chemist. Berzelius is considered, along with Robert Boyle, John Dalton, and Antoine Lavoisier, to be o ...
. He completed a
doctor of medicine Doctor of Medicine (abbreviated M.D., from the Latin ''Medicinae Doctor'') is a medical degree, the meaning of which varies between different jurisdictions. In the United States, and some other countries, the M.D. denotes a professional degree. ...
degree in 1837, also at the University of Uppsala.


Academic career

Berlin held a number of faculty positions at the
University of Lund , motto = Ad utrumque , mottoeng = Prepared for both , established = , type = Public research university , budget = SEK 9 billion pharmacology Pharmacology is a branch of medicine, biology and pharmaceutical sciences concerned with drug or medication action, where a drug may be defined as any artificial, natural, or endogenous (from within the body) molecule which exerts a biochemica ...
. Subsequently he also became a professor of chemistry and mineralogy in 1847, then rector of the university, 1854-1855, and lastly professor of medical and physiological chemistry in 1862. He served as the Director of the National Board of Hygiene (''Sundhetskollegiet'') beginning in 1864.


Elementary science textbooks

Berlin was the first chemist to write a textbook for elementary science for the general population. Berlin published two popular textbooks, which emphasized description and practical knowledge over theory (of which there was relatively little at the time). ''Vext-chemien i sammandrag'' was published in 1835, and ''Elementar-lärobok i oorganisk kemi'' first appeared in 1857. It went through 15 editions, selling more than 450,000 copies. His textbooks helped to catalyze the teaching of science in elementary schools. They received praise and an award from the Swedish parliament, and were translated into German and Finnish. The third edition of Berlin's textbook, which appeared in 1870, was heavily revised by
Christian Wilhelm Blomstrand Christian Wilhelm Blomstrand (20 October 1826 – 5 November 1897) was a Swedish mineralogist and chemist. He was a professor at the University of Lund from 1862-1895, where he isolated the element niobium in 1864. He developed an early version ...
, who added his own systematization of the elements. Berlin's father was a
vicar A vicar (; Latin: '' vicarius'') is a representative, deputy or substitute; anyone acting "in the person of" or agent for a superior (compare "vicarious" in the sense of "at second hand"). Linguistically, ''vicar'' is cognate with the English pre ...
. Berlin himself stated in his will that "Science and the thorough testing of its problems and results has never given me reason to doubt the truths of religion". As a scientist, and as a
popularizer of science ''Popular Science'' (also known as ''PopSci'') is an American digital magazine carrying popular science content, which refers to articles for the general reader on science and technology subjects. ''Popular Science'' has won over 58 awards, inclu ...
, Berlin situated scientific knowledge securely on a religious basis. This may have been an advantage when selling elementary science textbooks, since pastors often led the local school boards that chose the textbooks for their schools.


Research on rare earth elements

In 1787
Carl Axel Arrhenius Carl Axel Arrhenius (29 March 1757 – 20 November 1824) was an officer in the Swedish army as well as an amateur geologist and chemist. He is best known for his discovery of the mineral ytterbite (later called gadolinite) in 1787. The disc ...
found a dark mineral in a
feldspar Feldspars are a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the ''plagioclase'' (sodium-calcium) felds ...
mine in the village of
Ytterby Ytterby () is a village on the Swedish island of Resarö, in Vaxholm Municipality in the Stockholm archipelago. Today the residential area is dominated by suburban homes. The name of the village translates to "outer village". Ytterby is per ...
,
Sweden Sweden, formally the Kingdom of Sweden,The United Nations Group of Experts on Geographical Names states that the country's formal name is the Kingdom of SwedenUNGEGN World Geographical Names, Sweden./ref> is a Nordic countries, Nordic c ...
. He sent a sample of this ytterbite to
Johan Gadolin Johan Gadolin (5 June 176015 August 1852) was a Finnish chemist, physicist and mineralogist. Gadolin discovered a " new earth" containing the first rare-earth compound yttrium, which was later determined to be a chemical element. He is also ...
for further analysis. A number of researchers tried to identify elements composing the ore, which were particularly hard to separate due to their similar chemical properties. As a group, they were given the misnomer
rare-earth elements The rare-earth elements (REE), also called the rare-earth metals or (in context) rare-earth oxides or sometimes the lanthanides (yttrium and scandium are usually included as rare earths), are a set of 17 nearly-indistinguishable lustrous silve ...
. (In fact, they are not rare, just difficult to extract.) Individually, they were discovered and named by various scientists, often using variants based on the word "Ytterby". The first two ores to be derived were called ceria and yttria. In the 1830s and 40s,
Carl Gustav Mosander Carl Gustaf Mosander (10 September 1797 – 15 October 1858) was a Swedish chemist. He discovered the rare earth elements lanthanum, erbium and terbium. Early life and education Born in Kalmar, Mosander attended school there until he move ...
derived several substances from these known ores. In 1843 Mosander was able to extract three metal oxides from ytteria, a whitish "earth" which he called pure ytteria, a pink or rose-colored oxide which he called terbia, and a yellowish
peroxide In chemistry, peroxides are a group of compounds with the structure , where R = any element. The group in a peroxide is called the peroxide group or peroxo group. The nomenclature is somewhat variable. The most common peroxide is hydrogen p ...
which he called
erbia Erbium(III) oxide is the inorganic compound with the formula . It is a pink paramagnetic solid. It finds uses in various optical materials. Structure Erbium(III) oxide has a cubic structure resembling the bixbyite motif. The Er3+ centers are o ...
. Mosander was rightfully uncertain of their purity; they did however contain the elements
yttrium Yttrium is a chemical element with the symbol Y and atomic number 39. It is a silvery-metallic transition metal chemically similar to the lanthanides and has often been classified as a " rare-earth element". Yttrium is almost always found in co ...
,
erbium Erbium is a chemical element with the symbol Er and atomic number 68. A silvery-white solid metal when artificially isolated, natural erbium is always found in chemical combination with other elements. It is a lanthanide, a rare-earth element, ...
, and
terbium Terbium is a chemical element with the symbol Tb and atomic number 65. It is a silvery-white, rare earth metal that is malleable, and ductile. The ninth member of the lanthanide series, terbium is a fairly electropositive metal that reacts with w ...
. Like scientists before him such as Mosander and Arrhenius, Berlin also worked on separation of ytteria ore into its constituent compounds. In 1860, Berlin successfully reported the identification of two substances, yttrium, and a pink salt which Berlin named erbium. Subsequent chemists followed Berlin's designation rather than Mosander's. The naming of ytteria's components became further complicated in 1862, when Marc Delafontaine reported its separation into yttrium and a yellow peroxide, which he first called mosandrum (after Mosander) and later terbium. In this way, the names originally given to erbium and terbium became switched.


References


External links


Nils Johan Berlin

Nils Johan Berlin
{{DEFAULTSORT:Berlin, Nils Johan 1812 births 1891 deaths Swedish chemists Academic staff of Lund University Members of the Royal Swedish Academy of Sciences Rare earth scientists