Neste Renewable Diesel
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Neste Renewable Diesel (formerly NExBTL) is a vegetable oil refining fuel production process commercialized by the Finnish oil and refining company Neste. Whether as an admixture or in its pure form, Neste Renewable Diesel is able to supplement or partially replace diesel fuel without problems. Unblended Neste Renewable Diesel meets the requirements set by the European standard EN 15940. Fuel blends meet the European diesel fuel standard EN 590. Despite the former name BTL, the feedstock is
vegetable oil Vegetable oils, or vegetable fats, are oils extracted from seeds or from other parts of fruits. Like animal fats, vegetable fats are ''mixtures'' of triglycerides. Soybean oil, grape seed oil, and cocoa butter are examples of seed oils, or f ...
and waste animal fats, not whole plants. However, fuel quality is equal to the synthetic Fischer-Tropsch BTL and GTL diesel fuels.


Process

Neste Renewable Diesel is produced in a patented vegetable oil refining process. Chemically, it entails direct catalytic
hydrodeoxygenation Hydrodeoxygenation (HDO) is a hydrogenolysis process for removing oxygen from oxygen-containing compounds. Typical HDO catalysts commonly are sulfided nickel-molybdenum or cobalt-molybdenum on gamma alumina. An idealized reaction is: :R2O + 2 H2 ...
( hydrogenolysis) of plant oils, which are
triglyceride A triglyceride (TG, triacylglycerol, TAG, or triacylglyceride) is an ester derived from glycerol and three fatty acids (from ''tri-'' and ''glyceride''). Triglycerides are the main constituents of body fat in humans and other vertebrates, as ...
s, into the corresponding
alkane In organic chemistry, an alkane, or paraffin (a historical trivial name that also has other meanings), is an acyclic saturated hydrocarbon. In other words, an alkane consists of hydrogen and carbon atoms arranged in a tree structure in wh ...
s and
propane Propane () is a three-carbon alkane with the molecular formula . It is a gas at standard temperature and pressure, but compressible to a transportable liquid. A by-product of natural gas processing and petroleum refining, it is commonly used as ...
. The glycerol chain of the triglyceride is hydrogenated to the corresponding C3 alkane,
propane Propane () is a three-carbon alkane with the molecular formula . It is a gas at standard temperature and pressure, but compressible to a transportable liquid. A by-product of natural gas processing and petroleum refining, it is commonly used as ...
— there is no
glycerol Glycerol (), also called glycerine in British English and glycerin in American English, is a simple triol compound. It is a colorless, odorless, viscous liquid that is sweet-tasting and non-toxic. The glycerol backbone is found in lipids known ...
sidestream. This process removes oxygen from the oil; the diesel is not an oxygenate like traditional transesterified FAME
biodiesel Biodiesel is a form of diesel fuel derived from plants or animals and consisting of long-chain fatty acid esters. It is typically made by chemically reacting lipids such as animal fat ( tallow), soybean oil, or some other vegetable oi ...
. Catalytic isomerization into branched alkanes is then done to adjust the cloud point in order to meet winter operability requirements. As it is chemically identical to ideal conventional diesel, it requires no modification or special precautions for the engine.


Production

Two refineries in Porvoo, Finland were brought on stream in 2007 and 2009, each with a capacity of 0.2 million tons per year. Two larger refineries, with annual production of 0.8 million tons both, were brought on stream in
Singapore Singapore (), officially the Republic of Singapore, is a sovereign island country and city-state in maritime Southeast Asia. It lies about one degree of latitude () north of the equator, off the southern tip of the Malay Peninsula, bor ...
and
Rotterdam Rotterdam ( , , , lit. ''The Dam on the River Rotte (river), Rotte'') is the second largest List of cities in the Netherlands by province, city and List of municipalities of the Netherlands, municipality in the Netherlands. It is in the Prov ...
in 2010 and 2011, respectively.


Emissions

Neste has estimated that the use of NExBTL diesel cuts greenhouse gas emissions by 40 to 90 percent in comparison to fossil based diesel. Due to the chemistry of the process, the renewable diesel is pure
alkane In organic chemistry, an alkane, or paraffin (a historical trivial name that also has other meanings), is an acyclic saturated hydrocarbon. In other words, an alkane consists of hydrogen and carbon atoms arranged in a tree structure in wh ...
and contains no aromatics, oxygen (although oxygen would have promoted cleaner combustion) or sulfur.


Cloud point

The
cloud point In liquids, the cloud point is the temperature below which a transparent solution undergoes either a liquid-liquid phase separation to form an emulsion or a liquid-solid phase transition to form either a stable sol or a suspension that settles a ...
(or gel point) can be adjusted down to −40 °C (−40 °F) during the manufacturing process, compared to petrodiesel's cloud point of −30 °C (−22 °F), which could improve the cloud point of diesel when blended. The cloud point is the temperature when the wax precipitates out of the fuel in the form of small wax crystals, making the fuel cloudy and more difficult to move within the fuel lines and systems of vehicles. The lower the cloud point of a particular fuel is, the more suitable it is in colder environments.


Feedstocks

A mix of palm oil, rapeseed oil, and waste fat from the food industry can be used. Initially,
palm oil Palm oil is an edible vegetable oil derived from the mesocarp (reddish pulp) of the fruit of the oil palms. The oil is used in food manufacturing, in beauty products, and as biofuel. Palm oil accounted for about 33% of global oils produced fr ...
was the principal (90%) feedstock, although its share was reduced to 53% by 2013 and to less than 20% by 2017. However, the EU biofuels industry has increased its use of palm oil by 365% during the years 2006–2012, from 0.4 to 1.9 million tonnes per year, and the trend is increasing. Also note that categorising Palm Fatty Acid Distillate, PFAD, as waste is controversial since it can be used to make e.g. soap, candles and animal fodder. In the UK PFAD is classified as a bi-product). PFAD is also omitted from sustainability requirements regarding biodiversity and high carbon stock areas (HCV).Norwegian Environment Agency: Facts on biofuels. (in Norwegian) 3. March 2016. http://www.miljodirektoratet.no/no/Nyheter/Nyheter/2016/Mars-2016/Fakta-om-biodrivstoff/ Palm oil may endanger the
carbon neutrality Carbon neutrality is a state of net-zero carbon dioxide emissions. This can be achieved by balancing emissions of carbon dioxide with its removal (often through carbon offsetting) or by eliminating emissions from society (the transition to the "p ...
of the fuel if forest is cleared and swamps drained to make way for palm plantations. In response to this concern, Neste has joined the Round Table on Sustainable Palm Oil (RSPO) to certify that the palm oil is produced in a carbon-neutral, environmentally responsible manner. Neste purchases most of its palm oil from IOI, but requires a separate production chain for the RSPO-certified palm oil, in order not to create demand for rainforest destruction. Deforestation would release carbon to the atmosphere, and reduce the overall carbon binding capacity of the land, thus it would be counterproductive with respect to the carbon balance. In 2007,
Greenpeace Greenpeace is an independent global campaigning network, founded in Canada in 1971 by Irving Stowe and Dorothy Stowe, immigrant environmental activists from the United States. Greenpeace states its goal is to "ensure the ability of the Earth t ...
protested the use of palm oil, concluding the potential for deforestation remains. According to Greenpeace, increasing the production of palm oil reduces the available land area, so indirectly generates demand for rainforest destruction, even if the palm oil itself is rainforest-certified. Greenpeace noted RSPO is voluntary organization and claimed government regulation in palm oil producing countries, such as
Indonesia Indonesia, officially the Republic of Indonesia, is a country in Southeast Asia and Oceania between the Indian and Pacific oceans. It consists of over 17,000 islands, including Sumatra, Java, Sulawesi, and parts of Borneo and New Gui ...
, cannot be relied on because of
political corruption Political corruption is the use of powers by government officials or their network contacts for illegitimate private gain. Forms of corruption vary, but can include bribery, lobbying, extortion, cronyism, nepotism, parochialism, patronage, i ...
. Greenpeace also claimed
palm oil diesel Vegetable oils are increasingly used as a substitute for fossil fuels. Vegetable oils are the basis of biodiesel, which can be used like conventional Diesel fuel, diesel. Some vegetable oil blends are used in unmodified vehicles, but straight veget ...
can actually produce three to 10 times more carbon dioxide emissions than petrodiesel because of the indirect effects of clearing of
swamp A swamp is a forested wetland.Keddy, P.A. 2010. Wetland Ecology: Principles and Conservation (2nd edition). Cambridge University Press, Cambridge, UK. 497 p. Swamps are considered to be transition zones because both land and water play a role in ...
s, forest fires and indirect generation of demand for land area. Greenpeace demands that Neste should use domestic feedstocks such as
rapeseed oil Close-up of canola blooms Canola flower Rapeseed oil is one of the oldest known vegetable oils. There are both edible and industrial forms produced from rapeseed, the seed of several cultivars of the plant family Brassicaceae. Historicall ...
or
biogas Biogas is a mixture of gases, primarily consisting of methane, carbon dioxide and hydrogen sulphide, produced from raw materials such as agricultural waste, manure, municipal waste, plant material, sewage, green waste and food waste. It is a ...
, instead. However, rapeseed is a slower-growing, cold-climate source with lesser carbon-binding potential than the oil palm, making emissions from cultivation and transport proportionally more severe. In 2017, the share of palm oil in the feedstock has been reduced to less than 20%, being replaced by reclaimed waste oils such as used frying oil, animal and fish fat, and camelina, jatropha, soy and rapeseed oil. Use of reclaimed waste oil reduces the greenhouse gas impact by 88–91%. Neste is continuing to look into new feedstock, including
algae Algae (; singular alga ) is an informal term for a large and diverse group of photosynthetic eukaryotic organisms. It is a polyphyletic grouping that includes species from multiple distinct clades. Included organisms range from unicellular micr ...
, jatropha and
microbial oil Single cell oil, also known as Microbial oil consists of the intracellular storage lipids, triacyglycerols. It is similar to vegetable oil, another biologically produced oil. They are produced by oleaginous microorganisms, which is the term for ...
.


Use

This diesel is blended with petrodiesel. A market is created because the European Union required 5.75% of transport fuels should be biofuels by 2010. The EU further decided on 18 December 2008, that by 2020, the share of energy from renewable sources in all forms of transportation be at least 10% of the final consumption of energy. Systems and regions without an electrical grid will be the long-term market for hydrotreated vegetable oils, as the EU prefers electrical use by factor 2.5. In the Helsinki area, the Helsinki Metropolitan Area Council and the Helsinki City Transport conducted a three-year experiment by running buses with 25% Neste Renewable Diesel at first, and then switching to 100% in 2008. The trial, which was the largest field test of a biofuel produced from renewable raw materials worldwide, was a success: local emissions were decreased significantly, with particle emissions decreased by 30% and nitrogen oxide emissions by 10%, with excellent winter performance and no problems with catalytic converters. Since then, Helsinki buses have run on Neste Renewable Diesel. As a result of its hydrocarbon nature, Neste Renewable Diesel operates without problems in current diesel vehicles in all climatic conditions. It does not have any of the drawbacks of the traditional ester type FAME biodiesel, such as cold operability, 'best before' date, engine and fuel system deposit formation, risk for microbial growth and water pick up, engine oil dilution and deterioration. Neste Renewable Diesel can be blended into diesel fuel in any ratio, whereas the use of the traditional FAME biodiesel is limited to maximum 7% by the EN 590 standard in order to avoid technical problems in engines and vehicles. The European Union requires the use of renewable fuel, therefore it is expected to be a major market for Neste Renewable Diesel. Following a proposal by VDA,
Daimler Trucks Daimler Truck AG (holding company legal name Daimler Truck Holding AG) is one of the world's largest commercial vehicle manufacturers, with over 35 main locations worldwide and approximately 100,000 employees. Daimler Truck AG is headquartered in ...
and Daimler Buses recommend the biofuel Neste Renewable Diesel as an admixture to
petrodiesel Diesel fuel , also called diesel oil, is any liquid fuel specifically designed for use in a diesel engine, a type of internal combustion engine in which fuel ignition takes place without a spark as a result of compression of the inlet air an ...
.


See also

* Biomass to liquid (BtL)


References

{{Palm oil Synthetic fuel technologies Renewable energy technology Petroleum production Biofuels Palm oil