mineral
In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2 ...
species belonging to the zeolite group. It is a hydrated
sodium
Sodium is a chemical element with the symbol Na (from Latin ''natrium'') and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 of the periodic table. Its only stable ...
and
aluminium
Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. I ...
Hohentwiel
Hohentwiel is an extinct volcano in the Hegau region of Baden-Württemberg in southern Germany The mountain is west of the city of Singen and 20 miles (30 km) from Lake Constance.
Hohentwiel began forming, along with the chain of vol ...
Germany
Germany,, officially the Federal Republic of Germany, is a country in Central Europe. It is the second most populous country in Europe after Russia, and the most populous member state of the European Union. Germany is situated betwe ...
.
It was named natrolite by
Martin Heinrich Klaproth
Martin Heinrich Klaproth (1 December 1743 – 1 January 1817) was a German chemist. He trained and worked for much of his life as an apothecary, moving in later life to the university. His shop became the second-largest apothecary in Berlin, and ...
in 1803. The name is derived from ''natron'' (), the Greek word for
soda
Soda or SODA may refer to:
Chemistry
* Some chemical compounds containing sodium
** Sodium carbonate, washing soda or soda ash
** Sodium bicarbonate, baking soda
** Sodium hydroxide, caustic soda
** Sodium oxide, an alkali metal oxide
* Sod ...
, in reference to the sodium content, and ''lithos'' (), meaning stone. Needle stone or needle-zeolite are other informal names, alluding to the common acicular habit of the
crystal
A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macro ...
s, which are often very slender and are aggregated in divergent tufts. The crystals are frequently epitaxial overgrowths of natrolite, mesolite, and gonnardite in various orders.
Properties
Larger crystals most commonly have the form of a square prism terminated by a low pyramid, the prism angle being nearly a right angle. The crystals are tetragonal in appearance, though actually orthorhombic. There are perfect cleavages parallel to the faces of the prism. The mineral also often occurs in compact fibrous aggregates, the fibers having a divergent or radial arrangement. Natrolite is readily distinguished from other fibrous zeolites by its optical characteristics.
Between crossed
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s the fibers extinguish parallel to their length, and they do not show an optic figure in convergent polarized light. Natrolite is usually white or colorless, but sometimes reddish or yellowish. The luster is vitreous, or, in finely fibrous specimens, silky.
The specific gravity is 2.2, and the
hardness
In materials science, hardness (antonym: softness) is a measure of the resistance to localized plastic deformation induced by either mechanical indentation or abrasion. In general, different materials differ in their hardness; for example hard ...
is 5.5. The mineral is readily fusible, melting in a candle-flame to which it imparts a yellow color owing to the presence of sodium. It is decomposed by
hydrochloric acid
Hydrochloric acid, also known as muriatic acid, is an aqueous solution of hydrogen chloride. It is a colorless solution with a distinctive pungent smell. It is classified as a strong acid
Acid strength is the tendency of an acid, symbol ...
with separation of gelatinous
silica
Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is ...
.
Environment
Natrolite occurs with other zeolites in the amygdaloidal cavities of
basalt
Basalt (; ) is an aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the surface of a rocky planet or moon. More than 90 ...
ic
igneous rock
Igneous rock (derived from the Latin word ''ignis'' meaning fire), or magmatic rock, is one of the three main rock types, the others being sedimentary and metamorphic. Igneous rock is formed through the cooling and solidification of magma o ...
s. It is also common in nepheline syenites.
Notable localities
Excellent specimens of diverging groups of white prismatic crystals are found in compact
basalt
Basalt (; ) is an aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the surface of a rocky planet or moon. More than 90 ...
France
France (), officially the French Republic ( ), is a country primarily located in Western Europe. It also comprises of overseas regions and territories in the Americas and the Atlantic, Pacific and Indian Oceans. Its metropolitan area ...
. Huge crystals have been found on the Kola Peninsula, Russia (30 cm by 13 cm). The walls of cavities in the basalt of the Giants Causeway, in
County Antrim
County Antrim (named after the town of Antrim, ) is one of six counties of Northern Ireland and one of the thirty-two counties of Ireland. Adjoined to the north-east shore of Lough Neagh, the county covers an area of and has a population o ...
, are frequently encrusted with slender needles of natrolite, and similar material is found abundantly in the volcanic rocks (basalt and phonolite) of Salesel, Aussig and several other places in the north of Bohemia. Mont St. Hilaire,
Quebec
Quebec ( ; )According to the Canadian government, ''Québec'' (with the acute accent) is the official name in Canadian French and ''Quebec'' (without the accent) is the province's official name in Canadian English is one of the thirtee ...
has produced large crystals associated with many rare minerals. The Bay of Fundy in
Nova Scotia
Nova Scotia ( ; ; ) is one of the thirteen provinces and territories of Canada. It is one of the three Maritime provinces and one of the four Atlantic provinces. Nova Scotia is Latin for "New Scotland".
Most of the population are native Eng ...
,
New Jersey
New Jersey is a state in the Mid-Atlantic and Northeastern regions of the United States. It is bordered on the north and east by the state of New York; on the east, southeast, and south by the Atlantic Ocean; on the west by the Delaware ...
,
Oregon
Oregon () is a state in the Pacific Northwest region of the Western United States. The Columbia River delineates much of Oregon's northern boundary with Washington, while the Snake River delineates much of its eastern boundary with Idaho. T ...
, and
British Columbia
British Columbia (commonly abbreviated as BC) is the westernmost province of Canada, situated between the Pacific Ocean and the Rocky Mountains. It has a diverse geography, with rugged landscapes that include rocky coastlines, sandy beaches, ...
have also produced excellent specimens.
Several varieties of natrolite have been distinguished by special Nips. Fargite is a red natrolite from Glenfarg in Perthshire. Bergmannite, or Spreustein, is an impure variety which has resulted by the alteration of other minerals, chiefly sodalite, in the augitesyenite of southern Norway.
Natrolite is one of the closely associated minerals with Benitoite, a rare mineral with the type locality in San Benito County, California.
Images
File:Zeolite-greenland hg.jpg, Natrolite from the plateau basalts in east Greenland
File:Natrolite-61051.jpg, Colorless, radiating natrolite in zeolite pod
File:Catapleiite, Natrolite-168971.jpg, Catapleiite and natrolite from Poudrette quarry, Québec, Canada
File:Natrolite-Inesite-21148.jpg, Slender needles of natrolite are accented by deep pink inesites
File:Natrolite-223955.jpg, Natrolite in spherical clusters inside protective pocket of volcanic rock
File:Natrolite-Inesite-37029.jpg, Natrolite sprays of stark white crystals are shooting out from a
vug
A vug, vugh, or vugg (
) is a small- to medium-sized cavity inside rock. It may be formed through a variety of processes. Most commonly, cracks and fissures opened by tectonic activity (folding and faulting) are partially filled by quartz, ...